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rdac:C10001 bibo:Article

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Diesel Nucleation Mode Particles: Semivolatile or Solid?

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n2:filippoandreade n12:eb300f89d7d4d05c2bc16f7c8bbb1c8a

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Although the preponderance of current data points to semivolatile diesel nuclei particles composed of sulfuric acid and heavy hydrocarbons, the question remains as to what extent, if any, they contain solid cores. We present evidence here of a “solid” particle nucleation mode that accompanies normal soot emissions in the case of two modern light-duty diesel vehicles run with ultralow sulfur fuel. This mode is most prominent at idle, but also appears at speeds below ∼30 mph, and is highly sensitive to the level of exhaust gas recirculation (EGR). The nuclei particles are examined for their volatility and electrical charge. In stark contrast to “conventional” nuclei particles, they remain nonvolatile to >400 °C and exhibit a bipolar charge with a Boltzmann temperature of 580 °C. Their nonvolatile nature rules out sulfate and heavy hydrocarbons as primary constituents, and their electrical charge requires formation in a high-temperature environment capable of generating bipolar ions. This suggests that “solid” nuclei particles form during combustion but remain distinct from soot particles, analogous to what has been found recently in flames. As concerns about potential emissions of nonvolatile nanoparticles have already surfaced, an important conclusion of this study is that diesel particulate filters remove the “solid” nucleation mode with an efficiency comparable to soot. Electrical and volatility properties of “solid” diesel nuclei particles demonstrate that these are engine-formed, whereas their semivolatile counterparts nucleate as the exhaust cools.

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