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À propos de : Synthesis and Characterization of a HomolepticThiolate Complex of Titanium(IV)        

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  • Synthesis and Characterization of a HomolepticThiolate Complex of Titanium(IV)
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  • The reaction of Ti(NEt2)4 with 10 equiv of PhCH2SH in toluene resulted in the formation of the ionic complex [NEt2H2][Ti2(μ-SCH2Ph)3(SCH2Ph)6]. The X-ray structure of the complex has been determined. The coordination number at each titanium center is 6, and the geometry is approximately octahedral.
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