| Abstract
| - A novel chainlike coordination polymer [CuII(2,2‘-bipy)(H2O)2Al(OH)6Mo6O18]nn-, formed from a heteropolyanion [Al(OH)6Mo6O18]3-as a building unit and a copper(II) complex fragment, [CuII(2,2‘-bipy)(H2O)2]2+, as a linker, provides the first example of an extendedstructure based on an Anderson type of polyanion and a transitionmetal complex with organic ligand. The intra- and interchainO−H···O hydrogen-bonding interactions are seemingly responsiblefor the spiral shape of this chain. Crystal data: triclinic space groupP1̄, a = 11.2253(18) Å, b = 14.5194(17) Å, c = 15.2672(10) Å,α = 112.191(8)°, β = 106.693(9)°, γ = 93.916(13)°, and Z =2.
- The self-assembly process of copper−bipyridine complexes and Anderson type heteropolyanions leads to an inorganic−organic hybrid chain compound. The intra- and interchain O−H···O hydrogen-bonding interactions play an important role for the spiral shape of this chain.
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