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À propos de : Piperylene Sulfone: A Recyclable Dimethyl Sulfoxide Substitute forCopper-Catalyzed Aerobic Alcohol Oxidation        

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  • Piperylene Sulfone: A Recyclable Dimethyl Sulfoxide Substitute forCopper-Catalyzed Aerobic Alcohol Oxidation
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  • Piperylene sulfone was investigated as a recyclable dimethyl sulfide (DMSO) substitute for copper-catalyzedroom temperature aerobic alcohol oxidation. Under the optimal conditions, various primary alcohols couldbe selectively converted into aldehydes in excellent yields with exceptionally high turnover frequency (over31 h-1). The catalytic system also shows good compatibility with heteroatom-containing (S and N) substrates.Most importantly, the new developed catalytic system could also be recycled and reused for three runs withonly slight loss of catalytic activity.
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