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À propos de : Quasi-Thermoneutral P → B Interactions within Di- and Tri-PhosphineBoranes        

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  • Quasi-Thermoneutral P → B Interactions within Di- and Tri-PhosphineBoranes
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  • The existence of both open and closed forms of the di- and tri-phosphine boranes (2) and (3) have been revealed spectroscopically, structurally, and theoretically.
  • Spectroscopic, structural, and theoretical evidence is provided forboth open (no intramolecular P → B interaction) and closed (withintramolecular P → B interaction) forms of the di- and tri-phosphineboranes [o-(iPr2P)C6H4]2BPh (2) and [o-(iPr2P)C6H4]3B (3).
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