Documentation scienceplus.abes.fr version Bêta

À propos de : (THF)3LiCl as a Ligand for Low-CoordinateFe(II): Crystal Structure of[(Me3Si)2N]2Fe(μ-Cl)Li(THF)3        

AttributsValeurs
type
Is Part Of
Subject
Title
  • (THF)3LiCl as a Ligand for Low-CoordinateFe(II): Crystal Structure of[(Me3Si)2N]2Fe(μ-Cl)Li(THF)3
has manifestation of work
related by
Author
Abstract
  • The pale-green, air-sensitive complex [(Me3Si)2N]2Fe(μ-Cl)Li(THF)3 was synthesized serendipitously by the reaction of iron(II) chloride in THF with 1 equiv of KN(SiMe3)2 and subsequent addition of CpLi and was structurally characterized by X-ray diffraction. ClLi(THF)3 acts as a ligand and appears to be a better donor than THF for the three-coordinate trigonal-planar Fe atom.
article type
is part of this journal



Alternative Linked Data Documents: ODE     Content Formats:       RDF       ODATA       Microdata