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Is Part Of	http://hub.abes.fr/acs/periodical/jacsat/1985/volume_107
has manifestation of work	http://hub.abes.fr/acs/periodical/jacsat/1985/volume_107/issue_24/m/web http://hub.abes.fr/acs/periodical/jacsat/1985/volume_107/issue_24/m/print
issue	24
is Is Part Of of	Toward a theory of chemical reactivity based on the charge density On the optical activity of bromochlorofluoromethane Is hydrocyanic acid a normal acid? Proton transfer from hydrocyanic acid to bases and small inhibition of proton exchange by acid Synthesis and structural characterization of the complex [NiMo(CO)2{.mu.-.eta.2,.eta.2-C(Me)C(Me)C(O)}(.eta.-C5H5)(.eta.-C5H4Me)] Book Reviews Role of agostic interaction in .beta.-elimination of palladium and nickel complexes. An ab initio MO study Intramolecular kinetic deuterium isotope effects on microsomal hydroxylation and chemical chlorination of toluene-.alpha.-d1 and toluene-.alpha.,.alpha.-d2 Phenyliodonium bis(phenylsulfonyl)methylide, a new hypervalent iodonium ylide Monomeric tungsten(IV) phenoxide and thiolate complexes Layer cross-linking in pillared clays Organometallic clusters containing oxygen atoms. Preparation, structure, and properties of (.eta.-C5H5)11V13O18(NMe3)2 and (.eta.-C5H5)14V16O24, dimeric derivatives of (.eta.-C5H5)6V6O8 Prediction of silicon-29 nuclear magnetic resonance chemical shifts using a group electronegativity approach: applications to silicate and aluminosilicate structures Conformation of mono- and dicarboxylic acids adsorbed on silver surfaces Rare examples of structurally characterized five-coordinate organocobalt complexes. Novel dynamic NMR evidence for synergistic enhancement of cis and trans effects in B12 models Dual stereoselectivity in the nucleophilic attack on (.pi.-allyl)palladium complexes Dewar furan. Its generation and trapping with isobenzofuran Valence .sigma. ionization in systems with multiple metal-metal bonds Application of allenylsilanes in [3+2] annulation approaches to oxygen and nitrogen heterocycles Dependence of deuterium spin-lattice relaxation rates of multilamellar phospholipid dispersions on orientational order Preparation and conformations of the medium-ring dimethylphosphazenes (NPMe2)9-12: Crystal and molecular structures of octadecamethylcyclononaphosphazene, eicosamethylcyclodecaphosphazene, docosamethylcycloundecaphosphazene, and tetracosamethylcyclododecaphosphazene New hypervalent phosphorus compounds: neutral and cationic 10-P-5 species from O:P(OCH2CH2)3N and Lewis acids Nuclear magnetic response and conformational energy characterization of repeat peptides of elastin: the cyclohexadecapeptide, cyclo-(L-Val1-L-Pro2-Gly3-Gly4)4 Oxidative nucleophilic addition of organovanadium reagents to aldehydes with formation of ketones Structures and Raman spectra of two crystalline modifications of dithiodiglycolic acid Application of spin trapping to probe the radical-pair model in magnetic-field-dependent photoreduction of naphthoquinone in SDS micellar solution Cycloreversion induced by charge-transfer excitation of electron donor-acceptor complexes. Wavelength-dependent photochemistry of dianthracene Absolute electronegativity and absolute hardness of Lewis acids and bases Carbon acidity. 66. Equilibrium ion pair acidities of substituted diphenylmethanes in cyclohexylamine Stereochemistry of cycloadditions of fluoroallene On the stability of cubic phosphorus, P8 Tandem mass spectrometry methodology for the sequence determination of cyclic peptides Reaction of 6-yl radicals of uracil, thymine, and cytosine and their nucleosides and nucleotides with nitrobenzenes via addition to give nitroxide radicals. Hydroxide ion-catalyzed nitroxide heterolysis Reversible formation and disruption of micelles by control of the redox state of the head group Stereochemistry at iron during carbonyl insertion reactions of FeMeI(CO)2(PMe3)2 X-ray crystal structure and conformational analysis of tetradecamethylcycloheptasilane, (Me2Si)7 Proton NMR analyses, shielding mechanisms, coupling constants, and conformations in steroids bearing halogen, hydroxy, and oxo groups and double bonds Photochemistry of ketones in solution. Part 75. Photodecarbonylation of cis- and trans-2,7-dimethyl-3,5-cycloheptadienones: applicability of orbital symmetry theory to photochemical cheletropic fragmentations The formation of an enantiomerically pure product of free radical coupling. The chemistry of diphenylcarbene in polycrystalline S-(+)-2-butanol Photosensitized isomerization of norbornadiene to quadricyclane with (arylphosphine)copper(I) halides The ring opening of gas-phase cyclopropane radical cations Control of the photochemical reactivity of coordination compounds by formation of supramolecular structures: the case of the hexacyanocobaltate(III) anion associated with polyammonium macrocyclic receptors Experimental and theoretical studies of dinuclear gold(I) and gold(II) phosphorus ylide complexes. Oxidative addition, halide exchange, and structural properties including the crystal and molecular structures of [Au(CH2)2PPh2]2 and [Au(CH2)2PPh2]2(CH3)Br Complexation of tin(II) chloride by a novel macrocycle containing rhodium and nitrogen binding sites. The preparation and x-ray crystal structure of Rh2Sn2(CO)2Cl6[.mu.-2,6-bis(diphenylphosphino)pyridine]2 Measurement of hydrazine-hydrazine radical cation self-exchange electron-transfer rates by proton NMR Time-resolved resonance Raman studies of the .delta..delta.* excited state of octachlorodirhenate dianion (Re2Cl82-) .beta.-Diketonate cobalt(3+) chelates. Stereoisomerism and electrochemical studies of complexes with two different ligands Haptotropic rearrangements in polyene-MLn complexes. 3. Polyene-ML2 systems Conformation and dimerization of actinomycin-related peptide lactones in solution and in the solid state Stereoselective total synthesis of (.+-.)-8-deoxyanisatin Tetraaryldiphosphine cation radicals. Electrochemical generation and ESR study The geometries of the high-energy conformers of some acyclic 1,3-dienes Carbon acidity. 68. Hydrogen isotope exchange kinetics of 1,3-diphenylindene, cyclopentadiene, 1,4-diphenylcyclopentadiene, and 2,7-di-tert-butylfluorene Enzyme-catalyzed organic synthesis: a comparison of strategies for in situ regeneration of NAD from NADH NMR isotope shifts as a probe of electronic structure High-resolution NMR with a surface coil Ionic multimers from heterocyclic compounds. Clusters or polymers? Polypeptide-metal cluster connectivities in metallothionein 2 by novel proton-cadmium-113 heteronuclear two-dimensional NMR experiments Binucleating tetrapyrrole macrocycles Mixed olefin-alkyne complexes of molybdenum(II) and tungsten (II) dithiocarbamates Molecular organization in starches: a carbon 13 CP/MAS NMR study Synthesis and crystal structure of an optically active, internally coordinated alkylchloroborane. The boron-centered anomeric effect Simplification of proton NMR spectra by selective excitation of experimental subspectra Photochemistry of the carbonyl ylide produced by reaction of fluorenylidene with acetone. A comparison of carbonyl and nitrile ylides Thermal extrusion of dimethylsilanone from (hydridosilyt)ketenes. A retro-Wolff rearrangement Alkyl migration or carbonyl migration? Ab initio MO study of reaction mechanism for carbonyl insertion of palladium complex Low-temperature carbon-13 magnetic resonance in solids. 5. Chemical shielding anisotropy of the 13CH2 group Resolution of racemic mixtures via lipase catalysis in organic solvents Conversion of serine to stereochemically pure .beta.-substituted .alpha.-amino acids via .beta.-lactones Aqueous electrochemistry of trans-(py)4ReV(O)2+. Electrocatalytic reductions based on rhenium(II) Importance of entropy terms in triplet energy transfer equilibria Exciton delocalization of the excited singlet state of chlorophyll a monohydrate dimer and fluorescence lifetimes of translationally equivalent aggregates Masthead Coordination chemistry of microbial iron transport compounds. 34. The pH-dependent reduction of ferric enterobactin probed by electrochemical methods and its implications for microbial iron transport Analytical optical resolution of bromochlorofluoromethane by enantioselective inclusion into a tailor-made cryptophane and determination of its maximum rotation Electrophilic reactions at single bonds. 20. Selective monohalogenation of methane over supported acidic or platinum metal catalysts and hydrolysis of methyl halides over .gamma.-alumina-supported metal oxide/hydroxide catalysts. A feasible path for the oxidative conversion of methane into methyl alcohol/dimethyl ether Intramolecular proton transfer through water in diamine monocations Influence of acetate buffers and metal ions on ketonization rates of enolpyruvate: a further test of the Marcus function An alternant hydrocarbon .pi. system with nonalternant character. Evidence from UV-VIS spectroscopy for cyclic homoconjugation in homoazulene Mechanistic polyoxoanion chemistry: intramolecular rearrangements of the .alpha.-Mo8O264-, C6H5AsMo7O254-, and (C6H5As)2Mo6O244- anions On the application of the steady state to kinetic isotope effects Rotational spectra and structures of small clusters: Ar3-HF and Ar3-DF Selenium-77 nuclear magnetic resonance investigation of a protein-selenoligand complex: interaction of .alpha.-chymotrypsin with (phenylselenyl)acetate Resonance Raman spectra of oxyen adducts of cobalt porphyrins. Enhancement of solvent and solute bands via resonance vibrational coupling Internal molecular motion of triphenylphosphine oxide: analysis of atomic displacement parameters for orthorhombic and monoclinic crystal modifications at 100 and 150 K Studies in the cycloproparene series. The synthesis, trapping, and spectral characterization of 1H-cyclopropa[l]phenanthrene Radical cations of fulvenes: planar or twisted? Gas-phase isotope fractionation factor for proton-bound dimers of methoxide anions Metal-spine conductivity in a partially oxidized metallomacrocycle: (phthalocyaninato)cobalt iodide Synthesis of 9-decarboxymethoxatin. Metal complexation of methoxatin as a possible requirement for its biological activity X-ray and neutron diffraction study of H5Ir[P(iso-Pr)3]2 Highly conductive metallomacrocyclic assemblies. Synthesis via electrocrystallization and single-crystal properties of a phthalocyanine molecular metal without halogen counterions On the concept of local hardness in chemistry Superdegenerate electronic energy levels in extended structures Glycerol kinase: substrate specificity

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