| Abstract
| - Two new 3D copper(II) azido isomers, [Cu(N3)(nic)]∞ (1 and 2)(nic = nicotinate), have been synthesized and characterized. Tothe best of our knowledge, 1 is the first metal azido complexshowing rutile-type topology, while 2 is a chiral compound obtainedby spontaneous resolution upon crystallization.
- Two new 3D copper azido isomers with interesting structures have been synthesized by hydrothermal reactions, in which 1 is the first metal azido complex showing rutile-type topology and 2 provides a good example of a chiral compound obtained by spontaneous resolution upon crystallization without a chiral auxiliary. The magnetic properties of the two complexes were fully characterized.
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