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Relationship between the extractability and the rate of transfer of potassium ion by macrocyclic carriers in liquid membrane systems
Tying knots around chiral centers: chirality polynomials and conformational invariants for molecules
Structures and stabilities of fluorinated carbanions. Evidence for anionic hyperconjugation
Elucidation of medium effects on molecular structure by solid-state and solution carbon-13 NMR. Identification and x-ray structure of the orthorhombic modification of dimethyltin(I) bis(N,N-diethyldithiocarbamate)
Photochemical reaction of 1,4-naphthalenedicarbonitrile with alkylbenzenes and bibenzyls
Determination of the absolute configurations of the isomers of triamminecobalt(III) adenosine triphosphate
Hydrogen bonding between solutes in aqueous solution
First structural characterization of a boron-centered radical: x-ray crystal structure of [Li(12-crown-4)2]+ [BMes3]-.bul.
Carbanion rearrangements. Collision-induced dissociations of the enolate ion of heptan-4-one
Electrochemical reductive activation of mitomycin C
Generation, spectroscopic detection, and chemical reactivity of fluorinated vinylcopper reagents
Cation radical chain cyclopropanation
Transport of small molecules in swollen polymer beads
N-Hydroxypyridine-2-thione esters as radical precursors in kinetic studies. Measurements of rate constants for hydrogen-atom-abstraction reactions
A synthon for the silicon-silicon triple bond
He(I) photoelectron spectra, valence electronic structure, and back bonding in the deltahedral boron chlorides, B4Cl4, B8Cl8, and B9Cl9
Powder ENDOR spectra of p-benzoquinone anion radical: principal hyperfine tensor components for ring protons and for hydrogen-bonded protons
The [4 + 4] dimerization of 2,3-dimethylene-2,3-dihydrofuran: secondary deuterium kinetic isotope effect evidence for a two-step mechanism
Diadamantylcarbene in solution
Visible transients in gas phase UV photolysis of transition metal compounds: experimental and theoretical results for nickel carbonyl (Ni(CO)4)
Unusual selectivities of radical reactions by internal suppression of fast modes
Symmetry control of the coloring problem: the electronic structure of MB2C2 (M = calcium, lanthanum, ...)
Reactivity of mixed cyclometalated palladium compounds containing the [2-Me2NC6H4C(H)SiMe3] monoanion. Part 2. Transmetalation reaction and formation of a novel .mu.-alkylidene compound (x-ray) bis(.mu.-chloro)bis{.mu.-C,.sigma.-N-[2-(dimethylamino)benzylidene](.mu.-chloro)(diethyl sulfide)dipalladium(II)}
Some molecular hydrogen complexes of iridium
Hydrocarbation-formation of diiron .mu.-alkylidyne complexes from the addition of the carbon-hydrogen bond of a .mu.-methylidyne complex across alkenes
Comparison of the properties of binary and ternary metal ion complexes of 1,N6-ethenoadenosine 5'-triphosphate (.epsilon.-ATP) and adenosine 5'-triphosphate (ATP), including macrochelate and purine-indole stack formation
Second-order effects in two-dimensional cross-relaxation spectra of proteins: investigation of glycine spin systems
Role of membrane hydration and membrane fluidity in the mechanism of anion-induced fusion of didodecyldimethylammonium bromide vesicles
Photochemical electron transfer involving 1,5-dithiacyclooctane. A recoverable charge relay in the photosensitized oxidation of halide
Formation of iron-osmium, iron-ruthenium, and iron-cobalt bimetallic particles by thermal decomposition of heteropolynuclear clusters supported on partially dehydroxylated magnesia
Biomolecules in the gas phase. 1. Multiphoton-ionization mass spectrometry of native chlorophylls
Hyperstable olefins: further calculational explorations and predictions
Vanadium phenolates as models for vanadium in biological systems. 1. Synthesis, spectroscopy, and electrochemistry of vanadium complexes of ethylenebis[(o-hydroxyphenyl)glycine] and its derivatives
Reaction of dinitrogen pentoxide with fluoranthene
Total synthesis of (-)-coriolin
.pi.-.pi.* and .pi.'-.pi.'* Electronic transitions of diphenylbutadiyne
Dimerization of borirene to 1,4-diboracyclohexadiene. Structures and stabilities of (CH)4(BH)2 molecules
Formation of diiron .mu.-alkenyl complexes from the reaction of a .mu.-methylidyne complex with selected alkenes
Diazabenzosemibullvalene. A precursor to the benzoprefulvene biradical and indenylmethylene
Mechanistic insight into the photoinduced rearrangement of the tricyclo[4.1.0.02,7]heptyl skeleton
Chemistry of acetylene exposed to alumina and alumina-supported rhodium catalysts
Azadiboridine and diazaboridine: aromatic and antiaromatic three-membered-ring prototypes
Pyrolytic, kinetic, and theoretical studies on the isomerization of Me2HSiCH2.bul. to Me3Si.bul.
Particle bombardment (FAB) mass spectra of methanol at sub-ambient temperatures
Hydride transfer in the oxidation of formate ion by [(bpy)2(py)Ru(O)]2+
Reductive alkylation of aceheptylene - a simple route to a series of novel .pi.-perimeters
Prostacyclin: evidence that intramolecular general-acid catalysis by its carboxylic acid group is responsible for the extra hydrolytic lability
Crystal structure of 2,2,4,4-tetrahydro-2,2,2,4,4,4-hexaphenyl-1,3,2,4-dioxadistibetane (triphenylstibene oxide dimer) and related compounds
An efficient electrocatalytic model cytochrome P-450 epoxidation cycle
Two-step laser excitation study on the proton transfer and anion formation in the intramolecularly hydrogen-bonded 7-hydroxy-1-indanone and related compounds
An analysis of the absorption and fluorescence spectra of trimethylamine. Determination of the ~A-~X origin and the ground state inversion barrier
Structural studies of carbohydrates by deuterium NMR: sucrose
Identification of some intermediates in the titanocene-catalyzed dehydrogenative coupling of primary organosilanes
Direct acting, highly mutagenic, .alpha.-hydroxy N-nitrosamines from 4-chloroindoles
Direct ESR evidence for sodium selective, intramolecular ion pairing in redox-switched nitrogen-pivot lariat ethers
(Trifluoromethyl)cyclopentadienide: a powerful electron-withdrawing ligand for transition-metal complexes
The total synthesis of tetracycline
1-Naphthylcarbene: spectroscopy, kinetics, and mechanisms
Kinetics of disproportionation of tricarbonylbis(phosphine)iron(I) cation radicals probed by double potential step chronocoulometry
Chemistry of weakly solvated lanthanide-metal cations. Synthesis, characterization, and catalytic chemistry of [Eu(CH3CN)3(BF4)3]x
Crystal structure of methotrexate tetrahydrate
Ligation and reduction of iron(III) porphyrins by amines. A model for cytochrome P-450 monoamine oxidase
Determination of vinyl orientation in resting state and compound I of horseradish peroxidase by the proton nuclear Overhauser effect
Electron density analysis of the reaction of aldehydes with lithium hydride. The general importance of the HOMO-HOMO interaction
Silicon-29 NMR observation of an unprecedented rearrangement in tetraaryldisilenes
Ion chemistry of cyanides and isocyanides. 1. The carbon lone pair as proton acceptor: proton affinities of isocyanides. Alkyl cation nitrogen, oxygen, and carbon lone pair donors
Ammonia binds to the manganese site of the oxygen-evolving complex of photosystem II in the S2 state
Magnetic properties of manganese in the photosynthetic O2-evolving complex. 2. Evidence for a manganese tetramer
Solid-state structural chemistry of lariat ether and BiBLE cation complexes: metal-ion identity and coordination number determine cavity size
Stereospecific synthesis and ring closure of a racemic actinospectose equivalent: a concise route to the spectinomycin series
Masthead
Gas-phase reactivity of the formyl radical with unsaturated hydrocarbons: an experimental and theoretical study
Transient photoligation behavior of nickel protoporphyrin reconstituted myoglobin and hemoglobin
The (p-d) .pi. bonding in fluorosilanes? Gas-phase structures of (CH3)4-nSiFn with n = 1-3 and of (tert-Bu)2SiF2
Coupling between the rotation of the methyl group and the proton exchange in 5-methyl-9-hydroxyphenalen-1-one
Group IIB metal alkyls: the synthesis of trifluorosilyl and trifluoromethyl alkyls of cadmium and zinc
Pronounced proton and phosphorus-31 NMR spectral changes on meso-tetrakis(N-methylpyridinium-4-yl)porphyrin binding to poly[d(G-C)].cntdot.poly[d(G-C)] and to three tetradecaoligodeoxyribonucleotides: evidence for symmetric, selective binding to 5'CG3' sequences
A new cryptophane forming unusually stable inclusion complexes with neutral guests in a lipophilic solvent
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