| Abstract
| - Metalation of meso-hexakis(pentafluorophenyl)-substituted [26]hexaphyrin(1.1.1.1.1.1) (1) has been explored with group 12 metal ions Zn(II), Cd(II), and Hg(II). Zn(II) and Cd(II) ions afforded dinuclear gable-shaped complexes 2 and 3 in good yields, while Hg(II) ion provided bis-Hg(II) and mono-Hg(II) planar complexes, 4 and 5, via C−H bond cleavage.
- Metalation of meso-hexakis(pentafluorophenyl)-substituted [26]hexaphyrin(1.1.1.1.1.1) (1) has been explored with group 12 metalions Zn(II), Cd(II), and Hg(II). Zn(II) and Cd(II) ions affordeddinuclear gable-shaped complexes 2 and 3 in good yields, whileHg(II) ion provided bis-Hg(II) and mono-Hg(II) planar complexes(4 and 5) via C−H bond cleavage.
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