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Circularly polarized emission studies on chiral and achiral europium(III) .beta.-diketonate complexes in an optically active solvent
Interaction of aquated cis-diammineplatinum(II) with nucleic acid constituents. 1. Ribonucleosides
Synthesis of biocytin-containing peptides
A flash photolytic investigation of low energy homolytic processes in methylcobalamin
Exciplex quenching. A frontier molecular orbital rationale
Isolation and identification of cross-linked nucleosides from nitrous acid treated deoxyribonucleic acid
Stereoselection in the aldol condensation
The photochemical decomposition of 1,4-s-tetrazine-15N2
Production of antibiotics by biotransformation of 2,4,6/3,5-pentahydroxycyclohexanone and 2,4/3,5-tetrahydroxycyclohexanone by a deoxystreptamine-negative mutant of Micromonospora purpurea
Heterogeneous photocatalytic oxidation of cyanide ion in aqueous solutions at titanium dioxide powder
Dicyanocarbene. Triplet and singlet structures and energetics
Spin delocalization in 7-norbornenyl-type radicals. 2. The effect of 7-substitution on stereochemistry
Negative activation enthalpy in the dimerization of anthracene at very high pressure
Enantiomeric recognition during cyclopentanone formation with iron(0)
Redox reactions of di-.mu.-oxo bridged binuclear manganese(IV) and -(III) complexes
Remarkably different structures of two metalloporphyrins containing M2O34+ units
Remote and proximate substituent effects on trishomocyclopropenium ion formation in the solvolysis of methyl and phenyl substituted 9-pentacyclo[4.3.0.02,4.03,8.05,7]nonyl p-nitrobenzoates
Molecular orbital theory of the electronic structure of molecules. 31. Substituent stabilization of the phenyl cation
Absolute configuration of a ribonucleic acid adduct formed in vivo by metabolism of benzo[a]pyrene
Synthesis of methionine carrying a chiral methyl group and its use in determining the steric course of the enzymic C-methylation of indolepyruvate during indolmycin biosynthesis
Relative rates of halogen addition to double and triple bonds. The bromination of trans-cinnamic and phenylpropiolic acids and their esters
Radical anions of [2.2](2,7)naphthalenophane, [2.2](2,7)naphthalenophane-1,11-diene, and trans-12b,12c-dihydrocoronene as studied by electron spin resonance spectroscopy
Stereochemical rigidity in ML5 complexes. 4. Preparations and nuclear magnetic resonance line-shape analyses of intramolecular exchange in neutral ML5 complexes of iron, ruthenium, and osmium
Formolysis and acetolysis of .beta.-(syn-7-norbornenyl)ethyl-.alpha.-13C p-bromobenzenesulfonate. .pi.-Route generated 2-brexyl cation, a nonclassical nonbornyl type
Peri-bridged naphthalenes from 1,8-dilithionaphthalene
Adsorption of amino acid derivatives by d- and l-quartz
Catalysis in oxidation reactions. 3. The oxalic acid catalyzed chromic acid oxidation of tris(1,10-phenanthroline)iron(II)
.beta.-Lactam antibiotics. Novel synthetic routes to cephem-ring system from .beta.-lactam thiazolines via hydrazinothioazetidinones
Methods for the preparations of 1,5-dienes. A metathetical route to medium-sized carbocycles
Orbital interaction and chemical bonds. The role of antisymmetric orbitals in cyclic additions
Ion-molecule reactions of simple aliphatic ketones by continuous and trapped ICR
Proton magnetic resonance study of divalent metal ions binding to adenosine 5'-triphosphate
Synthesis and thermal rearrangements of 3-(2'-methylprop-1'-enylidene)tricyclo[3.2.1.02,4]oct-6-ene
Protonation of phthalic acid: an unusual acylium-carboxonium rearrangement
Variation of stoichiometry in tetrathiofulvalene-tetracyanoquinodimethane complexes
Ion-molecule reactions in mixtures of titanium tetrachloride with olefins in the gas phase
Proton spin-lattice relaxation and reduced values for the carbon-13 nuclear Overhauser enhancement
Kinetics and thermodynamics of intermolecular saturated amine excimers
Vestiges of the "inverted region" for highly exergonic electron-transfer reactions
Photolysis of organopolysilanes. Formation and reactions of substituted 1-silacyclopropene and 1-sila-1,2-propadiene
Nonrigidity in eight-coordinate tetrakis chelates: the stereochemical integrity and geometrical isomerism of tungsten (5-methylpicolinato) (5,7-dichloro-8-quinolinolato) complexes
Paramagnetic organometallic and dialkylamide complexes of trivalent titanium, vanadium, and chromium stabilized by diketonate ligands
Thermal rearrangements of spiro[4.4]nonapolyenes. Unusually rapid 1,5-vinyl migration
Reduction of excited singlet state acetone by 2-propanol
Synthetic analogs of the active sites of iron-sulfur proteins. 14. Synthesis, properties, and structures of bis(o-xylyl-.alpha.,.alpha.'-dithiolato)ferrate(II,III) anions, analogs of oxidized and reduced rubredoxin sites
Synthesis, structure, and physical properties of the bis(7,7,8,8-tetracyano-p-quinodimethane) salt of the paramagnetic cluster tris[(di-.mu.-chloro)(hexamethylbenzene)niobium], [Nb3(.mu.-Cl)6(C6Me6)3]2+(TCNQ)22-
A one-carbon homologation of carbonyl compounds to carboxylic acids, esters, and amides
Excited-state reactivity patterns of hexakisarylisocyano complexes of chromium(0), molybdenum(0), and tungsten(0)
The preparation of HMgX compounds
Solid-state chemistry of organic polyvalent iodine compounds. 10. Sequential, competitive, and reversible topotactic transformations
Photochemistry of unsaturated ketones in solution. 51. Photophysical and photochemical studies of Michler's ketone
Free radical participation in the reaction of metalate anions with alkyl halides
The utilization of a polymeric phenylthiomethyllithium reagent for the homologation of alkyl iodides and its application for the study of intraresin reactions of polymer-bound functional groups
Solvolysis of deuterium-labeled .beta.-(syn-7-norbornenyl)ethyl p-bromobenzenesulfonates. Multiple cation automerizations in tight ion pairs
Conjugate addition of vinylcopper complexes derived from addition of alkylcopper complexes to acetylenes. A stereospecific synthesis of trisubstituted olefins
Selenium stabilized anions. Synthetic transformations based on propargyl selenoxides
The synthesis of derivatives of [14]annuleno[14]annulene, [14]annuleno[16]annulene, and [14]annuleno[18]annulene, bicyclic compounds consisting of two ortho fused macrocyclic conjugated .pi. systems
Antineoplastic agents. 48. The isolation and structure of aplysistatin
The conformational analysis of the E and F rings of atisine, veatchine, and related alkaloids. The existence of C-20 epimers
The designed synthesis of tridecacarbonyldihydridoirondirutheniumosmium and tridecacarbonyldihydridoironrutheniumdiosmium. The first examples of clusters comprised of three different transition metals
Crown ether model systems for the study of photoexcited state response to geometrically oriented perturbers. The effect of alkali metal ions on emission from naphthalene derivatives
Contact chemical shifts for the carbon atoms of nickel complexes of the 4-alkylanilines. The factors governing the EPR hyperfine constants of carbon atoms
Three-electron oxidations. 12. Chromium(V) formation in the chromic acid oxidation of 2-hydroxy-2-methylbutyric acid
Tautomerism of heteroaromatic compounds with five-membered rings. 14. Confirmation of the structure of Reissert salts as condensed 5-aminooxazolium cations
Photolysis of tert-butyl peroxylaurate
Application of a novel thermistor mercury electrode to the study of changes of activity of an adsorbed enzyme on electrochemical reduction and oxidation
Solvolysis of 9-aryl-9-pentacyclo[4.3.0.02,4.03,8.05,7]nonyl p-nitrobenzoates. Unambiguous evidence for the presence of carbon participation by the application of the tool of increasing electron demand
Book Reviews
Competitive ligand substitution reactions in the gas phase: ion-molecule reactions of ligand molecules with ions derived from nitrosyltricarbonylcobalt(0) and with lithium(1+) ion
Chromic acid oxidation of iodide
Critical chain length for development of the .alpha. helix of the peptide having the sequence of L-alanyl-L-leucylglycine in the solid state
Chemically induced dynamic electron polarization in pulse radiolysis. S-T.+-.1 polarization from hydrogen radical reactions
Mechanism of reductive elimination. 2. Control of dinuclear vs. mononuclear elimination of methane from cis-hydridomethyltetracarbonylosmium
Conjugative interaction between .PI. and cyclobutane orbitals. The synthesis and electronic structure of bicyclo[4.1.1]octa-2,4-diene
Model for the binding of D-penicillamine to metal ions in living systems: synthesis and structure of L-histidinyl-D-penicillaminatocobalt(III) monohydrate, [Co(L-His)(D-Pen)].H2O
Sulfuranes. 22. Stereochemical course of an associative displacement at tetracoordinate sulfur(IV) in a sulfurane of known absolute configuration. A proposed system of nomenclature for optically active pentacoordinate species
The stereochemistry of sterols at C-20 and its biosynthetic implications
Anomalously large long-range halogen hyperfine coupling in 4-halo-1-norbornyl radicals
A new class of highly conductive molecular solids: the partially oxidized phthalocyanines
Rate constants and mechanism of reaction of sulfate radical anion with aromatic compounds
Electron density distribution of the azide ion. Quantitative comparison of theoretical calculations with experimental measurements
Masthead
Phase-transfer catalyzed and two-phase reactions of aromatic nitro compounds with iron carbonyls
Homogeneous catalysis by ruthenium carbonyl in alkaline solution: the water gas shift reaction
Chemical consequences of orbital interactions. 6. The similarity of solvent effects on carbocations
A stereochemical analysis of electrocyclic reactions of doublets
Studies of proteins in solution by natural-abundance carbon-13 nuclear magnetic resonance. Spectral resolution and relaxation behavior at high magnetic field strengths
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