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Is Part Of	http://hub.abes.fr/acs/periodical/jacsat/1985/volume_107
has manifestation of work	http://hub.abes.fr/acs/periodical/jacsat/1985/volume_107/issue_18/m/print http://hub.abes.fr/acs/periodical/jacsat/1985/volume_107/issue_18/m/web
issue	18
is Is Part Of of	Barriers to rotation adjacent to double bonds Stereochemical study of 1,2,3,4,5,6-(hexamethoxycarbonyl)cyclohexanes Ternary complexes of solution. 48. Influence of organic solvents on intramolecular aromatic-ring stacks in aqueous mixed-ligand metal ion complexes. Opposing solvent effects Artificial allosteric systems. 3. Cooperative carbon monoxide binding to diiron(II)-gable porphyrin-diimidazolylmethane complexes Intramolecular carbon-hydrogen insertion: synthesis of (.+-.)-pentalenolactone E methyl ester 1,3-Ditungstacyclobutadienes. 1. Reactions with alkynes. Alkyne adducts and 1,3-dimetallaallyl derivatives Model copolymerization reactions. Direct observation of a "penultimate effect" in a model styrene-acrylonitrile copolymerization Toward a master equation for predicting heterolysis energies of carbon-carbon bonds in solution Flash vacuum pyrolysis of organomanganese pentacarbonyl compounds Onium ions. 32. Intermediacy of the parent diazonium ion (protonated dinitrogen, N2+H) in the diazotization of ammonia and its derivatives with nitrosonium tetrafluoroborate (15NO+BF4-) giving 15N14N+ Electrochemical permeability control through a redox bilayer film Oxidative fragmentation of .beta.-stannyl oximes: stereospecific formation of unsaturated nitrile oxides Synthesis of 1,1-dilithio-2,2,3,3-tetramethylcyclopropane Book Reviews Some aspects of the triplet di-.pi.-methane rearrangement: comparison of the ring opening of cyclopropyldicarbinyl and cyclopropylcarbinyl Multiphoton infrared laser activation of organometallic species: a novel probe of the potential energy surfaces for reactions of cobalt ions with C5H10 isomers Reactions of coordinated dinitrogen. 16. New mono-dinitrogen complexes of molybdenum that produce ammonia and hydrazine Analysis of the interaction of haloenol lactone suicide substrates with .alpha.-chymotrypsin using computer graphics and molecular mechanics Metal ion complexation by rhodium and iridium metallomacrocycles. The preparation and x-ray crystal structures of Rh2(CO)2Cl2(.mu.-Ph2PCH2As(Ph)CH2PPh2)2 and [Rh2Pd(CO)2Cl3(.mu.-Ph2PCH2As(Ph)CH2PPh2)2][BPh4] Photoinduced reactions. 163. Trimethylsilyl cyanide as a trapping agent for dipolar peroxide intermediates Condensation of aldehydes with .mu.-alkylidyne diiron complexes: a new synthesis of .mu.-vinylcarbyne complexes Diethoxytriphenylphosphorane: a mild, regioselective cyclodehydrating reagent for conversion of diols to cyclic ethers: stereochemistry, synthetic utility, and scope A novel synthesis of metacyclophanes. Thermal and DDQ induced aromatization of bridgehead dienes Ozonolysis of olefins adsorbed on polyethylene: a new access to ozonides by cycloadditions of carbonyl oxides to ketones Oxidative dimerization of methane over a lithium-promoted magnesium oxide catalyst Total synthesis of the cytochrome P-450 epoxygenase metabolites 5(R),6(S)-, 5(S),6(R)-, and 14(R),15(S)-epoxyeicosatrienoic acid (EET) and hydration products 5(R),6(R)- and 14(R),15(R)-dihydroxyeicosatrienoic acid (DHET) Phosphine oxides and lithium aluminum hydride-sodium borohydride-cerium(III) chloride: synthesis and reactions of phosphine-boranes Additions and Corrections - A Method for the Analysis of Puckering Disorder in Five-Membered Rings: The Relative Mobilities of Furanose and Proline Rings and Their Effects on Polynucleotide and Polypeptide Backbone Flexibility Ab initio heats of formation of medium-sized hydrocarbons. 3. The valence isomers of benzene Kinetics and mechanism of the hydrolysis of acyclic oxyphosphonium salts Sensitized photooxygenation. 1. Reaction of singlet oxygen with 3,4-dihydro-6-methyl-2H-pyran-5-carboxylic acid ethyl ester. Isolation of hydroperoxides and evidence of their transformation to dioxetane Organometallic "electron reservoirs". 23. 36-40 Electron complexes (C6R6FeCp-CpFeC6R6).+-.n (R = H, Me; n = 0-2) and the first delocalized mixed valence complexes containing iron(I) Moessbauer effect study of triiron dodecacarbonyl and the reduced carbide clusters (PPN)[Fe3(CO)10CH], (PPN)2[Fe3(CO)9CCO], and (PPN)[Fe2Co(CO)9CCO] Construction of linear-fused tricyclopentanoids by intramolecular [6 + 2] cycloadditions of fulvenes with enamines MNDO calculations of ions in chloroaluminate molten salts Long range photoinduced electron transfer in a rigid polymer The unusual reactions of singlet oxygen with isomeric 1,4-di-tert-butoxy-1,3-butadienes. A 2S + 2a cycloaddition A theoretical evaluation of the mechanism of acetylene formation in the reactions of atomic carbon with hydrocarbons Vinyl cations. 42. Synthesis and solvolysis of substituted 1-cyclobutenyl nonaflates Isolation and structure of tunichrome B-1, a reducing blood pigment from the tunicate Ascidia nigra (Linnaeus) Total synthesis of (.+-.)-tirandamycin A Ground term splitting of high-spin cobalt(2+) ion as a probe of coordination structure. 1. Dependence of the splitting on coordination geometry Design of molecular assembly of diphenylcarbenes having ferromagnetic intermolecular interactions Supermonomolecular structure in the Langmuir-Blodgett films of a surface-active dye-fatty acid mixed system Duality of mechanism, radical and nonradical, in the dehalogenation of aryl halides by lithium 2,6-dimethylpiperidide A first example of generating aryl cations in the solvolysis of aryl triflates in trifluoroethanol 2s + 2s Reactions at transition metals. Part 3. Dichlorotitanacyclopropane. The structure and reactivity of a metallacyclopropane Surface photochemistry: cadmium sulfide-mediated dimerization of phenyl vinyl ether. The dark reaction Conformation, bonding, and flexibility in short-chain linear phosphazenes Oxyphosphorane hydrolysis. Reversible ring opening of spirophosphoranes containing six-atom rings Organic synthesis using haloboration reaction. Part 7. A stereospecific synthesis of (Z)-.delta.-halo-.gamma.,.delta.-unsaturated ketones via haloboration reaction of terminal alkynes Additions and Corrections - Nonlinear Fluorescence Quenching and the Origin of Positive Curvature in Stern-Volmer Plots Ground term splitting of high-spin cobalt(2+) ion as a probe of coordination structure. 2. The ligand environment of the active site metal ion of carboxypeptidase A in ester hydrolysis Synthesis, insertion and reductive elimination reactions of a hydrido(alkoxy)iridium complex An ab initio molecular orbital study on rearrangement/fragmentation processes of isomeric CH3N+.bul. ions The uncatalyzed Claisen rearrangement of chorismate to prephenate prefers a transition state of chair-like geometry Additions and Corrections - Determination of Adsorption Conformation from Surface Resolution Analysis A lipophilic salt of a transition-metal polyhydride: KOsH3(PMe2Ph)3 Ultrasound-promoted selective perfluoroalkylation on the desired position of organic molecules A logic-based program for synthesis design Diastereotopic selectivity at prochiral carbon centers: functionalization of differentiated hydroxymethyl groups provides access to either stereoisomeric configuration Stepwise metal-assisted conversion of carbon diselenide to diselenium and carbon dioxide. Novel bonding mode of the diselenium molecule in the double-Se2-bridged complex [(triphos)Rh(.mu.-Se2)2Rh(triphos)](BPh4)2.2DMF Kinetics and mechanism of the acid hydrolysis of mitomycins Stabilization of the phenyl cation by hyperconjugation Total synthesis of (+)-11,11'-di-O-methylelaiophylidene, an aglycon of elaiophylin Diastereoselection and the influence of chiraphos on metal-centered chirality in cis oxidative addition of hydrogen and triphenylsilane Contribution from microwave absorption to the abnormally large differences between the radio-frequency and visible-frequency polarizations of several metal trisacetylacetonates Gas-phase organometallic chemistry: chain-length effects Catalytic photochemical dehydrogenation of organic substrates by polyoxometalates pH dependence of the lifetime of a Norrish II biradical Dynamic intermolecular tautomerism of 3,5-dimethylpyrazole in the solid state by carbon-13 CP/MAS NMR spectroscopy and x-ray crystallography Symmetry-assisted synthesis of triepoxide stereoisomers of E,Z,E,-dodeca-2,6,10-trien-1,12-diol and their cascade reactions to 2,5-linked bistetrahydrofurans Additions and Corrections - Cluster Synthesis. 6. The Unusual Structures, Bonding, and Reactivity of Some Sulfido-Bridged Tungsten-Osmium Carbonyl Cluster Compounds Masthead Experimental and ab initio molecular orbital studies on collisions of methane radical ion(1+) (CH4+.cntdot.) and monoprotonated methane (CH5+) with molecular oxygen: on the formation of methane (CH42+) and methonium (CH52+) dications and stable CHn- species (n = 0-3) Infrared photochemistry of tetramethyldioxetane. 2. The nature of electronically excited products Farnesylpyrophosphate synthetase. A case for common electrophilic mechanisms for prenyltransferases and terpene cyclases Detection of the static 1,2-dimethyl-2-norbornyl cation by variable temperature carbon-13 CPMAS NMR

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