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type	work Issue
Is Part Of	http://hub.abes.fr/acs/periodical/jacsat/1981/volume_103
has manifestation of work	http://hub.abes.fr/acs/periodical/jacsat/1981/volume_103/issue_13/m/print http://hub.abes.fr/acs/periodical/jacsat/1981/volume_103/issue_13/m/web
issue	13
is Is Part Of of	Oscillations and bistability in hydrogen-platinum-oxyhalogen systems Oxo-peroxo oxygen exchange in peroxovanadium(V) and peroxomolybdenum(VI) compounds The new amino acid .beta.-carboxyaspartic acid (asa). Laboratory synthesis and identification in the ribosomal proteins of E. coli Kijanimicin. 2. Structure and absolute stereochemistry of kijanimicin Theoretical determination of molecular structure and conformation. 9. Ozonolysis of fluoroalkenes Buildup rates of the nuclear Overhauser effect measured by two-dimensional proton magnetic resonance spectroscopy: implications for studies of protein conformation Ab initio modeling of substituent effects in Hammett correlations Thermolysis of .alpha.-azido sulfides, sulfoxides, and sulfones: dependence of mechanism on oxidation state of sulfur Tetradentate 14-membered tert-phosphino-containing macrocycles Magnetic and micellar effects on photoreactions. 2. Magnetic isotope effects on quantum yields and magnetic field effects on separation efficiency. Correlation of carbon-13 enrichment parameters with quantum yield measurements Model studies for a molecular mechanism of action of oral anticoagulants Electron-impact-induced fragmentation of quaternary ammonium cations Quadruply bonded tetramethyltetrakis(trialkylphosphine)dimolybdenum compounds: phosphine exchange kinetics, acetone formation with carbon monoxide and crystal structure of Mo2Me4(PMe3)4 Cadmium-113 nuclear magnetic resonance studies of cadmium-ethylenediaminetetraacetic acid complexes Conformational analysis of polysubstituted ethanes Total synthesis of the C-nucleoside dl-showdomycin by a Diels-Alder, retrograde Dieckmann strategy Seven-coordinate dicarbonyltriphenylphosphinebis(N,N-dialkyldithiocarbamato)tungsten(II) complexes. Molecular structure and dynamic properties Gas-phase acid-induced nucleophilic displacement reactions. 4. A stereochemical probe for the existence and the relative stability of cyclic halonium ions in the gas phase Magnetic and micellar effects on photoreactions. 1. Carbon-13 isotopic enrichment of dibenzyl ketone via photolysis in aqueous detergent solution Mechanism of the reduction and oxidation reaction of cytochrome c at a modified gold electrode Thermoneutral dyotropic transfer of hydrogen in a hydrocarbon Tetrakis(trifluoromethyl)semibullvalenes. Could Cope degeneration be frozen out? Negative-ion states of terminal methyl-substituted butadienes. Evidence for through-space interactions involving methyl groups Calculation of the nuclear spin-spin coupling constants. 3. .sigma.- and .pi.-Electron contributions in some simple unsaturated hydrocarbons Formation of gas-phase .pi.-allyl radicals from propylene over bismuth oxide and .gamma.-bismuth molybdate catalysts Nuclear magnetic resonance studies of some sodium ion complexes with crown ethers and [2]-cryptands in various solvents Reductive cleavage of 9,9-diarylfluorenes by potassium in 1,2-dimethoxyethane Farnesylpyrophosphate synthetase. A stepwise mechanism for the 1'-4 condensation reaction Polymer films on electrodes. 6. Bioconductive polymers produced by incorporation of tetrathiafulvalenium in a polyelectrolyte (Nafion) matrix Sulfenium ion addition to hexamethyl (Dewar benzene). A case for a hypervalent sulfonium ion intermediate Theoretical determination of molecular structure and conformation. 7. Stereoselectivity of the ozonolysis reaction Absolute heats of formation for gas-phase cations The relationship between nuclear quadrupole coupling constants and the asymmetry parameter. The interplay of theory and experiment The pH jump: a rapid modulation of pH of aqueous solutions by a laser pulse General acid catalysis of alcohol heterolysis Farnesylpyrophosphate synthetase. Evidence for a rigid geranyl cation-pyrophosphate anion pair A chiral synthesis of L-acosamine and L-daunosamine via an enantioselective intramolecular[3 + 2]cycloaddition Iron(III) porphyrin-imidazole complexes. Analysis of carbon-13 nuclear magnetic resonance isotropic shifts and unpaired spin delocalization Photocycloaddition in liquid ethyl cinnamate and in ethyl cinnamate glasses. The photoreaction as a probe into the micromorphology of the solid Solvolysis of 2-(trifluoromethyl)-2-propyl trifluoromethanesulfonate. Solvent, salt, and .beta.-deuterium isotope effects. Substituent effect of a strongly deactivating group and rate-limiting solvent-assisted elimination Synthesis and complexing properties of chiral macrocycles containing enforced cavities Novel substrate-binding property of synthetic membrane vesicles involving an amino acid residue as a molecular component Electrochemistry of titanium(IV) in basic butylpyridinium chloride aluminum chloride in the presence of oxide Gas-phase acid-induced nucleophilic displacement reactions. 5. Quantitative evaluation of neighboring-group participation in bifunctional compounds Monoradical rearrangements of the 1,4-biradicals involved in Norrish type II photoreactions Mechanisms of polymer-supported catalysis. 2. Reaction of benzyl bromide with aqueous sodium cyanide catalyzed by polystyrene-bound onium ions Theoretical determination of molecular structure and conformation. 8. Energetics of the ozonolysis reaction. Primary ozonide vs. carbonyl oxide control of stereochemistry Mechanisms of polymer-supported catalysis. 1. Reaction of 1-bromooctane with aqueous sodium cyanide catalyzed by polystyrene-bound benzyltri-n-butylphosphonium ion Reactivity of carbonyl oxides. Characteristic nucleophilic oxygen atom transfer from R2COO beside electrophilic and radical reactions Dioxygenase model studies: reaction of oxygen with iron catecholates Stereocontrolled synthesis of cis-2,5-disubstituted tetrahydrofurans and cis- and trans-linalyl oxides Thermoneutral isotope-exchange reactions of cations in the gas phase Excited-state prototropism in esters of o-hydroxy-2-naphthoic acids The mechanism of ozone-alkene reactions in the gas phase. A mass spectrometric study of the reactions of eight linear and branched-chain alkenes Nickel-promoted cyclization/carbonylation in the preparation of .alpha.-methylene-.gamma.lactones. Stereospecific synthesis of (.+-.)-frullanolide Nitrogen-15 magnetic resonance spectroscopy of trioxodinitrate: N-protonation of an oxoanion Calixarenes. 4. The synthesis, characterization, and properties of the calixarenes from p-tert-butylphenol Oxygenation with molecular oxygen. Thermal and photochemical epoxidation of propylene in the presence of sulfur dioxide in acetonitrile at ambient temperature Conformationally 'concerted' changes in nucleotide structures. A new description using circular correlation and regression analyses Metathesis of acetylenes by tungsten(VI)-alkylidyne complexes Reactivity-selectivity relationships. A quantum-mechanical approach to transition-state structure. Application to the SN2 reaction of benzyl derivatives Solute-solvent interactions in perfluorocarbon solutions of oxygen. An NMR study Structure of C4H4+ produced in the unimolecular fragmentation of C6H6+ and C5H5N+ Kijanimicin. 1. Structures of the individual sugar components Ethylene glycol from synthesis gas via ruthenium melt catalysis NMR and conductometric studies of 2-pyridyl-substituted carbanions. 2. Effects of cation size and coordination Organo halide addition to tris(bis(diphenylphosphino)methane)dipalladium. Preparation of novel methylene- and phenylene-bridged complexes by two-center, three-fragment oxidative addition Observation of a novel effect on the anionic inhibition of carbonic anhydrase: implications for enzymic catalysis A widely useful chiral stationary phase for the high-performance liquid chromatography separation of enantiomers X-ray photoemission from the Creutz-Taube mixed valence complex: a reassessment What happens to molecules as they react? A valence bond approach to reactivity Photochemistry of .delta.-haloketones: anchimeric assistance in triplet-state .gamma.-hydrogen abstraction and .beta.-elimination of halogen atoms from the resulting diradicals Reaction of benzene radical cation with water. Evidence for the reversibility of hydroxyl radical addition to benzene Anatomy of a complex mutarotation. Kinetics of tautomerization of .alpha.-D-galactopyranose and .beta.-D-galactopyranose in water Photochemical reactivity in organized assemblies. 18. Light-induced electron-transfer processes in anionic micelles: specific electrolyte effects on the quenching process Ligand-induced valence tautomerism in manganese-quinone complexes

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