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À propos de : Molecular Charge-Transfer Salt of BEDT−TTF[Bis(ethylenedithio)tetrathiafulvalene] with theOxalate-Bridged Dimeric Anion [Fe2(C2O4)5]4-        

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  • Molecular Charge-Transfer Salt of BEDT−TTF[Bis(ethylenedithio)tetrathiafulvalene] with theOxalate-Bridged Dimeric Anion [Fe2(C2O4)5]4-
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  • The compound (BEDT−TTF)4·Fe2(C2O4)5 consists of an Fe(III)−Fe(III) oxalate bridged dimer, with a Fe−Fe distance of 5.472 Å interspersed with 4 BEDT−TTF in a “checker board” arrangement. It contains [Fe2(C2O4)5]4- anions and four dimerized BEDT−TTF cations each having an approximate charge of +1. The compound is semiconducting and exhibits short-range antiferromagnetic ordering at low temperature.
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