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Is Part Of	http://hub.abes.fr/acs/periodical/jacsat/1981/volume_103
has manifestation of work	http://hub.abes.fr/acs/periodical/jacsat/1981/volume_103/issue_23/m/print http://hub.abes.fr/acs/periodical/jacsat/1981/volume_103/issue_23/m/web
issue	23
is Is Part Of of	Production of gas-phase bare transition metal clusters by laser photodissociation of organometallic cluster compounds Semiconductor electrodes. 40. Photoassisted hydrogen evolution at poly(benzyl viologen)-coated p-type silicon electrodes Substituent effects on the aliphatic Claisen rearrangement. 1. Synthesis and rearrangement of cyano-substituted allyl vinyl ethers Synthesis and reactions of a dimetallacyclohexene. Thermal conversion to an o-xylylene complex and phosphine-induced conversion to free o-xylylene and a new reactive dinuclear cobalt complex Additions and Corrections - Isolation and Structure Elucidation of 22(S),23(S)-Methylene-Cholesterol. Evidence for Direct Bioalkylation of 22-Dehydrocholesterol Additions and Corrections - On the Question of Ground-State Perpendicular Olefins. Rehybridization of Twisted Olefins. Electrochemical investigations of compounds having isomeric forms with similar standard redox potentials: oxidation of bis(tri-n-butylphosphine)molybdenum tetracarbonyl and related complexes Kinetics and mechanism of the hydrolysis of anilide acetals Kinetic bistability in the permanganate oxidation of oxalate Efficient electron channel through self-aggregation of cytochrome c3 on an artificial membrane Oxygen chiral phosphodiesters. 5. Stereochemical course of the hydrolysis of thymidine 3'-[(4-nitrophenyl)[17O,18O]phosphate] in water (oxygen-16) catalyzed by the exonuclease from bovine spleen Diazomethane and thiobenzophenone: mechanistic elucidation of the Schoenberg reaction Additions and Corrections - Carbon-Phosphorus Heterocycles. Synthesis of Phosphorus-Containing Cannabinoid Precursors and a Single-Crystal Analysis of 1,2,3,4-Tetrahydro-10-hydroxy-8-n-pentyl-5H-phosphorus-[3,4-c[Ibenzopyran-5-one-3-Oxide]] Association of spin-labeled substrate molecules with poly(sodium 10-undecenoate) and the sodium 10-undecenoate micelle Valence ionizations of olefins coordinated to metals. Olefin dicarbonyl[.eta.5-(methyl- and pentamethyl)cyclopentadienyl]manganese complexes Heterogeneous photosynthetic production of amino acids at platinum/titanium dioxide suspensions by near ultraviolet light Rate and equilibrium constants for the formation and decomposition of the tetrahedral intermediate of the methanolysis of methyl benzoates Picosecond laser study of the adiabatic photodissociation of an endoperoxide Amino acids in the hydrolysis products of the reaction of carbon vapor with ammonia Direct evidence for solvent coordination in migratory carbon monoxide insertion Book Reviews Tris(4,5-diisopropylimidazol-2-yl)phosphine:zinc(2+). A catalytically active model for carbonic anhydrase Use of spy nuclei for relaxation studies in nuclear magnetic resonance Acenaphthyne Additions and Corrections - Absorption and Circular Dichroism Spectra of Chiral Triquinacenes Valence electronic structure of bridging methylenes: UV photoelectron spectroscopy of .mu.-methylene-bis[dicarbonyl(.eta.5-cyclopentadienyl)manganese] Locally excited triplet state production from excited charge-transfer complexes Formation constants of ion pair-ligand complexes. Application of crown ether network polymers Structures of two novel toxins from Protogonyaulax Nature of the intermediate between 4a-hydroperoxyflavin and 4a-hydroxyflavin in the hydroxylation reaction of p-hydroxybenzoate hydroxylase. Synthesis of 6-aminopyrimidine-2,4,5(3H)-triones and the mechanism of aromatic hydroxylation by flavin monooxygenases A micromethod for determining the branching points in oligosaccharides based on circular dichroism Facile regio- and stereoselective total synthesis of racemic aklavinone Cobalt(III)-mediated peptide synthesis. 1. Cobalt(III)-activated amino acid methyl esters and the synthesis of dipeptides Interaction of nickel(0) complexes with allyl carboxylates, allyl ethers, allylic alcohols, and vinyl acetate. .pi.-Complex formation and oxidative addition to nickel involving cleavage of the alkenyl-oxygen bond Thermal rearrangement of an allenic diazoalkane and intermolecular capture of a diazoethene by a cyclopropene to give a common dihydropyridazine product Binuclear ruthenium(II) porphyrins: reinvestigation of their preparation, characterization, and interactions with molecular oxygen Additions and Corrections - Chiral Perturbation of Olefins by Deuterium Substitution. The Optical Activity and Circular Dichroism Behavior of (1S)·[2-2H]Norbornene and Deuterated Apoboronenes Masthead Electroreductive alkylation of iron in porphyrin complexes. Electrochemical and spectral characteristics of .sigma.-alkylironporphyrins Crystal structures of repeating peptides of elastin. 2. N-(tert-Butoxycarbonyl)-L-valyl-L-prolylglycylglycine benzyl ester Crystal and molecular structure of [tris(4,5-diisopropylimidazol-2-yl)phosphine]dichlorozinc(II)-bis[N,N-dimethylformamide] Total synthesis of ionophore antibiotic X-14547A. 2. Coupling of the tetrahydropyran and tetrahydroindan systems and construction of the butadienyl and ketopyrrole moieties Coordination and coupling of alkylidene groups on a triosmium cluster framework. Crystal structure of Os3(CO)10(.mu.-CO)(.mu.-CHSiMe3) Novel intramolecular photorearrangement of alkane nitronate anions Additions and Corrections - Structure and Properties of Transition-Metal Ylide Complexes. 2. Organometallic Complexes of Gold(III) Additions and Corrections - Chelation of the Sodium Cation by Polyamines: A Novel Approach to Preferential Solvation, and to the Understanding of Sodium-23 Chemical Shifts and Quadrupolar Coupling Constants. Infrared multiphoton decomposition of monosilane Study of the synthesis and properties of [25](1,2,3,4,5)cyclophane Direct observation of excited state intramolecular proton transfer kinetics in 3-hydroxyflavone Thallium in organic synthesis. 61. Intramolecular capture of radical cations from thallium(III) trifluoroacetate oxidation of arylalkanoic acids and arylalkanols. New routes to oxygen heterocycles Formation of [9]- and [10]paracyclophane derivatives in cycloaddition reactions Photocatalysis. 6. Mechanism of the cyclotrimerization of trans-cycloheptene, catalyzed by copper(I) triflate Use of carbon-13 substituent chemical shifts to scale nonhydrogen-bonding dipolar interactions of protonic solvents Substituent effects on the aliphatic Claisen rearrangements. 2. Theoretical analysis Additions and Corrections - Complete Thermodynamic Analysis of the Hydration of Thirteen Pyridines and Pyridium Ions. The Special Case Of 2,6-Di-tert-butylpyridine Carbon monoxide activation by organoactinides. Migratory carbon monoxide insertion into metal-hydrogen bonds to produce mononuclear formyls Design and synthesis of a model peptide with .beta.-endorphin-like properties Transition-metal binding site of bleomycin. A synthetic analog capable of binding iron(II) to yield an oxygen-sensitive complex Novel photoisomerization of 1-acylindoles to 3-acylindolenines. General entry to the total synthesis of Strychnos and Aspidosperma alkaloids Chemical and spectroscopic properties of the binuclear copper active site in Rhus laccase: direct confirmation of a reduced binuclear type 3 copper site in type 2 depleted laccase and intramolecular coupling of the type 3 to the type 1 and type 2 copper sites Additions and Corrections - Synthesis of the Left-Hand Segment of the Antitumor Agent CC-1065 Equilibriums in solutions of nucleosides, 5'-nucleotides, and diethylenetriaminepalladium(2+) ESR detection of the dimethyl ether radical cation Additions and Corrections - Radical Anion and Radical Trianion of 1,4-Bis(dimethyl-phosphino)benzene Reversible wavelength shifts of chlorophyll induced by a point charge Novel packing material for optical resolution: (+)-poly(triphenylmethyl methacrylate) coated on macroporous silica gel Structure, properties, and transport mechanism of iron(III) complex of mugineic acid, a possible phytosiderophore Unusual sesterterpenoids from the secretion of Ceroplastes floridensis (Coccidae), an orchard pest. Application of the allylic benzoate method for determination of absolute configuration Cobalt(III)-mediated peptide synthesis. 2. Synthesis of tetrapeptides and [leu5]-enkephalin Additions and Corrections - Evaluation and Prediction of the Stability of Bridgehead Olefins. Quantitative electrochemical kinetics studies of "microelectrodes": catalytic water reduction by methyl viologen/colloidal platinum Induced optical activity and liquid crystal linear dichroism of 9,9'-spiro-bi[9H-fluorene] Effects of methyl group substitution on metal-coordinated cyclopentadienyl rings. Core and valence ionizations of methylated tricarbonyl(.eta.5-cyclopentadienyl)metal complexes Low-temperature fluorination of aerosol suspensions of hydrocarbons utilizing elemental fluorine Total synthesis of ionophore antibiotic X-14547A. 1. Enantioselective synthesis of the tetrahydropyran and tetrahydroindan building blocks Intercalation of potentially reactive transition-metal complexes in the lamellar manganese phosphide sulfide host lattice Additions and Corrections - Reversed Micelles of Aerosol-OT in Benzene. 3. Dynamics of the Solubilization of Picric Acid. Methoxymethyl-directed aryl metalation. Total synthesis of (.+-.)-averufin Electron-transfer-induced reactions. Termination steps and efficiency of the chain process in SRN1 aromatic substitutions Copper(II) hemocyanin models Solvation of ion pairs. Solvation complexes between the ion-paired 9-fluorenone anion radical and dipolar aprotic solvents Additions and Corrections - Pentaprismane Charge-transfer spectra of metallophthalocyanines: correlation with electrode potentials Chemistry of sulfenic acids. 4. The first direct evidence for the involvement of sulfenic acids in the oxidation of thiols Comparison of the capacities of the perhydroxyl and the superoxide radicals to initiate chain oxidation of linoleic acid Total synthesis of FK-156 isolated from a Streptomyces as an immunostimulating peptide: application of a novel copper chelate amino protection Photochemical formation of dihydrocarbazoles from diphenylamines and their thermal rearrangement and disproportionation reactions 24(S),25-Epoxycholesterol is a natural product of mammalian steroid biosynthesis Competitive inhibitor binding to the binuclear copper active site in tyrosinase Additions and Corrections - Spectroscopic Studies on Plastocyanin Single Crystals: A Detailed Electronic Structure Detemination of the Blue Copper Active Site

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