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Is Part Of	http://hub.abes.fr/acs/periodical/jacsat/1986/volume_108
has manifestation of work	http://hub.abes.fr/acs/periodical/jacsat/1986/volume_108/issue_16/m/print http://hub.abes.fr/acs/periodical/jacsat/1986/volume_108/issue_16/m/web
issue	16
is Is Part Of of	Wavelength dependence of excimer laser photolysis of Cr(CO)6 in the gas phase. A study of the infrared spectroscopy and reactions of the Cr(CO)x (x = 5, 4, 3, 2) fragments .beta.-Hydride elimination from methoxo vs. ethyl ligands: thermolysis of (DPPE)Pt(OCH3)2, (DPPE)Pt(CH2CH3)(OCH3) and (DPPE)Pt(CH2CH3)2 Vibrational circular dichroism of polypeptides. 9. A study of chain length dependence for 310-helix formation in solution Synthesis of punaglandin 3 and 4. Revision of the structures Correction. Total Synthesis of (+)-Latrunculin B Book Reviews Picosecond time resolved Raman scattering study of hydrogen abstraction by triplet excited benzoquinone Structure and reactivity of thiophosphoranyl radicals. A quantum chemical study Product ratio variation in reactions of o-(3-butenyl)halobenzenes and 6-bromo-1-hexene with alkali metals in ammonia/tert-butyl alcohol solution. Indications of reaction-during-mixing effects Diastereomeric atropisomers of the tricyclo[9.3.1.03,8]pentadecane ring system. Synthesis and structural studies Bonding in transition-metal methylene complexes. 3. Comparison of chromium and rubidium carbenes: prediction of stable LnM(CXY) systems Ab initio study of structures and binding energies for anion-water complexes Mixed carbonyl-isocyanide and carbonyl-nitrile complexes derived from the reactions of the multiply bonded dirhenium(II) complexes Re2X4(dppm)2(CO) (X = chloro or bromo-; dppm = Ph2PCH2PPh2). The structural characterization of Cl2Re(.mu.-Cl)(.mu.-dppm)2ReCl(CO) and Cl2Re(.mu.-Cl)(.mu.-CO)(.mu.-dppm)2ReCl(CNxylyl) Group IVA organometallic reagents. 2. Enantiomeric purity determination of 1,2-diols through NMR spectroscopy without chiral auxiliaries Thermochemical comparisons of homogeneous and heterogeneous acids and bases. 1. Sulfonic acid solutions and resins as prototype Broensted acids A total synthesis of plumericin, allamcin, and allamandin. Part 1. Basic strategy Complex between carboxypeptidase A and a possible transition-state analog: mechanistic inferences from high-resolution x-ray structures of enzyme-inhibitor complexes Molecular and electronic structure of Cu(tet-b)SSCH2CO2.cntdot.3CH3OH, a novel copper(II) alkyl persulfide complex Computer Software Reviews Temperature dependence of the lifetimes of excited benzyl and other arylmethyl radicals Stable perfluoroalkyl carbanion salts Total synthesis of (.+-.)-fawcettimine (Burnell's base A) Planarization of unsaturated rings. Cycloheptatriene with a planar seven-membered ring The preparation and characterization of radical cation salts derived from perfluorobenzene, perfluorotoluene, and perfluoronaphthalene Synthesis and characterization of a new semisynthetic enzyme, flavolysozyme Specific sequence-specific recognition of right-handed double-helical DNA by (2S,3S)- and (2R,3R)-dihydroxybis(netropsin)succinamide A synthetic model approach to the manganese(III) acid phosphatase and its iron(III)-substituted form Correction. Temperature Dependence of the Homolytic Abstraction of Benzylic Hydrogen by Bromine Atom Ab initio studies of molecular structures and energetics. 1. Base-catalyzed hydrolysis of simple formates and structurally related reactions Polarized single-crystal absorption spectra of cobalt2+-carboxypeptidase A Sulfoxide induced acceleration and enhancement of geometric selectivity of a [1,5]-sigmatropic hydrogen shift Prostaglandin synthesis. 12. Synthesis of (7E)- and (7Z)-punaglandin 4. Structural revision Theoretical determination of molecular structure and conformation. 19. Configurational changes of bridged annulenes: inversion at an ether oxygen atom Nucleophilic capture of 2-bicyclo[2.1.1]hexyl cations Oxidation of 3,5,5-trimethyl-2-oxomorpholin-3-yl (TM-3) with molecular oxygen. Generation of a persistent aminyl radical Neutral water-soluble aluminum complex of neurological interest Evidence for reversible formation of an intermediate in the "spontaneous" hydrolysis reaction of p-methoxystyrene oxide Correction. Heavy-Atom Kinetic Isotope Effects in the Acid-Catalyzed Rearrangement of N-2-Napthyl-N'-phenylhydrazine. Rearrangement is Shown To Be a Concerted Process Kinetic studies of carrier transport and recombination at the n-silicon methanol interface A flash photolysis investigation of dihydrogen elimination from phosphine complexes of iridium(III) and rhodium(III): H2IrCl(CO)(PPh3)2, H2IrCl(PPh3)3, and H2RhCl(PPh3)3 Main group chemistry on a metal framework. Reactions of [(.mu.-H)Fe3(CO)9BH2R]- (R = H, CH3) with Lewis bases Photochemical studies. 26. Irradiation-induced transformations of homoconjugated dienones. Highly selective photorearrangements in the spiro[5.5]undeca-1,3-dien-7-one system Phosphatranes as unusual stabilizing structures for hypervalent phosphorus: 10-P-5 mono- and divalent cations Macrolide biosynthesis. 3. Stereochemistry of the chain-elongation steps of erythromycin biosynthesis Slow complexation rates of crown ethers: what's taking so long? Macrocyclic receptor molecules for urea: the use of electrophiles in the (co-)complexation of neutral molecules Correction. New Synthetic Technology for the Construction of Oxocenes Helical twist and spontaneous polarization direction in ferroelectric smectic liquid crystals. 2 Inter- and intramolecular insertion of rhenium into carbon-hydrogen bonds Zwitterionic tetramethylenes as the common intermediates in the cycloaddition and polymerization reactions of N-vinylcarbazole with electrophilic tetrasubstituted ethylenes: a new explanation for charge-transfer initiation Novel organometallic ionophore with specificity toward lithium ion Photogenerated semi-enone radical anions. A new perspective on the reactions of 10-(hydroxymethyl)-2-octalone tosylate Effect of spin-orbit state on chemical reactivity: study of chemiluminescent and ground-state products from reaction of strontium(3PJ) with several halogen-containing molecules Hydrophobic perturbation of acyclic equilibria Correction. Contribution of Tunneling to Secondary Isotope Effects in Proton-Transfer Reactions. A binuclear iron peroxide complex capable of olefin epoxidation Retinal and rhodopsin analogs directed toward a better understanding of the H.T.-n model of the primary process of vision Thermolysis of the cobalt-carbon bond of adenosylcobalamin. 2. Products, kinetics, and cobalt-carbon bond dissociation energy in aqueous solution Synthesis of covalently-linked DNA/RNA cross sections Correction. Dimethylsilylene: Its Optical Absorption Spectrum and Reaction Kinetics Studies in the cycloproparene series: a theoretical and experimental study of the cyclopropabenzynes Generation and characterization of 2,6-azulylene Correction. Nucleophilic attack of amine and hydroxide to platinum dibenzonitrile dichloride. Crystal structure of [Pt(NH:CPhN-tert-BuCH2CH2NH-tert-Bu)Cl(NHCOPh)] and cis-[PtNH:CPhN-tert-BuCH2CH2NH-tert-Bu)Cl2(NCPh)] Hydrogen on zinc oxide. Theory of its heterolytic adsorption Radical chain mechanisms for alkyl rearrangement in organocobalt complexes Unusually detailed insight into the dynamic behavior of coordinated ambidentate ligands. Factors influencing the binding mode of 2-aminopyridines in B12 models The deprotonation of trialkylamine cation radicals by amines L-Aspartic acid in acyclic stereoselective synthesis. Synthetic studies on amphotericin B Photosensitized electron-transfer reactions in .beta.-cyclodextrin aqueous media: effects on dissociation of ground-state complexes, charge separation, and hydrogen evolution Correction. Preparation and Characterization of Stable Ruthenium (IV)-Oxo Complexes Which Contain Tertiary Phosphine Ligands Model for the initial stage in the oxidative addition of I2 to organoplatinum(II) compounds. X-ray structure of square-pyramidal [PtIII{C6H3(CH2NMe2)2-o,o'}(.eta.1-I2)] containing a linear Pt-I-I arrangement Barrier to reductive elimination of hydrogen from dihydridobis(trimethylphosphine)platinum(II) Surface-enhanced Raman spectroscopy of amino acids and nucleotide bases adsorbed on silver Helical twist sense and spontaneous polarization direction in ferroelectric smectic liquid crystals. 1 Isotope effects in arene carbon-hydrogen bond activation by [(C5Me5)Rh(PMe3)] The multiply bonded octahalodiosmate(III) anions. 2. Structure and bonding On the addition of silyl radicals to unsaturated carbonyl compounds. Regioselectivity of the attack and 1,3 carbon to oxygen silicon migration Masthead Electrochemically catalyzed aromatic nucleophilic substitution. Reactivity of cyanide ions toward aryl radicals in liquid ammonia Solvent dependence of the carbon kinetic isotope effect on the decarboxylation of 4-pyridylacetic acid. A model for enzymatic decarboxylations A total synthesis of plumericin, allamcin and allamandin. Part 2. A biomimetic strategy Epoxidation of olefins by iodosylbenzene catalyzed by binuclear copper(II) complexes Laser spectroscopy of calcium and strontium monocyclopentadienide Cycloreversion of quadricyclane derivative via triplet state. Adiabatic vs. biradicaloidal mechanism

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