| Abstract
| - The new imino sulfinamidine ligand PhS(NHt-Bu)NC(Me)N(C6H3-2,6-iPr2), LH(11) was synthesized and allowed to react with ZnEt2 or AlMe3 to give the complexes LZnEt(12) and LAlMe2(13), respectively. The structures of 12 and 13 were determined by X-ray diffraction and shown to contain L as a κ2-N1,N5 bidentate ligand in a six-membered chelate. Formation of the magnesium complex (LMgN(TMS)2·L2Mg) (14) highlighted a secondary coordination mode of L, binding through the sulfinamidine nitrogens in a four-membered chelate.
- The new imino sulfinamidine ligand PhS(NHt-Bu)NC(Me)N(C6H3-2,6-iPr2), LH(11) was synthesized from N-(2,6-diisopropylphenyl)acetamidine (9) and N-tert-butyl phenylsulfinimidoyl chloride (10). Reaction of LH (11) with ZnEt2or AlMe3 gave the complexes LZnEt(12) and LAlMe2(13), respectively. The structures of 12 and 13 were determinedby X-ray diffraction and were shown to contain L as a κ2-N1,N5 bidentate ligand in a six-membered chelate. Formationof the magnesium complex (LMgN(TMS)2·L2Mg) (14) from 11, MgI2, and KN(SiMe3)2 highlighted a secondarycoordination mode of L, binding through the sulfinamidine nitrogens in a four-membered chelate.
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