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Substituent effects in cluster species. 3. Structural consequences of intercage .pi. interactions in the dimer and trimer of 1,5-dicarbapentaborane(5)
Metal-ion recognition by macrocyclic ligands. Thermodynamic stabilities of nickel complexes of a series of O2N2-donor macrocyclic ligands
An electron diffraction study of 1,1-dimethylsilaethylene
Preparation of a "stabilized formyl" complex from carbon monoxide and hydrogen and the crystal structure of a derivative in which the carbon-oxygen bond has been cleaved
Photochemical transformations. 27. Acid-catalyzed photosolvolytic reactions and rearrangements. Evidence for heterolytic photochemical bond cleavage
Charge-transfer absorptions of copper(II)-imidazole and copper(II)-imidazolate chromophores
Topography of cyclodextrin inclusion complexes. 12. Structural chemistry of linear .alpha.-cyclodextrin-polyiodide complexes. X-ray crystal structures of (.alpha.-cyclodextrin)2.LiI3.I2.8H2O and (.alpha.-cyclodextrin)2.Cd0.5).I5.27H2O. Models for the blue amylose-iodine complex
Role of through space 2p-3d overlap in the alkylation of (.omega.-N,N-dimethylaminoalkyl)diphenylphosphines and in the alkaline decomposition of related quaternary phosphonium salts
A new diene synthesis via organopalladium chemistry
Reaction of 3-chloro-3-methyldiazirines with hydrogen atoms
Masthead
Torsion angles in the cystine bridge of oxytocin in aqueous solution. Measurements of circumjacent vicinal couplings between proton, carbon-13, and nitrogen-15
Unimolecular reactions of isolated organic ions. The importance of ion-dipole interactions
Structure, optical resolution, and conformational stability of perchlorotriphenylamine
Electron affinity of HO2 and HOx radicals
A vibrational study of zirconium tetraborohydride supported on aluminum oxide. 1. Interactions with deuterium, deuterium oxide, and water vapor
Cleaving carbon-carbon bonds in cyclopropenium ions
Nucleophilic addition to activated olefins. 3. Reactions of piperidine and morpholine with benzylidenemalononitrile in 50% dimethyl sulfoxide-50% water. Intrinsic barriers in nucleophilic additions
Transition metal catalyzed reactions of alkynes and boron hydrides: synthesis of 2-(cis-2-butenyl)pentaborane(9) and its conversion into monocarbon carboranes
The remarkable catalytic power of glymes in ester aminolysis carried out in nonpolar media
Ring inversion in 1,4,7-cyclononatriene (trishomobenzene). Force-field calculations for abnormally large bond angles
Chiral secondary amides. 2. Molecular packing and chiral recognition
Studies in nuclear magnetic resonance spectroscopy. 17. Deuteron quadrupole coupling constants in intramolecularly hydrogen bonded systems
Electron spin-echo studies of radical interaction and orientation on catalytic surfaces. Hydroxymethyl radicals in A-, Y-, and X-type zeolites
Theory of hyperfine interaction in five-liganded divalent and trivalent manganese porphyrin systems
Reaction of singlet oxygen with .alpha.,.beta.-unsaturated ketones and lactones
Decarboxylation reactions: reactivity of a free carboxylate anion in ethereal solvents
Synthesis and spectroscopic and structural properties of bis(N-acetyl-DL-tryptophanato)copper(II) complex and its amine adducts. Effect of amines on the amino acid coordination. Crystal and molecular structure of diaquabis(N-acetyl-DL-tryptophanato)bis(pyridine)copper(II)
Vapor phase association in acetic and trifluoroacetic acids. Thermal conductivity measurements and molecular orbital calculations
Divalent lanthanide derivatives in organic synthesis. 1. Mild preparation of samarium iodide and ytterbium iodide and their use as reducing or coupling agents
Mechanism of reductive elimination of acetophenone from Me4+[cis-(CO)4Mn(COMe)(COPh)]-
Photolysis of the endoperoxide of heterocoerdianthrone. A concerted, adiabatic cycloreversion originating from an upper excited singlet state
An MO theoretical study on the stability of tetrahedrane
Autoxidation of 2-tert-butyl-2,3-diazabicyclo[2.2.1]heptane. Stereospecific loss of hydrogen from N-3 and C-5, and N-3 and C-6
Effect of solvation on .beta. values for formyl, acetyl, and pivaloyl transfer between sulfur and oxygen nucleophiles
Semiconductor electrodes. 26. Spectral sensitization of semiconductors with phthalocyanine
Crystal structure of a beauvericin-barium picrate complex
Optical rotatory dispersion studies. 128. Octant contributions of methyl groups in 4-tert-butylcyclohexanones
Secondary deuterium isotope effects on formyl transfer reactions between sulfur and oxygen nucleophiles
Chemistry of exciplexes. 9. Viscosity effect on intramolecular exciplex formation in saturated hydrocarbons
A 1,3-O- to -C-alkyl shift catalyzed by palladium
Hemoprotein models: NMR of imidazole chelated protohemin cyanide complexes
A major leaving group effect on chemical events after the group has left: reactions of acetone enolate ion with halobenzenes and related substrates provoked by solvated electrons
High-resolution variable-temperature phosphorus-31 NMR of solid calcium phosphates
Electrochemistry of vitamin B12. 5. Cyanocobalamins
Photochemical kinetics of salicylidenaniline
Kinetics and mechanism of reduction of horse heart cytochrome c by hexaammineruthenium(II) ion. Reactivities of the electronic isomers of cytochrome c
EPR detection of (CF3)3CI-. A test case regarding the stability of RX- radical anions
Correlating phosphorus core binding energies, phosphorus lone pair ionization potentials, and proton affinities of tervalent phosphorus compounds
Production of dixenon cation by reversible oxidation of xenon
Photophysical and photochemical properties of chloropentaamminerhodium(2+) in nonaqueous solvents. Solvent control of the photolabilization pathways of the ligand field excited states
Thermal isomerization of allyl-substituted cyclopropenes. An example of a nonsynchronous cope rearrangement
Total synthesis of dl-tazettine
Ab initio study of bis(nitrogen dioxide)(1+) and bis(carbon dioxide)(1-) ions
Preferred kinetic migration of methyl and preferred thermodynamic migration of phenyl in conversion of cis-acetylbenzoyltetracarbonylrhenate(I) to cis-benzoylmethyltetracarbonylrhenate(I) and cis-acetylphenyltetracarbonylrhenate(I)
1-Benzyl-1,4-dihydronicotinamide as a reagent for replacing aliphatic nitro groups by hydrogen: an electron-transfer chain reaction
Adiabatic J cross-polarization in liquids for signal enhancement in NMR
Evidence for the incursion of intermediates in the hydrolysis of tertiary, secondary, and primary substrates
Synthesis of perfluoroalkyl trifluoromethanesulfonates from perfluoroalkyl halides. Substitutive electrophilic dehalogenation with chlorine(I) and bromine(I) trifluoromethanesulfonates
Reactivity of alkyne tungsten and molybdenum complexes. Heterolytic carbon-hydrogen bond activation in coordinated alkynes
Preparation, disproportionation, and reactions of two semi-met forms of hemerythrin
A vibrational study of zirconium tetraborohydride supported on aluminum oxide. 2. Interactions with ethylene, propylene, and acetylene
Cp2M2(CO)4 - quadruply bridging, doubly bridging, semibridging, or nonbridging?
Visual pigments. 11. Spectroscopy and photophysics of retinoic acids and all-trans-methyl retinoate
Reaction of .alpha.-arylvinyl halides with antimony pentafluoride. A proton and carbon-13 NMR spectroscopic investigation
Pyrazolo[4,3-d]pyrimidine nucleosides. 9. Studies on the isomeric N-methylformycins
Poly(dimethylphosphazene), (Me2PN)n
Organo-sulfur mechanisms. 11. [1,3]-Sigmatropic shifts for 5-X-bicyclo[2.1.0]pent-2-enes. An evaluation of the pseudopericyclic model
Proton-transfer reactions involving alkyl ions and alkenes. Rate constants, isomerization processes, and the derivation of thermochemical data
Variational transition state theory. Primary kinetic isotope effects for atom transfer reactions
Separation and identification of residual diastereomers in a maximally labeled triarylamine
Structure of the free-base "capped" porphyrin, 5,10,15,20-[pyrromellitoyl(tetrakis-o-oxyethoxyphenyl)]porphyrin
Further evidence for single electron transfer during the alkylation of the benzophenone anil dianion
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