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À propos de : Terminal Phosphide and Dinitrogen Molybdenum Compounds Obtained from Pnictide-Bridged Precursors        

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  • Terminal Phosphide and Dinitrogen Molybdenum Compounds Obtained from Pnictide-Bridged Precursors
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  • The syntheses of molybdenum terminal phosphide and dinitrogen complexes supported by N-iso-propylanilide ligands are not as straightforward as those previously reported for the analogous N-tert-butylanilide complexes. To arrive at these synthetic targets, facile, high-yielding syntheses of bridging pnictide precursors have been developed, and their reduction chemistry has been explored. Cleavage of the reduced μ-E1 compounds was undertaken using CO and N2, providing access to the target compounds.
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