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À propos de : Solids with Rhombic Channels: Syntheses andCrystal Structures of[Cu3(NTA)2(4,4‘-bpy)2(H2O)2]·9H2O and[{Cu(4,4‘-bpy)(H2O)4}{Cu2(NTA)2(4,4‘-bpy)}]·7H2O (NTA = Nitrilotriacetate, 4,4‘-bpy =4,4‘-Bipyridine)        

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  • Solids with Rhombic Channels: Syntheses andCrystal Structures of[Cu3(NTA)2(4,4‘-bpy)2(H2O)2]·9H2O and[{Cu(4,4‘-bpy)(H2O)4}{Cu2(NTA)2(4,4‘-bpy)}]·7H2O (NTA = Nitrilotriacetate, 4,4‘-bpy =4,4‘-Bipyridine)
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  • Crystal structure determination of the two substances Cu3(NTA)2(4,4‘-bpy)2(H2O)2]·9H2O (1) and [{Cu(4,4‘-bpy)(H2O)4}{Cu2(NTA)2(4,4‘-bpy)}]·7H2O (2) reveals that 1 has layer structure with cross-linking rhombic channels generated from helical chains. 2 contains rhombic channels generated from both covalent bonds and hydrogen bonds between the cations and dimeric anions.
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