Synthesis, Structural Characterization, and Photophysics of Dinuclear Gold(II) Complexes[{Au(dppn)Br}2](PF6)2 and [{Au(dppn)I}2](PF6)2 with an Unsupported AuII−AuII Bond
A series of novel dinuclear gold(II) complexes having an unsupported Au(II)−Au(II) bond with well-definedoxidation state at the gold center were synthesized. Red shifts in both the low-energy absorption and emissionbands were observed upon increasing the donor ability of the coordinated halogen atoms.
A series of dinuclear gold(II) complexes having an unsupported Au(II)−Au(II) bond with well-defined oxidation state at the gold center were synthesized. Red shifts in both the low-energy absorption and emission bands were observed upon increasing the donor ability of the coordinated halogen atoms.