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| - Synthesis and Characterization of Bimagnetic Bricklike Nanoparticles
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| Abstract
| - Bimagnetic FePt/CoFe2O4 nanoparticles having a bricklike morphology were synthesized by growing a soft magnetic CoFe2O4 phase on FePt cubic nanoparticle seeds. The size of the soft phase could be controlled by tuning the material ratio of the FePt seeds to the CoFe2O4 component. To obtain magnetic hardening, the as-synthesized bricklike nanoparticles were annealed at elevated temperatures under a reductive atmosphere to convert the disordered face-centered cubic FePt phase into the ordered L10 phase having high magnetic anisotropy. When the particles were annealed, a gradual change was observed in morphology from bricklike particles to spherical polycrystalline nanocomposite particles because of diffusion. Meanwhile, the magnetic energy density was enhanced as a result of the exchange coupling between the hard and soft phases. The enhancement was dependent on the ratio of the volumes of the soft phase and the hard phase.
- Bimagnetic FePt/CoFe2O4 bricklike nanoparticles were synthesized by growing a CoFe2O4 phase on cubic FePt nanoparticles. Reductive annealing of an assembly of the bricklike nanoparticles transformed it into a magnetic nanocomposite having an enhanced energy product resulting from exchange coupling between the hard and soft magnetic phases.
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| - Bimagnetic Bricklike Nanoparticles
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