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À propos de : Self-Assembly of an Azido-Bridged [NiII6] Cluster Featuring Four Fused Defective Cubanes        

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  • Self-Assembly of an Azido-Bridged [NiII6] Cluster Featuring Four Fused Defective Cubanes
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  • A novel [NiII6] cluster [Ni6(H2L)2(HL1)2(N3)8]·2C2H5OH·2H2O (1·2C2H5OH·2H2O) is formed with the help of N3− ligands together with the parent Schiff base ligand H2L− and its hydrolyzed form HL1− in μ and μ3 modes, featuring four fused defective cubanes and showing intramolecular ferromagnetic interactions.
  • The cluster [Ni6(H2L)2(HL1)2(N3)8]·2C2H5OH·2H2O [1·2C2H5OH·2H2O], featuring four fused defective cubanes, has been obtained via azido-bridge-driven dimerization of two phenolate-centered trinuclear Ni3 fragments.
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