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Picosecond laser spectroscopy of intramolecular heteroexcimer systems. Time-resolved absorption studies of p-(CH3)2NC6H4(CH2)n-1-pyrenyl and 9-anthryl systems
Photoelectron spectroscopy of f-element organometallic complexes. 4. Comparative studies of bis(pentamethylcyclopentadienyl) dichloride and dimethyl complexes of uranium(IV), thorium(IV), and zirconium(IV)
Differing behavior of pyrrolidine and piperidine as nucleophiles toward 2,4-dinitrophenyl and 2,4-dinitro-6-methylphenyl phenyl ethers
Acid-catalyzed hydrolyses of acylpyrroles and acylindoles. Noninvolvement of protonated substrates
Nitrone cycloaddition. New approach to .beta.-lactams
Direct evidence supporting a single electron transfer pathway in the reduction of ketones by primary, secondary, and tertiary Grignard reagents
Dynamics of light-induced water cleavage in colloidal systems
Unidirectional current flow and charge state trapping at redox polymer interfaces on bilayer electrodes: principles, experimental demonstration, and theory
Iron(II, III)-chlorin and -isobacteriochlorin complexes. Models of the heme prosthetic groups in nitrite and sulfite reductases: means of formation and spectroscopic and redox properties
Reactions of secondary amines with their N-(2,4-dinitro-1-naphthyl) derivatives to form Jackson-Meisenheimer adducts. Substantial difference in reaction rates between pyrrolidine and piperidine
Search for singlet oxygen in the disproportionation of superoxide anion
Nitrogen-15 chemical shift tensors in L-histidine hydrochloride monohydrate
Structural consequences of electron-transfer reactions. VI. Electronic structures and structural preferences of cyclooctatetraene- and cyclooctadiene- iron and cobalt compounds and their radical anions
Stable free radicals. 13. Reinvestigation of the pyridinyl diradical, 1,1'-trimethylenebis(4-(carbomethoxy)pyridinyl)
Electronic effects on the binding of dioxygen and carbon monoxide to hemes
Bis(triphenylphosphine) iminium nitrite, mild, versatile nitrosylating reagent
Tridentate to bidentate in a platinum(II) chelate: a 90.degree. anthranilaldehyde rotation
Does the cyclohexyl cation exist in the dilute gas state? Direct evidence from a radiolytic study
Decomposition and isomerization of bridgehead cis 1,2-diazenes (azoalkanes)
A semichelating metal-.beta.-diketonate complex
Electronic and geometric structural properties of the bare silver (Ag3) cluster and ions
Nucleophilic addition to olefins. 5. Reaction of 1,1-dinitro-2,2-diphenylethylene with water and hydroxide ion in 50% dimethyl sulfoxide-50% water. Complete kinetic analysis of hydrolytic cleavage of the C:C double bond in acidic and basic solution
Comparative NMR studies of cytochrome c and its active site octapeptide
Gold-197 Moessbauer spectroscopic data for antiarthritic drugs and related gold(I) thiol derivatives
Dinucleating octaaza macrocyclic ligands from simple imine condensations
Calculations of ground- and excited-state potential surfaces for conjugated heteroatomic molecules
Experimental chemical shift correlation maps from heteronuclear two-dimensional NMR spectroscopy. 1. Carbon-13 and proton chemical shifts of raffinose and its subunits
Stable free radicals. 12. New aspects of the behavior of 1-alkyl-4-(carboalkoxy)- and 1-alkyl-4-carbamidopyridinyl radicals in solution and in thin films
Aluminum chloride catalyzed skeletal rearrangement of permethylated acyclic polysilanes
End-to-end cyclization of hydrocarbon chains. Photochemical and computer simulation studies
Assignment of the nitrogen-15 nuclear magnetic resonances of biotin and unequivocal synthesis of (+)-[1-15N]biotin
Rhodium(I)-copper(II) catalyzed oxidation of 1-hexene by oxygen using immobilized, site-separated organosulfide complexes
Book Reviews
1-Alkyl-2-(carbomethoxy)pyridinyl radicals: monomers and dimers defined through chemical and photochemical properties and electron paramagnetic resonance
Solution and solid carbon-13 magnetic resonance study of the conformation of 9,10-dihydroanthracene and its 9,10-methylated derivatives
"Spontaneous" formation of radicals from nitroso compounds. Inadvertent photolysis vs. molecule assisted homolysis
Pressure dependence of the structure and properties of liquid n-butane
Photosensitized oxygenation of .alpha.-diazoquinone
Mechanism of the zirconium-catalyzed carboalumination of alkynes. Evidence for direct carboalumination
Rearrangement of vobasine to ervatamine-type alkaloids catalyzed by liver microsomes
The binary metal hydrido anion hexahydroferrate(4-). X-ray structural characterization
NMR studies of base-catalyzed proton exchange in amides
Bis(2,2'-bipyridyl)diisopropoxymolybdenum(II). Structural and spectroscopic evidence for molybdenum-to-bipyridyl .pi.* bonding
Effect of molecular structure on mesomorphism. 12. Flexible-center Siamese-twin liquid crystalline diesters - a "prepolymer" model
Thin-film optical spectroscopic investigations of 1-alkyl-2-(carbomethoxy)- and 2-acetylpyridinyl radical monomers and dimers
The mechanism of hemiacetal decomposition. Substituent effects in breakdown of substituted benzaldehyde ethyl hemiacetals
Preparation and reactivity of model compounds related to oligomers from thiamin. A mechanism for oligomerization
Synthesis of bridging vinylideneiron dimers using 1,1-dichlorocyclopropanes. Cyclopropenes as intermediates
Novel bay-region diol epoxides from benzo[c]phenanthrene
Volumes of complexation of cryptands with mono- and divalent cations in water and in methanol
Kinetics of reactions of cyclic secondary amines with 2,4-dinitro-1-naphthyl ethyl ether in dimethyl sulfoxide solution. Spectacular difference between the behavior of pyrrolidine and piperidine
Stereocontrolled trans and cis nucleophilic attack by acetate on .pi.-allylpalladium complexes. Applications to stereoselective palladium-catalyzed 1,4-diacetoxylation of cyclic 1,3-dienes
Carbenoid insertion reactions: formation of [4.1.1]propellane
Stereochemical analysis of .gamma.-replacement and .gamma.-elimination processes catalyzed by a pyridoxal phosphate dependent enzyme
New route to 11-oxygenated steroids
Molecular Orbital Calculations on Carbyne Complexes CpMn(CO)2CR+ and (CO)5CrCNEt2+. Frontier-Controlled Nucleophilic Addition to Metal-Carbon Triple Bond
Synthesis and characterization of a novel cholesterol nitroxide spin label. Application to the molecular organization of human high-density lipoprotein
Temperature-dependent spin-state equilibrium in aquo and hydroxo ferric heme octapeptide complexes. Model systems for the spin equilibrium of ferric hemoproteins
Acyclic stereoselection. 14. O-alkyllactic acid esters: reagents for the stereoselective construction of erythro- and threo-.alpha.-methyl-.alpha.,.beta.-dihydroxy carbonyl compounds
Synthesis and characterization of "long-chain" alkylidene-bridged hetero bimetallic complexes
Mechanisms of acid-catalyzed proton exchange in amides
Photoexcitation of nonconjugated, strained, saturated hydrocarbons. Relationship between ease of oxidation and the quenching of naphthalene fluorescence by saturated hydrocarbons
Conformational study of the tetrapeptide Boc-Arg-Ala-Gly-Glu-NHEt. A .beta. turn locked by a salt bridge
Elimination, fragmentation, and proton transfer in 1,3-dithianes and 1,3-dithiolanes in the gas phase
Structural consequences of electron-transfer reactions. 5. Electrochemically induced isomerizations of (cyclooctadiene)- and (cyclooctatetraene)cobalt compounds
Dye-sensitized photooxygenation of 4,6-di-tert-butyl-2-diazo-1,2-benzoquinone
Study of additivity of correlation and polarization effects in relative energies
The ambidentate thiocyanate ligand. Niobium-93 nuclear magnetic resonance detection of (thiocyanato)- and (isothiocyanato)niobium(V) complexes
Enzyme-catalyzed organic synthesis: NAD(P)H cofactor regeneration by using glucose-6-phosphate and the glucose-5-phosphate dehydrogenase from Leuconostoc mesenteroides
Synthesis and molecular structure of .mu.4-carbido-.mu.2-carbonyl-dodecacarbonyltetrairon, a neutral iron butterfly cluster bearing an exposed carbon atom
Regiocontrolled hydration of 2-butyne-1,4-diol derivatives to give 4,5-dihydro-3(2H)-furanones. Practical synthesis of bullatenone and geiparvarin
Dication ether salts, R+-O-R+.2CF3SO3-, from the reaction of trifluoromethanesulfonic anhydride with activated ketones
Fluorescence detected circular dichroism of proteins with single fluorescent tryptophans
Masthead
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