| Abstract
| - The synthesis, electrochemistry, spectroscopy, andstructural characterization of two high-valent phenylσ-bondedcobalt corroles containing a central cobalt ion in formal +IV and+V oxidation states is presented. Thecharacterized compounds are represented as phenyl σ-bonded cobaltcorroles, (OEC)Co(C6H5) and[(OEC)Co(C6H5)]ClO4, where OECis the trianion of2,3,7,8,12,13,17,18-octaethylcorrole. Theelectronic distributionin both molecules is discussed in terms of their NMR and EPRspectroscopic data, magnetic susceptibility, andelectrochemistry.
- The synthesis, electrochemistry, spectroscopy,and structural characterization of two high-valent phenyl σ-bondedcobalt corroles is presented. The investigated compounds arerepresented as (OEC)Co(C6H5) and[(OEC)Co(C6H5)]ClO4,where OEC is the trianion of2,3,7,8,12,13,17,18-octaethylcorrole. Theelectronic distribution in both molecules is discussed in terms oftheir NMR and EPR spectroscopic data, magnetic susceptibility andelectrochemistry.
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