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Molecular structure of a stable N-methylimidazole-magnesium 2,4-dinitrophenoxide complex. A model for histidine and N.tau.-methylhistidine coordination in MgATPases and their uncouplers
Titanium-catalyzed olefin metathesis
Concerted intramolecular displacement with rearrangement in allylic systems. Displacement of an allylic ester with a carbanion
Quenching of the fluorescent state of rubrene directly to the ground state
Quantum-chemical considerations on the acidity of thiamin pyrophosphate and related systems
Biosynthesis of vitamin B1 in yeast. Origin of the thiazole unit
Phthalocyanine thin films as semiconductor electrodes
In situ resonance Raman spectroscopic investigation of the tetrathiafulvalene-tetracyanoquinodimethan electrode surface
Ground states of molecules. 55. MINDO/3 study of rearrangements of C4H7 radicals
Kinetic applications of electron paramagnetic resonance spectroscopy. 34. Rate constants for spin trapping. 2. Secondary alkyl radicals
Physical, chemical, and enzymological characterization of enolpyruvate
Synthesis of 2,7-di-tert-butyl-4-ethoxycarbonyl-5-methylthiepin. A remarkably stable and simple monocyclic thiepin
A new bisannulation reagent easily prepared from a butadiene telomer, and its application to steroid synthesis
Pentamethylcyclopentadienyl organoactinides. Trivalent uranium organometallic chemistry and the unusual structure of bis(pentamethylcyclopentadienyl)uranium monochloride
Thermal rearrangement of cyclobutylidene to methylenecyclopropane. Intermediacy of a novel nonclassical carbene
Hydrolysis mechanism of tetrahydroborate(1-) ion in moist acetonitrile. 2. The nature of the intermediate
Spectroscopic studies of ceruloplasmin. Electronic structures of the copper sites
Total synthesis of dl-aplysistatin
Structure and reactivity of the first hafnium carbonyl, bis(.eta.5-cyclopentadienyl)dicarbonylhafnium
Total synthesis of tryptoquivaline G
Conformation of ligated tris(dimethylamino)phosphine
Book Reviews
Coal chemistry. 8. Reactions of tetralin with coal and with some carbon-14-containing model compounds
Molecular beam electric deflection behavior and polarity of hydrogen-bonded complexes of ROH, RSH, and RNH
Catalyzed dimerization of a diquinoethylene and formation of diquinoethylene-rhodium complexes
Quest for an observable model for the SN2 transition state. Pentavalent pentacoordinate carbon
Roles of multiplicity and electronic excitation on intramolecular reactions of alkylcarbenes in condensed phase
Reactions of tantalum(III) with alkynes and nitriles
Unstable carbanions. General acid catalysis of the cleavage of 1-phenylcyclopropanol and 1-phenyl-2-arylcyclopropanol anions
Reactions of atomic metal ions with alkyl halides and alcohols in the gas phase
Spectroscopic studies of Rhus vernicifera and Polyporus versicolor laccase. Electronic structures of the copper sites
Bis(dipicolinate) complexes of cobalt(III) and iron(II) as new probes of metalloprotein electron-transfer reactivity. Analysis of reactions involving cytochrome c and cytochrome c551
Hexakis(pyridine)ruthenium(II) tetrafluoroborate. Molecular structure and spectroscopic properties
Host-guest complexation. 21. Catalysis and chiral recognition through designed complexation of transition states in transacylations of amino ester salts
Structures of [C4H4O]+.cntdot.ions produced from 2- and 4-pyrone
Rapid selective dimerization of ethylene to 1-butene by a tantalum catalyst and a new mechanism for ethylene oligomerization
Structure-basicity relationships in carbonyl compounds
.alpha.-Chloroalkenylalanates. Their preparation and conversion into (E)-1-chloro-1-alkenes and mixed 1,1-dihalo-1-alkenes
Masthead
Acidity function of solid-bound acids
Carbon-13 NMR relaxation mechanisms in methyl-transition metal compounds
Organocobalt cluster complexes. 28. Highly stabilized (nonacarbonyltricobalt)carbon-substituted carbonium ions
Chromopeptides from C-phycocyanin. Structure and linkage of a phycocyanobilin bound to the .beta. subunit
Metal ion complexes of .alpha.-amido acids. 1. Structure and magnetic properties of the nickel and cobalt hippurates. Pseudo-one-dimensional magnetic systems
Host-guest complexation. 18. Effects on cation binding of convergent ligand sites appended to macrocyclic polyethers
Intermolecular energy exchange of infrared-laser excited chlorodifluoromethane or silicon tetrafluoride with bromine at excitation energies of 70-200 kJ/mol
Alkaloid synthesis by the intramolecular imino Diels-Alder reaction. .delta.-Coniceine and tylophorine
The importance of hyperconjugation in nucleophilic vinylic substitution
Reactivity of cyclopropylchlorocarbene: an interactive experimental and theoretical analysis
Molecular orbital theory of the electronic structure of molecules. 39. Highly unusual structures of electron-deficient carbon compounds. Reversal of van't Hoff stereochemistry in BBC ring systems
A tris(dialkylamino)phosphine with pyramidal nitrogens
A total synthesis of gascardic acid
Doubly hindered 7,11-dicis isomers of retinal. Synthesis, properties, and interaction with cattle opsin
Fluxional behavior and substituent site preferences in cationic monosubstituted tropyliumiron tricarbonyl complexes
Mechanism of reductive elimination. Reaction of alkylpalladium(II) complexes with tetraorganotin, organolithium, and Grignard reagents. Evidence for palladium(IV) intermediacy
General acid catalysis in the hydrolysis of benzo[a]pyrene 7,8-diol 9,10-epoxides
Application of force field calculations to organic chemistry. 8. Internal rotation in simple to congested hydrocarbons including 2,3-dimethylbutane, 1,1,2,2-tetra-tert-butylethane, 2,2,4,4,5,5,7,7-octamethyloctane, cholestane
Determination of the .beta.-anomeric configuration of cytidine 5'-monophospho-N-acetylneuraminic acid by carbon-13 NMR spectroscopy
Alkylrhodium tetracarbonyl derivatives as catalytic intermediates in homogeneous hydroformylation reactions. An infrared spectroscopic study
An unusual twist-boat conformation for a six-membered ring phosphorus heterocycle
Palladium-catalyzed coupling of tetraorganotin compounds with aryl and benzyl halides. Synthetic utility and mechanism
Metal clusters. 21. Synthesis of rhodium phosphite clusters
Host-guest complexation. 20. Chiral recognition in transport as a molecular basis for a catalytic resolving machine
Oxidation of carbon monoxide to carbon dioxide by nickel-nitrogen dioxide complexes: a mechanistic study
Oxidation of ruthenium coordinated alcohols by molecular oxygen to ketones and hydrogen peroxide
Anion-radical crystal lattice energies
m-Quinomethane: synthesis of a covalent-biradicaloid pair of valence tautomers
Direct calculation of resonance energies of conjugated hydrocarbons with ab initio MO methods
Structure and photochemistry of lumiprednisone and lumiprednisone acetate
Berninamycin biosynthesis. 1. Origin of the dehydroalanine residues
Photooxidation of azines. Evidence for a free-radical oxidation initiated by singlet oxygen
Estimation of excited-state redox potentials by electron-transfer quenching. Application of electron-transfer theory to excited-state redox processes
A simple total synthesis of (.+-.)-zearalenone by intramolecular alkylation using a butadiene telomer as a building block
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