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Deuterium nuclear quadrupole resonance spectra of nonlinear hydrogen bonds
Higher coordinate cyanide and isocyanide complexes. 15. Reductive coupling of coordinated alkyl isocyanides in seven-coordinate molybdenum(II) and tungsten(II) complexes. Removal of the coupled ligand as an oxamide
Generation of 2-(trimethylsiloxy)allyl cations and their reactions with 1,3-dienes. Change in mechanism of 3 + 4 .fwdarw. 7 cycloaddition with solvent
New methods for alkaloid synthesis: .alpha.-acylamino radical cyclizations
Relative binding energies of organic molecules to manganese(+) ion in the gas phase
Proton-induced disproportionation of superoxide ion in aprotic media
Regiocontrolled coupling of (.pi.-allylic)palladium complexes with organozirconium species
Structures of the 1:1 complexes of 18-crown-6 with hydrazinium perchlorate, hydroxylammonium perchlorate, and methylammonium perchlorate
A new thermal rearrangement in the 4-isoxazoline system. Some chemical and stereochemical properties of a benzodiazepine oxide-ethyl propiolate adduct
A Diels-Alder route to pyridone and piperidone derivatives
Oxidation of substituted alkyl radicals by hexachloroiridate(2-), hexacyanoferrate(3-), and permanganate ions in aqueous solution. Electron transfer versus chlorine transfer from hexachloroiridate(2-) ion
Transient protection: efficient one-flask syntheses of protected deoxynucleosides
Complete kinetic analysis of the thermal stereomutations of (+)-(1S,2S,3R)-r-1-cyano-t-2-methyl-1,2,t-3-trideuteriocyclopropane
Use of large magnetic fields to probe photoinduced electron-transfer reactions: an example from photosynthetic reaction centers
Photodissociation study of C6H6O+.cntdot. ions in an ion cyclotron resonance spectrometer
Reactions of aluminum(+) and magnesium(+) ions with alcohols and organic halides in the gas phase
Ab initio calculations of the relative energies of triplet 2,4-dimethylenecyclobutane-1,3-diyl and singlet 2,4-dimethylenebicyclo[1.1.0]butane
Aluminum atom-ethylene and aluminum atom-acetylene complexes: matrix isolation electron spin resonance study
Pyranose benzoates: an additivity relation in the amplitudes of exciton-split CD curves
Acid-base and tautomeric equilibriums in the solid state: nitrogen-15 NMR spectroscopy of histidine and imidazole
"Mercaptan-tail" porphyrins: synthetic analogs for the active site of cytochrome P-450
Model studies of terpene biosynthesis. Intermolecular 1'-2 electrophilic condensation of 3-methyl-2-butenyl acetate
Stereospecific alkyl group effects on amine lone-pair ionization potentials: photoelectron spectra of alkylpiperidines
Secondary ion mass spectrometry of metal halides. 2. Evidence for structure in alkali iodide clusters
Fe2(.mu.2-E2)(CO)6 (E = sulfur, selenium, and tellurium) as reagents for the preparation of mixed-metal chalcogenide clusters
1,2,5-Thiadiazole 1-oxides. 3. An experimental and theoretical investigation of the inversion barrier
Role of the protein outside active site on the diffusion-controlled reaction of enzymes
Ionization energies of p-quinodimethan and 2,5-dimethyl-p-quinodimethan
Theoretical study of the chromium-chromium quadruple bond
The state of lithium tetraphenylborate, lithium picrate, and sodium picrate dissolved in 1,2-dichloroethane containing one of several phase-transfer catalysts
Ligand additivity: applications to the electrochemistry and photoelectron spectroscopy of d6 octahedral complexes
Biosynthesis of the pyrrolidine rings of cocaine and cuscohygrine from [5-14C]-ornithine via a symmetrical intermediate
An ab initio molecular orbital study of the rearrangement of .alpha.-disulfoxide to thiosulfonate
Origins of inhomogeneous broadening in the vibronic spectra of visual chromophores and visual pigments
Direct determination of rate constants of slow dynamic processes by two-dimensional "accordion" spectroscopy in nuclear magnetic resonance
Stable carbocations. Part 236. A carbon-13 and silicon-29 NMR spectroscopic study of .alpha.- and .beta.-(trimethylsilyl)-substituted carbocations
Coronation of ligating acetonitrile by 18-crown-6. X-ray crystal structure of {[trans-Ir(CO) (CH3CN)(PPh3)2]2+.18-crown-6}[PF6]2-.2CH2Cl2
Kinetic and thermodynamic acidity of hydrido transition-metal complexes. 1. Periodic trends in Group VI complexes and substituent effects in osmium complexes
Dienophilic thioaldehydes
One and two electron reduction of oxygen by 1,5-dihydroflavins
Masthead
The effects of solvent on axial ligation constants of a cobalt(II) porphyrin
Preparation and molecular and electronic structures of cyclo-1.lambda.5-phospha-3,5-dithia-2,4,6-triazenes and their norbornadiene adducts
Model studies of terpene biosynthesis. Stereospecific cyclization of N-methyl-(S)-4-([1'-2H]neryloxy)pyridinium methyl sulfate to .alpha.-terpineol
Ruthenium-catalyzed oxygenation of catechols to muconic acid anhydrides and 2H-pyran-2-ones. Intradiol and extradiol cleavage of carbon-carbon bond
Stereocontrolled total synthesis of Antibiotic A-23187 (calcimycin)
Direct reduction of acetylene at molybdenum modified polymeric sulfur nitride, (SN)x, electrodes
Relative binding energies of organic molecules to aluminum(+) ion in the gas phase
Homolysis and acidolysis reactions of (.alpha.-hydroxyalkyl)- and (.alpha.-alkoxyalkyl)chromium(III) complexes: kinetics, steric effects, and bond energies
Design and synthesis of an amphoteric four-stage redox hydrocarbon bearing phenalenyl moieties. 1,2-Bis(phenalen-1-yliden)ethane
Photooxygenation via electron transfer. 1,1-Dimethylindene
Nucleophilic displacements on phosphoric monoesters: stereochemical evidence
Reactivities of ruthenium cluster anions: implications for catalysis of the water-gas shift reaction
Oxidation of mandelic acid by Fenton's reagent
Reactions of the monomeric metaphosphate anion generated from different sources
Silylene rearrangements in the reactions of recoiling silicon atoms with trimethylsilane
Biosynthesis of sulfur compounds. Investigations of the biosynthesis of asparagusic acid
Macro rings. 48. Transannular effects of acidity of heteroannularly disubstituted [2.2.] paracyclophane
N,N'-Bridged porphyrins. Novel synthesis, metal complexes, and conversion into N-monosubstituted porphyrins. Crystal structure of [N,N'-[(benzyloxy)methylene]tetraphenylporphyrin-N'',N''']dibromopalladium(II)
Oxidation-reduction mechanisms. Inner-sphere and outer-sphere electron transfer in the reduction of iron(III), ruthenium(III), and osmium(III) complexes by alkyl radicals
Thiamin catalysis. 2. Kinetics and mechanism of the generation of the yellow form of thiamin
Kinetic and structural studies on the intermediates formed in the reactions of 5'-adenosine monophosphate and 5'-guanosine monophosphate with cis-dichlorodiammineplatinum(II) using proton and platinum-195 magnetic resonance spectroscopy
Model studies of terpene biosynthesis. A stepwise mechanism for cyclization of nerol to .alpha.-terpineol
"Open-face" macrobicycles as tunable binucleating ligands. Design, synthesis and dicopper(II) complexes
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