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Is Part Of	http://hub.abes.fr/acs/periodical/jacsat/1981/volume_103
has manifestation of work	http://hub.abes.fr/acs/periodical/jacsat/1981/volume_103/issue_12/m/print http://hub.abes.fr/acs/periodical/jacsat/1981/volume_103/issue_12/m/web
issue	12
is Is Part Of of	Fluoromethyl formate. Synthesis, microwave spectrum, structure, dipole moment, and anomeric effect Organoselenium-based synthesis of sulfur-containing prostacyclins Reactivity of the [(.eta.5-C5H5)Ti(Mo5O18)]3- anion: synthesis and structure of MoO2Cl+ and Mn(CO)3+ adducts Direct observation of alkyl/nitrosyl migratory insertion in an organotransition metal complex Electronic relaxation of intra- and intermolecular exciplexes in the vapor phase Total synthesis of sarracenin Activation of cobalt-nitro complexes by Lewis acids: catalytic oxidation of alcohols by molecular oxygen Proton nuclear magnetic resonance study of the relaxation behavior and kinetic lability of exchangeable protons in the heme pocket of cyanometmyoglobin Cleavage of DNA by the 1,10-phenanthroline-copper ion complex. Superoxide mediates the reaction dependent on NADH and hydrogen peroxide Masthead Barriers to ring rotation in 1,1',4,4'-tetra-tert-butyluranocene and 1,1',3,3'-tetra-tert-butylferrocene UPE studies of conjugation involving Group 5A elements. 1. Phenylphosphines Principal components of the cadmium-113 shielding tensors in cadmium sulfate hydrates: a nuclear magnetic resonance study of cadmium coordinated with oxygen Slow multiphoton excitation as a probe of bimolecular and unimolecular reaction energetics. Multiphoton dissociation of proton-bound alcohol dimers Mechanisms of thermal decomposition of diethylbis(triethylphosphine)platinum(II) Crystal structure of vacuum-dehydrated fully ammonium-exchanged zeolite A Gas-phase reactions of O(3P) atoms with methanethiol, ethanethiol, methyl sulfide, and dimethyl disulfide. 2. Reaction products and mechanisms Transport of photoproduced ions in water in oil microemulsions: movement of ions from one water pool to another Ketenedithioacetals as synthetic intermediates. A versatile synthesis of pyridenes, polypyridinyls, and pyrylium salts Additions and Corrections - Conformations of Six N-Methylated Diketopiperazines in Solution Intramolecular electron delocalization: a four-site model Electron spin resonance study of electronic and geometrical structures of C2H6+ and other simple alkane cations at 4.2 K: possible evidence for Jahn-Teller distortion Fast oxidants for NADH and electrochemical discrimination between ascorbic acid and NADH Metalloporphyrins with unusual geometries. 1. Mono-, di-, triatom-bridged porphyrin dimers Additions and Corrections - Effect of Photoelectrode Crystal Structure on Output Stability of Cd(Se,Te)/Polysulfide Photoelectrochemical Cells Generation of rhodium(II) and rhodium(I) from the one-electron reduction of tris(2,2'-bipyridine)rhodium(III) ion in aqueous solution Minor and trace sterols in marine invertebrates. 23. Xestospongesterol and isoxestospongesterol - first examples of quadruple biomethylation of the sterol side chain Book Reviews Additions and Corrections - The Solution Conformational Preferences of the Sugar and Sugar Phosphate Constituents of RNA and DNA The nonadiabaticity problem of outer-sphere electron-transfer reactions. Reduction and oxidation of europium ions Mechanisms of elimination reactions. 33. Carbon isotope effects in E2 reactions of (2-phenylethyl-2-14C)trimethylammonium ion. The role of tunneling Crystal structure and chelate ring pucker of bidentate (pyrophosphato)tetraaquochromium(III) trihydrate, a model for metal-ADP coordination Electron spin resonance and electron spin echo studies of photoproduced tetramethylbenzidine cation radical in frozen aqueous micellar solutions: cation surroundings and retention of micellar structure in frozen solutions Silver(I) photocatalyzed addition of acetonitrile to norbornene Intramolecular electron-transfer reactions in bridged binuclear ruthenium(II)-cobalt(III) molecules Hybrid multidentate ligands. Tridentate amidophosphine complexes of nickel(II) and palladium(II) The sudden polarization effect: MC-SCF calculations on planar and 90.degree. twisted methylenecyclopropene Synthesis of (5Z)- and (5E)-6,9-thiaprostacyclins Carbon-13-proton coupling constants in carbocations. 3. Variation of .DELTA.J with electron demand in aryldialkyl carbocations Carboxypeptidase A catalysis of an .alpha.,.beta.-elimination reaction Quantitative prediction and analysis of enthalpies for the interaction of gas-phase ion-ion, gas-phase ion-molecule, and molecule-molecule Lewis acid-base system Conformational interconversions in pentaalkylhydrazine cation tetrafluoroborates Tetrahedral complexes containing the Fe(II)S4 core. The syntheses, ground-state electronic structures and crystal and molecular structures of the bis(tetraphenylphosphonium) tetrakis (thiophenolato)ferrate (II) and bis (tetrapheny lphosphonium) bis(dithiosquarato)ferrate (II) complexes. An analog for the active site in reducd rubredoxins (Rdred) Characterization of particulate titanium dioxide photocatalysts by photoelectrophoretic and electrochemical measurements Organoselenium-based synthesis of oxygen-containing prostacyclins The first general index of molecular complexity The nature of the 1n.pi.* .rarw. S0 transition. 4. The first excited singlet state of acetaldehyde Specific sequestering agents for the actinides. 6. Synthetic and structural chemistry of tetrakis(N-alkylalkanehydroxamato)thorium(IV) complexes Complete retention in substitution and stereospecificity in transannular reactions of cis- and trans-3-tert-butylcyclooctyl tosylates Photochemistry of stilbene-capped cyclodextrins. Exclusive ring closure of cis cap and direct evidence for trans A,D structure Selective epoxidation of olefins by molybdenum porphyrin catalyzed peroxy-bond heterolysis The cycloheptatrienylidene-cycloheptatetraene problem. A MNDO investigation Theoretical investigation of the structure and rotational barriers of peroxyformimidic acid. The mechanism of stereomutation at the carbon-nitrogen double bond Conversion of coordinated carbon monoxide into carbon dioxide via oxygen-atom transfer from coordinated nitrite: thermolysis of bis(nitrito)dicarbonylbis(triphenylphosphine)ruthenium Palladium(II) complexes with trans bis-(carbon-metal) bonds. Ligand syntheses, complexation, x-ray analysis, and biochemical activity with supercoiled DNA New synthesis of aflatoxin M1 High-resolution NMR spectra in inhomogeneous magnetic fields: application of total spin coherence transfer echoes Additions and Corrections - Stereochemistry of an Enzymatic Baeyer-Villiger Reaction. Application of Deuterium NMR Characterization of apical copper(II)-thioether bonding. Structure and electronic spectra of bis(2,2-bis(5-phenyl-2-imidazolyl)propane)copper(II) diperchlorate and bis(1,3-bis(5-phenyl-2-imidazolyl)-2-thiapropane)copper(II) diperchlorate Neighboring group participation in solvolyses. 11. Kinetic isotope effect study of the solvolysis of neophyl arenesulfonates Laser flash photolysis with NMR detection. Submicrosecond time-resolved CIDNP: kinetics of triplet states and biradicals Lifetimes of some styrene triplets in fluid solution. Triplet geometries and the effect of alkylation Activation of water molecule. 5. Rhodium(I) hydride catalyzed water gas shift reaction. Identification of the elemental reactions comprising the catalytic cycles Kinetic studies and a molecular orbital interpretation of reactions at bridging sulfur ligands in dimeric molybdenum complexes Mechanism of the disproportionation of ascorbate radicals A uranium-carbon multiple bond. Crystal and molecular structure of (.eta.5-C5H5)3UCHP(CH3)2(C6H5) Purported Fischer-Tropsch alkylation of benzene: Reaction of benzene with aluminum trichloride revisited Study of methanesulfonates and trifluoromethanesulfonates. Evidence for hydrogen bonding to the trifluoro group Theoretical studies of dodecahedrane. 3. Ab initio studies of dodecahedrane and its inclusion compounds Organocobalt cluster complexes. 23. Novel chemistry of (acylmethylidyne)- and (aroylmethylidyne)tricobalt-nonacarbonyl complexes Thermal decomposition of di(cycloalkyl)bis(triethylphosphine)platinum(II) complexes Stereospecific total syntheses of dl-coriolin and dl-coriolin B Photoinduced electron transfer in organized assemblies Reactivity of coordinated nitriles Carbon monoxide activation by organoactinides. Catalytic hydrogenation of inserted carbon monoxide 6-Silafulvene via silylcarbene rearrangement from diazo-2-silacyclohexa-3,5-diene UPE studies of conjugation involving Group 5A elements. 2. Substituted tert-butylacetylenes Crystal structure and conformation of cyclo-(glycyl-D-leucyl-L-leucyl)2 Gas-phase reactions of O(3P) atoms with methanethiol, ethanethiol, methyl sulfide, and dimethyl disulfide. 1. Rate constants and Arrhenius parameters Hydrolysis of 3-(m-nitrophenyl)-3-methoxyphthalide Bifunctional chiral synthons via microbiological methods. 1. Optically active 2,4-dimethylglutaric acid monomethyl esters Selective isomerization of butadiene-cyclobutene systems via infrared multiphoton excitation The F3NO- radical anion. ESR spectra, structure, and its dissociation to F2NO Versatility of tetrakis(tert-butylthiolato)molybdenum. Selective formation of a series of thiolato-molybdenum(I), -molybdenum(II), and -molybdenum(IV) compounds Ketene dithio acetals as synthetic intermediates. Synthesis of unsaturated 1,5-diketones

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