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Asymmetric Induction of the Iodolactonization Reaction ofα-Sulfurated γ-Unsaturated Amides
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The 1,3-asymmetric iodolactonization reaction of enantiopure α-sulfurated γ-unsaturated amideshas been investigated. With sulfinyl and sulfonyl groups, a poorly stereoselective reaction wasobserved, whereas with a sulfanyl moiety, the diastereoselectivity can be high as 96:4. The role ofthe oxygen atom on the sulfur moiety is discussed.
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