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À propos de : An Unprecedented 8-Fold Interpenetrating Diamondoid-like CoordinationPolymer Containing a Cu+4(RCO2)4 Cluster as Connecting Node        

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  • An Unprecedented 8-Fold Interpenetrating Diamondoid-like CoordinationPolymer Containing a Cu+4(RCO2)4 Cluster as Connecting Node
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  • The reaction of Cu(I)(CH3CN)4BF4 with 4-pyridylacrylic acid (4-HPYA) affords an unprecedented 8-fold interpenetrating diamondoid-like coordination polymer network [Cu(I)3(4-PYA)2(H2O)(BF4) ] (1) with a Cu+4(CO2)4 cluster as connecting node. The interpenetration in metal coordination polymers is the highest degree ever found within diamondoid nets containing a cluster as connecting note. Strong yellow-green fluorescent emission is observed for 1 at room temperature.
  • The reaction of Cu(I)(CH3CN)4BF4 with 4-pyridylacrylic acid(4-HPYA) affords an unprecedented 8-fold interpenetrating diamondoid-like coordination polymer network [Cu(I)3(4-PYA)2(H2O)(BF4) ] (1) with a Cu+4(CO2)4 cluster as connecting node. Theinterpenetration in metal coordination polymers is the highestdegree ever found within diamondoid nets containing a cluster asconnecting note. Its fluorescent property was also reported.
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