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Determination of the absolute configuration of a secondary hydroxy group in a chiral secondary alcohol using glycosidation shifts in carbon-13 nuclear magnetic resonance spectroscopy
Multiple metal-carbon bonds. 8. Preparation, characterization, and mechanism of formation of the tantalum and niobium neopentylidene complexes, M(CH2CMe3)3(CHCMe3)
The molybdenum site of nitrogenase. Preliminary structural evidence from x-ray absorption spectroscopy
Enantioselective carbenoid cyclopropanation catalyzed by chiral vic-dioximatocobalt(II) complexes prepared from natural camphor and .beta.-pinene. Mechanism and stereochemistry
Oxobis(2,2'-bipyridine)pyridineruthenium(IV) ion, [(bpy)2(py)Ru:O]2+
Olefin homologation with titanium methylene compounds
Collisional activation and metastable ion characteristics. 59. Efficiency of collisional activation of gaseous organic ions
Prediction of carbon-13 nuclear magnetic resonance chemical shifts
Reactions of metal-to-metal multiple bonds. 3. Addition of nitric oxide to hexakis(alkoxy)dimolybdenum compounds. Preparation and properties of bis(nitrosyl)hexakis(alkoxy)dimolybdenum compounds and structural characterization of the isopropoxy derivative
Electron density in bis(dicarbonyl-.pi.-cyclopentadienyliron) at liquid nitrogen temperature by x-ray and neutron diffraction
Total synthesis of (.+-.)-dendrobine
Generation of stable acidic solutions of copper(III) chelates from basic copper(II) solutions
A general, selective, and facile method for ketone synthesis from acid chlorides and organotin compounds catalyzed by palladium
Thermolysis of .gamma.-peroxy-.gamma.-butyrolactones: alternate modes for fragmentation
Bicyclobutadienylene(tricyclo[4.2.0.02,5]octa-1,3,5,7-tetraene)-.eta.5-cyclopentadienylcobalt. A possible intermediate in the remarkable gas phase rearrangement of 1,2-diethynyl-.eta.4-cyclobutadiene-.eta.5-cyclopentadienylcobalt
Stereocontrolled approach to steroid side chain via organopalladium chemistry. Partial synthesis of 5.alpha.-cholestanone
Neutral products from deprotonation of tertiary cations in the gas phase
Protein rotational correlation times determined in aqueous solution by carbon-13 rotating frame spin-lattice relaxation in the presence of an off-resonance radiofrequency field
Laser photolysis study of the photoisomerization of retinals
The potential surface for 1,3-dimethylenecyclobutadiene
Allylic alkylation: nucleophilic attack on .pi.-allylpalladium complexes
2-Deoxypentoses. Stereoselective reduction of ketene dithioacetals
Tyrosine protecting groups: minimization of rearrangement to 3-alkyltyrosine during acidolysis
Octahydro- and perhydro[0.0]paracyclophane
Existence and structure of the molecular ion 18-vanadate(IV)
Ab initio calculations on the very strong hydrogen bond of the biformate anion and comparative esterification studies
A highly enantioselective synthesis of cyclopropane derivatives through chiral cobalt(II) complex catalyzed carbenoid reaction. General scope and factors determining the enantioselectivity
Aqueous lanthanide shift reagents. 6. Lanthanide effects on the proton and carbon-13 relaxation rates of sarcosine. Evidence for isostructural amino acid complexes along the lanthanide series
Lithium ion promotion in the synthesis of novel dinuclear iron-carbyne complexes
Allylic alkylation: preparation of .pi.-allylpalladium complexes from olefins
Quinol intermediates in the reaction of .pi.-allylnickel bromides with quinones
Photoreduction and photodecarboxylation of pyruvic acid. Applications of CIDNP to mechanistic photochemistry
Model compounds for R-state and T-state hemoglobins
Highly reduced organometallics. 3. Tetrasodium tetracarbonylmetalates(4-) of chromium, molybdenum, and tungsten, Na4M(CO)4
Biosynthetic studies with carbon-13. Lankacidin group of antibiotics
Sequential rearrangements via bridged carbocations
Novel binuclear cationic complexes of rhodium(I) and iridium(I)
Formation of dithioether dications in the anchimerically assisted reduction of monosulfoxides of mesocyclic and acyclic dithioethers
Antineoplastic agents. 53. The crystal structure of radiatin
Avidin-biotin affinity columns. General methods for attaching biotin to peptides and proteins
MNDO parameters for third period elements
An unusual reaction of tri-tert-butylphosphine with rhodium(III) and iridium(III) chlorides
Matrix electron nuclear double resonance studies of the proton environment of the radical in natural and solvent-refined coal
Spectroelectrochemical studies of olefins. 3. The dimerization mechanism of the 4,4'-dimethoxystilbene cation radical in the absence and presence of methanol
Osmium-catalyzed vicinal oxyamination of olefins by N-chloro-N-argentocarbamates
Flash vacuum pyrolysis studies. 5. Methanesulfenic acid
A model .beta. turn. Circular dichroism and infrared spectra of a tetrapeptide
A synthesis of dl-cocaine using nitrone intermediates
Properties and structure of a tetrakis(tert-phosphino) macrocycle
Catalysis of ester aminolysis by macrocyclic ionophores
Catalysis of carbon monoxide hydrogenation by soluble mononuclear complexes
Substrate selectivity and orientation in aromatic substitution by molecular fluorine
Selective kinetic equalization of chemical shifts in protonated 1,3-dithiane
Reactions of recoil generated chlorine-38 atoms with 2,3-dichlorohexafluoro-2-butene. Cis/trans isomerization accompanying chlorine for chlorine replacement
Pressure saturation of the collisional quenching of the 3B1 state of sulfur dioxide
3-Benzyloxyisoxazole system in construction of tetracyclines
Alkali metal ion specificity in the solution ordering of a nucleotide, 5'-guanosine monophosphate
Addition compounds of alkali metal hydrides. 15. Steric effects in the reaction of representative trialkylboranes with lithium and sodium hydrides to form the corresponding trialkylborohydrides
Nitrogen-15 nuclear magnetic resonance studies of iron-bound cyanide(nitrogen-15)(1-) ion in ferric low-spin cyanide complexes of various porphyrin derivatives and various hemoproteins
Binuclear copper(II) "face to face" inclusion complex of a macrotricyclic ligand
Detection and investigation of allyl and benzyl radicals by photoelectron spectroscopy
Charge distributions and chemical effects. 13. Ab initio study of the charge density-carbon-13 nuclear magnetic resonance shift correlation for ethylenic carbon atoms
Heavy transition metal complexes of biologically important molecules. 3. Crystal and molecular structure of bis(.mu.-1-methylthyminato-N3,O4)bis(cis-diammineplatinum(II)) dinitrate hydrate, [(NH3)2Pt(C6H7N2O2)2Pt(NH3)2](NO3)2.H2O
Masthead
Molecular-beam study of the activation energy requirements for the dioxetane reaction
Three-dimensional aromaticity of polyhedral boranes
An ultraviolet photoelectron spectroscopic-molecular orbital study of some cyclopolyphosphines
Iron(III) chelates with hexadentate ligands from triethylenetetramine and .beta.-diketones or salicylaldehyde. Spin state dependent crystal and molecular structures of [Fe(acac)2trien]PF6(S = 5/2), [Fe(acacCl)2trien]PF6(S = 5/2), [Fe(sal)2trien]Cl.2H2O(S = 1/2), and [Fe(sal)2trien]NO3.H2O(S = 1/2)
Properties and reactions of ketene in the gas phase by ion cyclotron resonance spectroscopy and photoionization mass spectrometry. Proton affinity, site specificity of protonation, and heat of formation of ketene
Reactivity of methyl-substituted ethylenebromonium ions. Correlation between charge distribution and regio- or chemoselectivity
High-yield synthesis and crystal structure of 1,5,9,13-tetraazacyclohexadecane ([16]aneN4)
New silicon-phosphorus reagents in organic synthesis. Carbonyl and conjugate addition reactions of silicon phosphite esters and related systems
The role of substituents in controlling the mode of intramolecular cycloaddition of nitrile ylides
Reactivity and ion pairing of alkali .beta.-ketoenolates
Stereochemistry of vicinal cyanohydrin reduction-elimination
Prototypes for aliphatic and aromatic diazonium ions. An ab initio study of the methane- and benzenediazonium ions
Book Reviews
Allylic alkylation: nature of the nucleophile and application to prenylation
Decarboxylation of monosubstituted derivatives of carbonic acid. Comparative studies of water- and acid-catalyzed decarboxylation of sodium alkyl carbonates in water and water-d2
Mechanism of action of coenzyme B12. An overall anionic mechanism for carbon-skeleton rearrangement in a model reaction
Chemistry of oxasilacyclopropane. 2. Formations of dioxasilacyclopentanes in the reaction of oxasilacyclopropane derivatives with adamantanone and norbornone
Complexation of 4-biphenylcarboxylate by cyclohexaamylose. A conductometric and carbon-13 nuclear magnetic resonance spectrometric analysis
The primary water splitting light reaction. Mass spectrometric determination of gaseous hydrogen and oxygen evolution from water photolysis by platinized chlorophyll a dihydrate polycrystals
An intramolecular cyclization of enaminones involving benzyne intermediates and application to the synthesis of .gamma.-lycorane and related compounds
A novel synthesis of (.+-.)-4-demethoxydaunomycinone
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