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À propos de : A Study on Liquid−Liquid Distribution Based onSingle Picoliter Droplets and in SituElectrochemical Measurements        

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  • A Study on Liquid−Liquid Distribution Based onSingle Picoliter Droplets and in SituElectrochemical Measurements
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  • A microelectrode technique combined with the microcapillary injection/manipulation of a single organic dropletin water was developed. The technique was applied to thestudy of the distribution of a ferrocene derivative acrossa single-picoliter-nitrobenzene-droplet/water interface andto the simultaneous in situ electrochemical determinationof the distributed solute in the picomole−femtomolerange. The liquid−liquid distribution processes werediscussed in terms of droplet size and solute concentration (in water) dependencies of the interfacial masstransfer rate.
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