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Ab initio studies of (1,2)-hydrogen migrations in open-shell hydrocarbons: vinyl radical, ethyl radical, and triplet methylcarbene
Molecular generality of surface-enhanced Raman spectroscopy (SERS). A detailed investigation of the hexacyanoruthenate ion adsorbed on silver and copper electrodes
Synthesis of 3,6-disulfonated 4-aminonaphthalimides
Nucleophilic activation of carbon monoxide for reduction by hydrogen
Vibrational spectroscopy of the electronically excited state. 4. Nanosecond and picosecond time-resolved resonance Raman spectroscopy of carotenoid excited states
Kinetic and thermodynamic contributions to energy barriers and energy wells: application to proton-bound dimers in gas-phase proton-transfer reactions
Palladium-catalyzed cyclocarbonylation of acetylenic alcohols to methylene lactones. Scope and synthesis of appropriate substrates
Nuclear magnetic resonance investigation of the spontaneous decarboxylation of 2-oxalopropionic acid. 2. Species in solution
"Wolf and Lamb" reactions equilibrium and kinetic effects in multipolymer systems
Photoinduced ESR signals from the primary electron donors in deuterated highly carbon-13 enriched photosynthetic bacteria and algae
Racemization - free photochemical coupling of peptide segments
Electronic structure of the phosphenium ions PH2+, HPF+, and PF2+
Selectivity and directed charge transfer through an electroactive metallopolymer film
Anionic metal hydride catalysts. 1. Synthesis of potassium hydrido(phosphine)ruthenate complexes
Formation of monocyclic and bicyclic aza-.beta.-lactams and other novel heterocycles from 1-(diphenylmethylene)-3-oxo-1,2-diazetidinium inner salt
Cobalt(III) complex of pseudotetrapeptide A of bleomycin
Stereochemical studies on the intramolecular imino Diels-Alder reaction
Models for the coordination site of iron in cytochrome P-450. Synthesis and spectroscopic properties of a dioxygen adduct of (2,3,5,6-tetrafluorophenylthiolato)iron(II) tetraphenylpivalcylporphyrin
The central bond length in hexaphenylethane and hexakis(2,6-di-tert-butyl-4-biphenylyl)ethane
Substituent control of the poly(C)-directed oligomerization of guanosine 5'-phosphoroimidazolide
N-alkylformamidyl radicals. Identification and electronic structure
Azocyclopropane
Photochemical studies of an oleate oil in water microemulsion
Kinetics of outer-sphere electron transfers between metal complexes in solutions and polymeric films on modified electrodes
Palladium-catalyzed 1,3-oxygen-to-carbon alkyl shifts. A cyclopentanone synthesis
Regiochemistry of the reaction of chromium-carbene complexes with acetylenes
Theoretical study of the role of valence and Rydberg states in the photochemistry of ethylene
Palladium-catalyzed 1,3-oxygen-to-carbon alkyl shifts. Basic studies
Activation of molecular oxygen. Kinetic studies of the oxidation of hindered phenols with cobalt-dioxygen complexes
The structure of CC-1065, a potent antitumor agent and its binding to DNA
Oxygen-atom-transfer reactions from a carbonyl oxide (produced from a 1,2,3-trioxolane) to electron-deficient unsaturated compounds
Experimental study of the n-silicon/acetonitrile interface: Fermi level pinning and surface states investigation
Electrochemical study of the kinetics of NADH being oxidized by diimines derived from diaminobenzenes and diaminopyrimidines
Deuterium isotope effects on methyl transfer to alcohols. Possible asynchronous solvent repolarization and internal structural changes
Identification and structure of the benzene-hydrogen chloride complex from microwave spectroscopy
Stable glucopyranosylpalladium compound with a cis .beta.-hydrogen
Book Reviews
13-(Trifluoromethyl)retinal forms an active and far-red-shifted chromophore in bacteriorhodopsin
Chemistry of higher order, mixed organocuprates. 1. Substitution reactions at unactivated secondary centers
Cis-Alkylcarbamoyl radicals. The overlooked conformer
Vanadium-catalyzed epoxidations. 2. Highly stereoselective epoxidations of acyclic homoallylic alcohols predicted by a detailed transition-state model
Localized molecular orbital studies of three-, four-, five-, and six-membered ring molecules and ions formed from sulfur and nitrogen
Theoretical studies of SN2 transition states. 1. Geometries
Heterogeneous one-electron reduction of metal-containing biological molecules using molecular hydrogen as the reductant: synthesis and use of a surface-confined viologen redox mediator that equilibrates with hydrogen
Theoretical studies of SN2 transition states. 2. Intrinsic barriers, rate-equilibrium relationships, and the Marcus equation
Homogeneous catalysis of the electrochemical reduction of dioxygen by a macrocyclic cobalt(III) complex
Synthesis and characterization of the pentacarbonylmanganese(0) radical, Mn(CO)5, in low-temperature matrixes
Photochemical hydroformylation of olefins with cobalt catalysts. 2. Ionic cobalt carbonyls
First evidence for the existence of intramolecular carbon-hydrogen-carbon hydrogen bonds: carbanions of [1.1]ferrocenophane, 1-methyl-[1.1]ferrocenophane, and 1,12-dimethyl-[1.1]ferrocenophane
Masthead
Organometallic electron reservoirs. 5. Novel mode of carbon-hydrogen activation using dioxygen via superoxide radical anion in solution and in the solid state with C5R5FeIC6R'6. Subsequent bond formation with carbon, silicon, phosphorus, manganese, iron, chromium, and molybdenum
Photochemical hydroformylation of olefins with cobalt catalysts. 1. Neutral cobalt carbonyls
Synthesis of stabilized phenyltin(II) compounds: inhibition of the conversion to tin(IV) by substitution
Gas-phase ion-molecule reactions of cyclopentadienyl anion (c-C5H5-)
Selective symmetric and asymmetric palladium-catalyzed dimerizations of pyrimidinylmercuric salts
Molecules in an electric field. Model for molecular geometry
Novel thermal-catalyzed isomerization of certain substituted 1,2,6-triphenyl-4-phosphorinanones. Stereochemical and conformational analysis of substituted 1,2,6-triphenyl-4-phosphorinanones and 2,6-diphenyl-4-thianones via ultraviolet spectrometry, carbon-13 NMR spectroscopy, and liquid crystal circular dichroism spectropolarimetry
Stereochemistry of an alkoxide-accelerated [1,3] migration
Base catalysis in a photochemical Smiles rearrangement. A case of general base catalysis of a photoreaction
Coupled fragment molecular orbital method for interacting systems
Homolytic substitution at carbon: 1,3- and 1,5-ring closures in organotin-substituted radicals
Ketone methylenation with optical resolution. Total synthesis of the ginseng sesquiterpene (-)-.beta.-panasinsene and its enantiomer
Vibrational spectroscopy of the electronically excited state. 5. Time-resolved resonance Raman study of tris(bipyridine)ruthenium(II) and related complexes. Definitive evidence for the "localized" MLCT state
Cell-free biosynthesis of penicillins. Conversion of peptides into new .beta.-lactam antibiotics
Heteropolypentatungstobisphosphonates. Cyclopentane-like pseudorotation of an oxometalate structure
A unique stereospecific [.pi.2s + .sigma.2a] cycloaddition of tetracyanoethylene to substituted cyclopropanone acetals
Association of alkali and alkaline earth cations with benzo-18-crown-6 and its neutral and negatively charged acyclic analogs in methanol solution
Anionic metal hydride catalysts. 2. Application to the hydrogenation of ketones, aldehydes, carboxylic acid esters, and nitriles
3-Oxo-1,2-diazetidinium tosylate
Synthesis and structure of triphenylphosphinegold-dodecacarbonyltricobaltiron ([FeCo3(CO)12AuPPh3]): a trimetallic trigonal-bipyramidal cluster. Gold derivatives as structural analogs of hydrides
Oxygen-17 ENDOR of horseradish peroxidase compound I
Stereospecific reactions of dichloroketene with vinyl sulfoxides: a new type of polar cycloaddition
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