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À propos de : Critical Size of a Nano SnO2 Electrode for Li-Secondary Battery        

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  • Critical Size of a Nano SnO2 Electrode for Li-Secondary Battery
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  • SnO2 nanoparticles with different sizes of ∼3, ∼4, and ∼8 nm were synthesized using a hydrothermalmethod at 110, 150, and 200 °C, respectively. The results showed that the ∼3 nm-sized SnO2 nanoparticleshad a superior capacity and cycling stability as compared to the ∼4 and ∼8 nm-sized ones. The ∼3nm-sized nanoparticles exhibited an initial capacity of 740 mAh/g with negligible capacity fading. Theelectrochemical properties of these nanoparticles were superior to those of thin-film analogues.Transmission electron microscopy (TEM) and X-ray diffraction (XRD) confirmed that the ∼3 nm-sizedSnO2 nanoparticles after electrochemical tests did not aggregate into larger Sn clusters, in contrast tothose observed with the ∼4 and ∼8 nm-sized ones.
  • The ∼3 nm-sized SnO2 nanoparticles, synthesized using a hydrothermal method at 110 °C, exhibited an initial capacity of 740 mAh/g with negligible capacity fading.
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