Abstract
| - The first 10-vertex phosphadicarbaboranes, 6-R-arachno-6,8,9-PC2B7H111 (R = Ph 1a or Me 1b) and 6-Me-arachno-6,5,7-PC2B7H112 have been synthesized in good yields and structurally characterized with the aid of DFT/GIAO/NMR calculations in conjunction with multinuclear NMR studies.
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