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Formation and thermal reactions of rhodium-carbon bonds derived from the reactions of octaethylporphyrin-rhodium(III) dimer with alkyl carbon-hydrogen bonds in alkyl aromatics
Stereoelectronic aspects of the intercalative binding properties of 7,12-dimethylbenz[a]anthracene metabolites with DNA
The mechanism of Lewis acid catalyzed ene reactions
On the singlet and triplet excited states of nitrosamines
X-ray crystal structure and hydrocarbon solution dynamics of tetrameric 1-(dimethylamino)-3-lithiopropane
Synthesis of aromatic Schiff base oligomers at the air/water interface
Stereodynamics of a series of di-tert-butylphosphines [(tert-C4H9)2PR; R = H, Me, Et, CH2Ph, iso-C3H7, tert-C4H9, and Ph]. Carbon-13, proton, and phosphorus-31 NMR studies. Molecular mechanics calculations
Efficient total synthesis of (.+-.)-anatoxin a
Study of intramolecular sensitization and other excited-state pathways in orthometalated azobenzene complexes of palladium(II)
Toward an ab initio derivation of crystal morphology
Spectral and electrochemical identification of iron(IV)-oxo porphyrin and iron(IV)-oxo porphyrin .pi.-cation species
A vinyltrimethylenemethane intermediate in the 1,3-sigmatropic rearrangement of the 6-methylenebicyclo[3.1.0]hex-2-enyl system
The dependence of biological electron transfer rates on exothermicity. The cytochrome c/cytochrome b5 couple
Total synthesis of a novel antiulcer agent via a modification of the intramolecular Wadsworth-Emmons-Wittig reaction
Electronic structure of three-membered rings containing phosphorus atoms. PE spectroscopic investigations and model calculations
Synthesis and structure of a new ternary chalcogenide Nb3Pd0.72Se7; interrelationships in the packing of prisms and planes
Pyrophosphate formation via a phosphoramidate intermediate in polyammonium macrocycle:metal ion-catalyzed hydrolysis of ATP
Gas-phase generation of singlet oxygen by reaction of ozone with organic substances
Structure and conformations of 4-chloro-1-butanol: electron-diffraction evidence for internal hydrogen bonding
On the incidence of internal ion pair return during solvolysis of sec-alkyl benzenesulfonates
Kinetics and mechanism of nitrate reduction by a dimeric aquamolybdenum(III) complex in aqueous solution. Direct evidence for an oxo-group transfer
A quantitative theory of mass spectral fragmentation patterns
Direct observation of ion-pair dynamics
A theoretical study of the phosphinonitrene (H2P:N)-iminophosphane (HP:NH) rearrangement
Activation of methane by photoexcited copper atoms and the photochemistry of methylcopper hydride in solid methane matrixes
Cadmium-113 shielding tensors in cadmium-substituted metalloproteins
Preparation and structures of novel di- and trinuclear clusters of iridium(II) without carbonyl ligands
Quantization effects in the photocurrent spectroscopy of superlattice electrodes
Mixed-valence dialkylbiferrocenium salts: an explanation for the observed temperature dependence of electron-transfer rates
Novel structure of the complex between carboxypeptidase A and a ketonic substrate analog
Correction. Anomerization of Furanose Sugars and Sugar Phosphates
Factors determining carbon monoxide adsorption sites on palladium and platinum (100) and (111) surfaces: theoretical study
Theoretical studies of the system H3O+(H2O)n for n = 1, 9
Synthetic, structural, spectroscopic, and theoretical studies of decamethylvanadocene arylnitrenes
Association phenomena. 7. Mixed chelate and comicellar catalysis of acetyl phosphate olysis reactions
Infrared multiphoton dissociation of some oxygen-containing hydrocarbon ions. Differentiation of isomeric ion structures in the gas phase
Multinuclear NMR study of the disproportionation and syn/anti isomerism in solutions of amino-substituted methylmercury derivatives of adenine and 9-methyladenine
Structural insights from the molybdenum K-edge x-ray absorption near edge structure of the iron-molybdenum protein of nitrogenase and its iron-molybdenum cofactor by comparison with synthetic iron-molybdenum-sulfur clusters
Valence-detrapping modes for electron transfer in the solid state of mixed-valence, oxo-centered, trinuclear iron acetate complexes: x-ray structure and physical data for [Fe3O(O2CCH3)6(4-Et-py)3](4-Et-py)
Distonic oxonium and ammonium radical cations. A neutralization-reionization and collisional activation study
Study of stereochemical properties of molecular orbitals by Penning ionization electron spectroscopy. Effects of through-space/through-bond interactions on electron distributions
Highly reactive organolanthanides. A mechanistic study of catalytic olefin hydrogenation by bis(pentamethylcyclopentadienyl) and related 4f complexes
Solution equilibria between carbon-bonded carbonyl and .PI.-carbonyl ligands in four-iron clusters and cleavage of the .PI.-carbonyl ligand
Interaction of a hydrogen molecule with palladium
A compound with a tin-phosphorus double bond: the first stable stannaphosphene
New carbon-carbon bond-forming reaction of carbon monoxide: remarkable trialkylation of a carbonyl ligand in a molybdenum pentadienyl complex
Oxidation of 2,6-di-tert-butylphenol by molecular oxygen. 2. Catalysis by cobaltous polyamine chelates through their (.mu.-peroxo)- and (.mu.-peroxo)(.mu.-hydroxo)dicobalt(III) complexes
Cystine peptides. The antiparallel .beta.-sheet conformation of two synthetic cyclic bis(cystine peptides)
An asymmetric Simmons-Smith reaction
Sequence-specific cleavage of double-helical DNA. N-Bromoacetyldistamycin
Electron transfer through aromatic spacers in bridged electron-donor-acceptor molecules
Nature of the migrating group in 1,5-sigmatropic hydrogen shifts
Highly stereoselective reduction of .alpha.-substituted .beta.-keto amides by means of hydrosilane-fluoride ion and hydrosilane-acid reagent. A practical approach to aldols of both threo and erythro configurations
Silapyran and silacyclobutene formation in the gas-phase pyrolysis of 2-(dimethylsilyl)furan
N-Carboxybiotin formation by pyruvate carboxylase: the stereochemical consequence at phosphorus
Book Reviews
Structure elucidation of nitrosocimetidine, a mutagenic charge-transfer system
Synthesis and structures of distibene (RSb:SbR) and bridging stibinidene (RSb) iron complexes
Photocatalysis of oxygen transfer from p-cyano-N,N-dimethylaniline N-oxide to meso-(tetraphenylporphinato)chromium(III) chloride
Correction. Hartree-Fock MO Theoretical Approach to Aromaticity. Interpretation of Hückel Resonance Energy in Terms of Kinetic Energy of π Electrons
Laser flash photolysis study of the hydrogen atom transfer reaction from triplet 1-naphthol to ground benzophenone
Influence of solvent properties on the kinetics of complexation of the sodium ion with 18-crown-6
Asymmetric synthesis of 2-alkyl pyrrolidines and piperidines. Synthesis of (+)-metazocine
Pyrazolyl-bridged iridium dimers. 10. Sequential addition at the metal centers in a diiridium configuration. Oxidatively induced relocation of a bent, terminal nitrosyl group to occupy a bridging site
Correction. Bimetallic Solvated Metal Atom Dispersed Catalysts. New Materials with Low-Temperature Catalytic Properties
Properties of metal-metal single bonds. Vibrational and electronic spectra of binuclear rhodium(II) and iridium(II) isocyanide complexes with comparisons to decacarbonyldimanganese [Mn2(CO)10]
Factors influencing conformational preferences in cyclohexenes
On the reaction of trioxodinitrate(II) with hemoglobin and myoglobin
Charge carrier trapping and recombination dynamics in small semiconductor particles
Metallocalixarenes: syntheses and x-ray crystal structures of titanium(IV), iron(III), and cobalt(II) complexes of p-tert-butylcalix[4]arene
Highly reactive organolanthanides. Synthesis, chemistry, and structures of 4f hydrocarbyls and hydrides with chelating bis(polymethylcyclopentadienyl) ligands
New mode of ligation for 1,3-butadiene to two metal centers. Synthesis and structure of [{(iso-Pr)2PCH2CH2CH2P(iso-Pr)2}Rh]2(.mu.-.eta.3-.eta.3-C4H6): a partial butadiene sandwich
Isopentenyl diphosphate:dimethylallyl diphosphate isomerase. Irreversible inhibition of the enzyme by active-site-directed covalent attachment
Simultaneous determination of photoreaction dynamics and energetics using pulsed, time-resolved photoacoustic calorimetry
Theoretical interpretation of the cyclohexane .fwdarw. benzene reaction on the platinum(III) surface
Variations in reactivity of lone-pair electrons due to intramolecular hydrogen bonding as observed by Penning ionization electron spectroscopy
First examples of polynuclear, sulfur-containing, zirconium compounds. Synthesis and structural characterization of the trinuclear Zr3S3(S-tert-Bu)2(BH4)4(THF)2 and the hexanuclear Zr6S6(S-tert-Bu)4(BH4)8(THF)2 clusters
Chiral complexes polymerize methacrylate esters to give helical polymers that mutarotate by uncoiling
Masthead
Tailored excitation for Fourier transform ion cyclotron mass spectrometry
Crystal and molecular structure of and magnetic coupling in two complexes containing gadolinium(III) and copper(II) ions
Arsenite-inhibited xanthine oxidase - determination of the molybdenum-sulfur-arsenic geometry by EXAFS
Calcium and magnesium binding to .gamma.-carboxyglutamate and .beta.-carboxyaspartate residues: structures of calcium and magnesium complexes of methylmalonic acid
Synthesis, structure, and reactivity of the {[(.eta.5-C5H5)2U]2(.mu.-TiW5O19-.kappa.2O)2}4- anion
On the nucleophilic nature of a TMM-PdL2 intermediate: a direct palladium catalyzed addition of trimethylenemethane to heteroatom unsaturation
Inclusion of spin-orbit and low-symmetry effects in a vibronic coupling (PKS) model for mixed-valence dimers: application to the Creutz-Taube ion
Structural dependence of the singlet-triplet energy gap of the tetramethylene biradical
Association phenomena. 6. NMR studies of the mixed chelates of triethylenetetramine, phosphate, and metal ions
Specific rate enhancement by olefin coordination in reductive elimination of .eta.3-allylpalladium complexes
Metal-metal bonds involving actinides. Synthesis and characterization of a complex having an unsupported actinide to transition metal bond
Metal promoted cyclization. 9. Controlled and catalytic acylpalladation. A novel route to cyclopentenone and cyclohexenone derivatives
Monte Carlo study of the conformation-dependent hydration of the 18-crown-6 macrocycle
g-Tensor in a low-spin heme system using molecular orbital theory - ferricytochrome c and nitrosylhemoglobin
Mixed copper/iron clusters. The preparation and structures of [(Ph3P)2Cu]2Fe(CO)4 and [(diphos)2Cu]2Cu6Fe4(CO)16
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