| Abstract
| - The unsymmetrical Mn-Anderson-based hybrid with the formula of [N(C4H9)4]3[MnMo6O18(C4H6O3NO2)(C4H6O3NH2)] (1) has been synthesized and characterized by X-ray crystallography and electrospray ionization mass spectrometry (ESI-MS). Covalent functionalization of compound 1 results in the formation of controlled assemblies of four new unsymmetrical compounds 2−5, which have been observed in solution directly by ESI-MS.
- The unsymmetrical Mn-Anderson polyoxometalate cluster, [N(C4H9)4]3[MnMo6O18(C4H6O3NO2)(C4H6O3NH2)] (1; N(C4H9)4+ = TBA+), has been prepared and characterized by X-ray crystallography and electrospray ionization mass spectrometry (ESI-MS). Covalent functionalization of compound 1 leads to the controlled assemblies of unsymmetrical alkoxopolyoxometalate clusters of compounds 2−5, which can be directly observed in solution as revealed by ESI-MS studies.
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