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À propos de : Mechanism of Water Oxidation Catalyzed by the μ-Oxo Dimer [(bpy)2(OH2)RuIIIORuIII(OH2)(bpy)2]4+        

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  • Mechanism of Water Oxidation Catalyzed by the μ-Oxo Dimer [(bpy)2(OH2)RuIIIORuIII(OH2)(bpy)2]4+
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  • Ce(IV) oxidation ofthe ruthenium blue dimer leads to catalytic oxidation of water.Kinetic and spectroscopic studies have revealed evidence forRuVORuV as the active catalyst. Redoxcycling occurs between RuIIIORuIII andRuVORuV via a complex sequence of coupledsteps involving oxidations by Ce(IV) and second-order crossreactions of the dimer. The oxygen-evolving step is not ratedetermining in the catalyticcycle.
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