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Induced internal redox processes in molybdenum-sulfur chemistry: conversion of tetrathiomolybdate(2-) ion to octathiodimolybdate(2-) ion by organic disulfides
Study of hydrogen atom abstraction reactions of triplet diphenylcarbene in solution
Photoelectron spectroscopic study of the ground states of chloromethyl(+), dichloromethyl(+), and chlorofluoromethyl(+) cations
Reactions of polyanions derived from alkylbenzenes
Masthead
Intramolecular exciplex emission from aqueous .beta.-cyclodextrin solutions
Infrared spectrum and photochemistry of methoxychlorocarbene
Absolute rate constants for the reactions of tributylgermyl and tributylstannyl radicals with carbonyl compounds, other unsaturated molecules, and organic halides
A tandem cycloaddition-ene strategy for the synthesis of (.+-.)-verrucarol and (.+-.)-4,11-diepi-12,13-deoxyverrucarol
Synthesis, structure, and magnetic properties of catena-(.mu.-oxo)(hemiporphyrazinato)iron(IV), the first polymeric .mu.-oxo-bridged complex of iron
The .alpha. vs. .beta. protonation of pyrrole and indole
Monte Carlo simulation of the influence of solvent on nucleic acid base associations
Self-diffusion of water at the protein surface: a measurement
Aluminum alkyls and transition metal hydrides: "nonclassical" adduct structure and catalysis of hydrogen migration
The pKa and keto-enol equilibrium constant of acetone in aqueous solution
Structures of nickel(II) and cobalt(II) carboxypeptidase A
Solid-state formation of quinhydrones from their components. Use of solid-solid reactions to prepare compounds not accessible from solution
Synthesis and characterization of a new polyquinone exhibiting a two-electron, single-wave reduction
Conformation and dynamics of the 8 substituted deoxyguanosine 5'-monophosphate adduct of the carcinogen 2-(acetylamino) fluorene
Conservation of triplet spin polarization in the energy transfer between triplet carbonyl compounds and aromatic hydrocarbons in glassy matrixes. A time-resolved electron spin resonance study
Application of Marcus theory to metal ion catalyzed group transfer reactions
Characterization of the first examples of isolable molecular hydrogen complexes, M(CO)3(PR3)2(H2) (M = molybdenum or tungsten; R = Cy or isopropyl). Evidence for a side-on bonded dihydrogen ligand
NOC approach to spiroketals. A total synthesis of (.+-.)-talaromycin B
Catalytic incorporation of carbon monoxide into a ketonic carbon. Conversion of cyclobutanones to disiloxycyclopentenes with hydrosilane and carbon monoxide in the presence of cobalt carbonyl
Single-crystal polarized electronic absorption spectrum and ligand-field interpretation of the bonding of Zeise's salt
Silanes in organic synthesis. 21. Configurational stability of the 2,2-diphenyl-1-(trimethylsilyl)cyclopropyl carbanion and free radical. Absolute stereochemical assignments to select silylcyclopropanes
Conformational analysis. 45. Syn-axial methyl/phenyl and gauche methyl/methyl interactions
Synthesis of neutral ruthenium formyls by hydride transfer from triphenylphosphinehydridocopper ([Ph3PCuH]6). Evidence for a radical-initiated decomposition of neutral formyl complexes
Oxygen-17 NMR and oxygen-18-induced isotopic shifts in carbon-13 NMR for the elucidation of a controversial reaction mechanism in carbohydrate chemistry
Chemistry of new heteronuclear bridging hydrides: (.mu.-H)[Fe(CO)4M(CO)5]- (M = chromium, molybdenum, or tungsten)
Photodimerization of Lewis acid complexes of cinnamate esters in solution and the solid state
Dissociation dynamics of energy-selected hexamethyldisilane ions and the heats of formation of trimethylsilyl(1+) ion ((CH3)3Si+) and trimethylsilyl radical ((CH3)3Si)
Mechanism of phosphine photolysis. Application to Jovian atmospheric photochemistry
Anthracycline synthesis with Fischer carbene complexes
Heterocycles in synthesis: chiral amino acids/dipeptides via a novel photooxidative cleavage of trisubstituted imidazoles
Electronic structure of 3,7-diphenyl- and 3,7-bis(dimethylamino)-1,5-dithia-2,4,6,8-tetrazocines: ab initio calculations and photoelectron spectra
Nickel-promoted thermal dimerization of 1-phenyl-3,4-dimethylphosphole: the first synthesis of a diphospholene
Atropisomerism in metal chelates. Preparation and partial resolution of (3,4-diacetyl-2,5-hexanedionato)bis[(2,2',2"-triaminotriethylamine)cobalt(III)] ion
A general procedure for assigning the phosphorus-31 spectra of nucleic acids
Steric effects of bridgehead carbons which are .alpha. to carbonyls
Reactions of benzvalene with tetracyanoethylene, 2,3-dichloro-5,6-dicyano-p-benzoquinone, chlorosulfonyl isocyanate, and sulfur dioxide. Evidence for concerted 1,4-cycloadditions to a vinylcyclopropane system
Photolysis of 3-chlorodiazirine in the presence of alkenes. Kinetic evidence for intervention of a carbene-alkene intermediate in addition of chlorocarbene to alkene
Solubility properties in polymers and biological media. 4. Correlation of octanol/water partition coefficients with solvatochromic parameters
The ionic hydrogen bond. 4. Intramolecular and multiple bonds. Protonation and complexes of amides and amino acid derivatives
Relevance to Synthetic Polynuclear Chemistry of Novel μ3-Coordination Modes for the Anions Ph2PCHCOOC2H2- and Mo(CO)3Cp-. Synthesis and X-ray Structure of Pd(8-mq)Br(Ph2PCH2COOC2H5), {[Pd(8-mq)]3(μ3-Ph2PCHCOOC2H5)(μ3-OH)}PF6, and {[Pd(8-mq)]3 [μ3-Mo(CO)3Cp](μ3-Cl)}BF4
Unprecedented asymmetric induction from a chiral acetate enolate equivalent. The condensation of acetyl(triphenylphosphine)carbonyl-.eta.-cyclopentadienyliron [(.eta.-C5H5)Fe(CO)(PPh3)(Ac)] with imines
Efficient catalytic asymmetric alkylations. 1. Enantioselective synthesis of (+)-indacrinone via chiral phase-transfer catalysis
Crystal and molecular structure of an N-arylporphyrin complex: chloro(N-phenyl-5,10,15,20-tetraphenylporphinato)zinc(II)
Total synthesis of bongkrekic acid
Geometric effects of reduction of dimensionality in interfacial reactions
Intermetallic charge-transfer spectra of copper(I)-metal(III) centers in doped crystals of cesium trichloromagnesate (CsMgCl3)
1H-Cycloprop[b]anthracene
The 2s + 2s reactions at transition metals. 1. The reactions of deuterium with dichlorohydrotitanium(1+) ion (Cl2TiH+), titanium hydrogen dichloride (Cl2TiH), and scandium hydrogen dichloride (Cl2ScH)
A general procedure for assigning the phosphorus-31 spectra of nucleic acids
Laser pH-jump initiated proton transfer on charged micellar surfaces
Localization and transfer of protons between nitrogen-15 atoms of meso-tetraphenylporphine probed by nuclear Overhauser effects and dipole-dipole relaxation times
Formation of thermalized singlet silylene in the reactions of recoiling silicon atoms
Synthesis and thermal isomerization of a cyclobuta[d]naphthalenone
Is tetramethylene an intermediate?
N-Fluoro-N-alkylsulfonamides: useful reagents for the fluorination of carbanions
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