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À propos de : Layered K4[Re6S10(CN)2] and ChainlikeK4[Re6Se10(CN)4]: New Types of ChalcocyanideCluster Compounds with Bridging ChalcogenideLigands        

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  • Layered K4[Re6S10(CN)2] and ChainlikeK4[Re6Se10(CN)4]: New Types of ChalcocyanideCluster Compounds with Bridging ChalcogenideLigands
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  • The chalcocyanide compounds K4[Re6S10(CN)2] (1) and K4[Re6Se10(CN)4] (2) have been synthesized from ReQ2 (Q = S, Se) and molten KCN at high temperatures and characterized by single-crystal X-ray diffraction methods. Both compounds exhibit bridging chalcogenido ligands between [Re6Q8]2+ cores and terminal CN- ligands.
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