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À propos de : Use of Calix[4]arenes in the Redox Chemistry of Lanthanides: theReduction of Dinitrogen by a Calix[4]arene−Samarium Complex        

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  • Use of Calix[4]arenes in the Redox Chemistry of Lanthanides: theReduction of Dinitrogen by a Calix[4]arene−Samarium Complex
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  • The synthesis and structural characterization of a samarium−dinitrogen complex supported by a calix[4]arene ligand in which the N−N bond distance has been stretched to 1.611(16) Å are described. The central μ3-η2:η2:η2-hydrazido tetraanion formed is bonded to three SmIII centers with an overall butterfly-type arrangement.
  • The synthesis and structural characterization of a samarium−dinitrogen complex supported by a calix[4]arene ligand in whichthe N−N bond distance has been stretched to 1.611(16) Å aredescribed. The central μ3-η2:η2:η2-hydrazido tetraanion formed isbonded to three SmIII centers with an overall butterfly-typearrangement.
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