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Kohashi Yasuji
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http://hub.abes.fr/acs/periodical/jacsat/1979/volume_101/issue_17/101021ja00511a043/authorship/3
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Synthesis of 2,7-di-tert-butyl-4-ethoxycarbonyl-5-methylthiepin. A remarkably stable and simple monocyclic thiepin
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