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| - TAML Oxidant Activators: ANew Approach to the Activationof Hydrogen Peroxide forEnvironmentally SignificantProblems
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| - In the Institute for Green Oxidation Chemistry, we develop oxidation catalysts with useful lifetimes via an iterative design processin which oxidation-sensitive ligand groups are identified andreplaced. The process has led to catalysts with greatly enhancedstability toward oxidative and hydrolytic degradation. The ironcatalysts described herein can be comprised exclusively of biochemically common elements. They are efficient and selectiveperoxide activators for many areas of technology. They are water-soluble and are effective in minute quantities (nanomolar to lowmicromolar) over a broad pH range. Various green chemistryapplications are sketched.
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