| Abstract
| - The thermodynamic stability of Li2MnSiO4 polymorphs and their electrochemical properties as electrode for Li batteries are investigated combining experimental and computational methods. Three possible Li2MnSiO4 forms have been considered crystallizing in Pmnb, Pmn21 (β-Li3PO4 derivatives) and P21/n (γ-Li3PO4 derivative) space groups (S.G.). We have first demonstrated that the relative stability of β- and γ-Li3PO4 polymorphs is well-reproduced by density functional theory (DFT) methods (LDA, GGA). For Li2MnSiO4, the Pmnb form is predicted to be 2.4 meV/f.u. and 65 meV/f.u. more stable than the Pmn21 and P21/n forms, respectively (GGA + U results). Computational results indicate that the denser Pmn21 polymorph can be obtained by high pressure/high temperature treatment of the other polymorphs or their mixtures. A sample of Li2MnSiO4 prepared at 900 °C consists of a mixture of polymorphs, as detected by XRD and confirmed by means of SAED and 6Li MAS-NMR. As expected from DFT results, exposing the as-prepared Li2MnSiO4 sample to high pressure/high temperature (pressure range 2−8 GPa, temperature range 600−900°C) allows to isolate the Pmn21 polymorph. The crystal structure has a minor impact in the average lithium intercalation voltage for the two electron process (GGA+U calculated voltages are 4.18, 4.19, and 4.08 V for Pmnb, Pmn21 and P21/n, respectively). Major structural rearrangements are expected under lithium deinsertion from the P21/n polymorph, as previously found for the β-Li3PO4 derivatives, rendering any MnSiO4 delithiated hosts prompt to transform into a more stable structure or a mixture of them.
- The Pmnb-Li2MnSiO4 polymorph is 2.4 eV/f.u. and 65 meV/f.u. more stable than the Pmn21 and P21/n forms, respectively. Calculations and experiments show that the denser Pmn21 polymorph can be isolated at high pressure. Calculated average lithium intercalation voltages are around 4.1 V for the three polymorphs. All the delithiated MnSiO4 forms are likely to decompose.
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