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Is Part Of	http://hub.abes.fr/acs/periodical/jacsat/1983/volume_105
has manifestation of work	http://hub.abes.fr/acs/periodical/jacsat/1983/volume_105/issue_6/m/print http://hub.abes.fr/acs/periodical/jacsat/1983/volume_105/issue_6/m/web
issue	6
is Is Part Of of	Cluster synthesis. 1. The use of sulfido ligands in the synthesis of high nuclearity transition metal cluster compounds. The synthesis and crystal and molecular structures of Os6(CO)17(.mu.4-S)2 and Os6(CO)16(.mu.4-S)(.mu.3-S) Metal-ion catalysis of anhydride hydrolysis. Metal-ion-promoted water- and hydroxide-ion-catalyzed reactions of mixed cinnamic acid anhydrides Titanium-induced cyclization of keto esters: a new method of cycloalkanone synthesis Synthetic applications of titanocene methylene complexes: selective formation of ketone enolates and their reactions Convenient direct synthesis of (SN)x films from S4N4 at lower temperatures Masthead Absorption spectra and photochemical rearrangements of toluene, cycloheptatriene, and norbornadiene cations to methylenecyclohexadiene cation in solid argon Carbenes and the oxygen-hydrogen bond: 3-cyclopentenylidene. A novel approach to bis(homocyclopropenyl) cations Silicon-29 NMR study of dehydrated/rehydrated silica gel using cross polarization and magic-angle spinning Spin trapping of peroxy radicals by phenyl N-(tert-butyl) nitrone and methyl N-duryl nitrone Photoreduction of keto carboxylic acid derivatives to oxyacid derivatives catalyzed by ZnTPPS[zinc tetraphenylporphyrintetrasulfonate]-quinolinium-3-carboxamide-CTAB micelle Tandem mass spectrometry: structural and stereochemical information from steroids Isolation and characterization of two new bacteriochlorophylls d bearing neopentyl substituents Applications of molybdenum-95 NMR spectroscopy. 7. Studies of metal-metal bonded systems including aqueous molybdenum(IV) and molybdenum(V). Crystal and molecular structure of Na2[Mo3O4((O2CCH2)2NCH3)3].7H2O Sequential assignments for the hydrogen and phosphorus-31 atoms in the backbone of oligonucleotides by two-dimensional nuclear magnetic resonance An unsymmetrically substituted diphosphene: NMR spectroscopic data pertinent to the phosphorus-phosphorus double bond MCSCF/CI investigation of the low-lying potential energy surfaces of the formyloxyl radical, HCO2.cntdot. Magnetic field and magnetic isotope effects on photoinduced emulsion polymerization Host recognition in parasitic angiosperms: use of correlation spectroscopy to identify long-range coupling in an haustorial inducer Preparation and properties of molybdenum and tungsten dinitrogen complexes. 18. Preparation and characterization of novel .mu.3-dinitrogen mixed metal complexes Laser photodissociation of nitrogenous bases from pentacoordinated cobalt(II) porphyrins Toward tricyclo[2.2.2.2]decane. 1. [n.2.2.2]Paddlane systems, n = 10-14 Crystal structure and solid-state reactivity of 4,4'-methylenediphenyl isocyanate (MDI) Evidence for a perepoxide intermediate in the 1,2-cycloaddition of singlet oxygen to adamantylideneadamantane: nucleophilic oxygen atom transfer to sulfoxides Cofacial assembly of partially oxidized metallamacrocycles as an approach to controlling lattice architecture in low-dimensional molecular solids. Chemical and architectural properties of the "face-to-face" polymers [M(phthalocyaninato)O]n, where M = Si, Ge, and Sn Novel reaction of metal-metal triple-bonded complexes and nitro compounds. Decarbonylation and the formation of high oxidation state molybdenum and tungsten complexes bearing bridging and terminal oxygen ligands Evidence for a silylenium ion in solution Correlated rotation in bis(9-triptycyl)methanes and bis(9-triptycyl) ethers. Separation and interconversion of the phase isomers of labeled bevel gears Stereospecific synthesis of racemic daunosamine. Diastereofacial selectivity in a nitrone cycloaddition La coupe du roi and its relevance to stereochemistry. Combination of two homochiral molecules to give an achiral product Cofacial assembly of partially oxidized metallamacrocycles as an approach to controlling lattice architecture in low-dimensional molecular solids. Chemical, structural, oxidation state, transport, magnetic, and optical properties of halogen-doped [M(phthalocyaninato)O]n macromolecules, where M = Si, Ge, and Sn Photoinduced reaction. 142. Intramolecular hydrogen abstraction from triplet states of 2,4,6-triisopropylbenzophenones: importance of hindered rotation in excited states Mechanistic studies of unimolecular ionic decompositions by deuterium and heavy-atom isotope effects. Concerted elimination of acetaldehyde from the benzyl ethyl ether radical cation Rearrangement of 4,4-diarylcyclohexadienones induced by attack of methyl metaphosphate at the carbonyl group Total synthesis of (.+-.)-chaenorhine Heavy-atom tunneling as the dominant pathway in a solution-phase reaction? Bond shift in antiaromatic annulenes Quantum and statistical mechanical studies of liquids. 25. Solvation and conformation of methanol in water Nonlinear fluorescence quenching and the origin of positive curvature in Stern-Volmer plots Reversible nitrogen-nitrogen bond homolysis in tetrakis(trifluoromethylthio)hydrazine at room temperature. Electron spin resonance, thermodynamic, and kinetic results Optically active amines. 31. Spectral observations on the substituted benzene chromophore Flash EXAFS for structural analysis of transient species: rapidly melting aluminum Intramolecular general base-acid catalysis in transaminations catalyzed by pyridoxamine enzyme analogs Electron-transfer reactions and associated conformational changes. Electrochemical reduction of some vicinal dibromides Cyclic phosphonic-carboxylic imides and anhydrides as reactive intermediates. 1. Rearrangement and solvolysis of N-(amino(methyl)phosphinyl)-L-phenylalanine derivatives Preparation and reactivity of a dimeric ruthenium .mu.-methylene complex with no metal-metal bond: crystal and molecular structure of [(.eta.5-C5H5)Ru(CO)2]2(.mu.-CH2) Detection of a tetrahedral adduct in a trypsin-chloromethyl ketone specific inhibitor complex by carbon-13 NMR Dynamic gearing and residual stereoisomerism in labeled bis(9-triptycyl)methane and related molecules. Synthesis and stereochemistry of bis(2,3-dimethyl-9-triptycyl)methane, bis(2,3-dimethyl-9-triptycyl)carbinol, and bis(1,4-dimethyl-9-triptycyl)methane Oxygen-18 isotope effect in carbon-13 nuclear magnetic resonance spectroscopy. 7. Hydrolysis of 2,2-dimethyloxirane in dilute acid and by microsomal epoxide hydratase 2,2-Dimethylpropanethial: a long-lived aliphatic thioaldehyde Book Reviews Conformational dynamics of propane, di-tert-butylmethane, and bis(9-triptycyl)methane. An analysis of the symmetry of two threefold rotors on a rigid frame in terms of nonrigid molecular structure and energy hypersurfaces Tris(dialkylamino)sulfonium enolates. Synthesis, structure, and reactions Cyclic phosphonic-carboxylic imides and anhydrides as reactive intermediates. 2. Solvolysis of N-(hydroxy(methyl)phosphinothioyl)-L-phenylalanine derivatives Rotational excitation in the carbon monoxide product of ketene photodissociation Synthesis, structure, and photochemistry of tetracarbonyl(fulvalene)diruthenium. Thermally reversible photoisomerization involving carbon-carbon bond activation at a dimetal center Unique high-spin-low-spin transition of the central ion in a linear, trinuclear iron(II) triazole compound Carbon-13 nuclear magnetic relaxation in carbon-13 uniformly enriched glycine and aspartic acid Intramolecular electron transfer in a series of mixed-valence copper(II)-copper(I) complexes Kinetic features of an intraresin reaction A new approach to asymmetric synthesis of polycycles on the basis of o-quinodimethane generation A cyclic phosphate: base and metal acetate catalyzed ring opening Equilibration of 1-octanol with alcohol dehydrogenase. Evidence for horse liver alcohol dehydrogenase responsibility for exchange of the 1-pro-S hydrogen atom Aryl isomerization during aliphatic carbon-hydrogen bond activation Highly reduced organometallics. 13. Synthesis and chemistry of the tricarbonylnitrosylmanganate(2-) ion, Mn(CO)3NO2- On the thickness of hydrophobic bilayers Molecular structure of acetylacetone. A crystallographic determination Stereocontrolled synthesis of a cis-carbapenem antibiotic (-)-carpetimycin A Acyclic stereoselection. 16. High diastereofacial selectivity in Lewis acid mediated additions of enol silanes to chiral aldehydes Mechanisms of ligand binding to pentacoordinate protoheme An improved route to 4-demethoxydaunomycinone. A-Ring functionalization and resolution studies of tetracyclic precursors Thermal sigmatropic rearrangements of vinylallenes leading to 11-cis-retinoids and the novel properties of 9-cis,11-cis,13-cis-retinal and 11-cis,13-cis-retinal Tandem mass spectrometry of higher molecular weight compounds Total synthesis of the major human urinary metabolite of prostaglandin D2, a key diagnostic indicator Phosphine ligands for the construction of polynuclear complexes. I. Bis(diphenylphosphinomethyl)phenylphosphine complexes of palladium(II) and rhodium(I) Genesis, bonding mode and reaction with carbon monoxide of an oxymethylene unit bridging two metal atoms Argon-matrix isolation of bis(trifluoromethyl)oxirene, perfluoromethylethyloxirene, and their isomeric ketocarbenes

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