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type	work Issue
Is Part Of	http://hub.abes.fr/acs/periodical/jacsat/1987/volume_109
has manifestation of work	http://hub.abes.fr/acs/periodical/jacsat/1987/volume_109/issue_16/m/print http://hub.abes.fr/acs/periodical/jacsat/1987/volume_109/issue_16/m/web
issue	16
is Is Part Of of	Circular dichroism studies of the solution structure of chiral pyridine substituted crowns and their complexes Density functional approach to frontier controlled reactions A versatile new synthesis of organic compounds with chiral methyl groups: stereochemistry of protolytic rhenium-carbon bond cleavage in chiral alkyl complexes (.eta.5-C5H5)Re(NO)(PPh3)(R) Mechanism of titanocene metallacyclobutane cleavage and the nature of the reactive intermediate Unique spectroscopic properties of mixed-ligand complexes with 2,2'-dipyridylamine: a dual luminescence from a ruthenium(II) complex Investigation of the 2,7-dihalofluorenylidenes: search for heavy atom effects in the reactions of triplet carbenes Cycloheptatrienylidene singlet-triplet energetics: theory responds Vibrational spectroscopic characterization of the CCO ligand and the possible occurrence of CCO on surfaces Infrared spectroscopy and photochemistry of iron-ethylene oxide in cryogenic matrixes. The FTIR spectrum of vinyliron hydroxide Magnetic-field effects in the low-temperature polarized emission and absorption spectra of single-crystal tris(2,2'-bipyridine)ruthenium(2+) bis(hexafluorophosphate) ([Ru(bpy)3](PF6)2) Macrolide formation by free radical cyclization Dianions and dications derived from bridged [4n + 2]annulenes. Paratropism as a function of ring size, conformation, and configuration Platinacyclobutanes on the route to cyclopropanation A formal 4 + 1 route to alkylidenecyclopentenediones. A synthetic application of the transition-metal-catalyzed terminal alkyne .dblharw. vinylidene rearrangement Generation of mono- and dianions of 1,4-diphenyl-2-tetrazene by nonoxidative N-N bond formation. A novel route to a 2-tetrazene, a silacyclotetrazene, and the tetrazenide complex (1,4-diphenyltetrazenido)bis(triethylphosphine) palladium Ion pairing in transition-metal carbonylates modeled by ab initio calculations on BH2COMa (Ma = lithium, sodium) Ozonolysis of vinyl ethers. Evidence for intramolecular oxygen transfer from a carbonyl oxide moiety to a methoxyvinyl group Direct observation of photochemical cleavage of a cyclopropylalkoxycarbene to an alkyne Carbon-13 CIDNP investigation of the thermal decomposition of tert-butyl phenylperacetate Systematic design of chemical oscillators. 40. A mechanism for dynamical behavior in the Landolt reaction with ferrocyanide Amelioration of the conjugate addition chemistry of .alpha.-alkoxycopper reagents: application to the stereospecific synthesis of C-Glycosides Kinetics of hexafluorobenzene decomposition on a platinum surface Book Reviews Membrane-spanning steroidal metalloporphyrins as site-selective catalysts in synthetic vesicles Correction. Heavy-Atom Kinetic Isotope Effects and Mechanism of the Acid-Catalyzed o-Semidine and p-Semidine Rearrangements and Disproportionation of 4,4'-Dichlorohydrazobenzene Correction. Intromolecular Carbonyl Oxide - Ester Cycloaddition. Structure of a Novel Alkoxy Ozonide Generation of the distonic ion CH2NH3.bul.+: nucleophilic substitution of the ketene cation radical by ammonia and unimolecular decarbonylation of ionized acetamide The catalytic activation and functionalization of carbon-hydrogen bonds. Aldimine formation by the insertion of isonitriles into aromatic carbon-hydrogen bonds NMR spectra of porphyrins. Part 31. Ring currents in hydroporphyrins Kinetic isotope effects as probes of the mechanism of reaction of 1-naphthylcarbene with cyclohexane and toluene Structure of FK506, a novel immunosuppressant isolated from Streptomyces Direct observation of a dienolate intermediate in the base-catalyzed isomerization of 5-androstene-3,17-dione to 4-androstene-3,17-dione FTIR spectra of hydroxylamine-hydrogen fluoride complexes in solid argon Self-complexation of macrocyclic polyethers studied by carbon-13 NMR longitudinal relaxation time measurements and molecular mechanics Infrared spectra and ab initio SCF calculations for alkane-hydrogen fluoride complexes Kinetics of the reaction of the methylthiyl radical (CH3S) with unsaturated hydrocarbons The oscillatory Landolt reaction. Empirical rate law model and detailed mechanism Structure and conformation of two coprogen-type siderophores. Neocoprogen I and neocoprogen II Mechanistic diagnosis of aminium salt initiated Diels-Alder cycloadditions in the diene/diene format Stereochemistry and mode of intermolecular silicon-hydrogen unsaturated carbene insertions Oxidative dimerization of methane over magnesium and calcium oxide catalysts promoted with Group IA ions: the role of [M+O-] centers Induced fit in synthetic receptors: nucleotide base recognition by a molecular hinge Syntheses, kinetics, and mechanism of ligand substitution reactions of 17-electron cyclopentadienyl and pentadienyl vanadium carbonyl complexes Intramolecular cyclopropanation and olefin metathesis reactions of (CO)5W:C(OCH2CH2CH:CHOCH3)C6H4CH3-p Kinetics of cyclopropyl radical reactions. 3. Study of some 1-substituted cyclopropyl radicals by EPR spectroscopy. The inversion barrier for 1-methylcyclopropyl The biosynthesis of LL-C10037.alpha. from the shikimate pathway Correction. Inter- and Intramolecular Insertion of Rhenium into Carbon-Hydrogen Bonds Thermal stability and kinetic lability of the metal carbonyl bond. A theoretical study on M(CO)6 (M = chromium, molybdenum, tungsten), M(CO)5 (M = iron, ruthenium, osmium), and M(CO)4 (M = nickel, palladium, platinum) Synthesis of trifluorosilyl organometallic complexes from trifluorosilyl radicals and metal atoms Remarkable enantioselective 1,4-addition reactions of chiral allylphosphonyl anions (ambident nucleophiles) with cyclic enones (ambident electrophiles) Far ultraviolet resonance Raman scattering. Highly excited torsional levels of ethylene Computer Software Reviews An x-ray photoelectron spectroscopy study of rhodium carbonyls adsorbed on planar aluminas: formation of geminal dicarbonyl species Stereorational total synthesis of (.+-.)-porantherine The mechanism of the chorismate mutase reaction Electroreduction of carbon monoxide to methane and ethylene at a copper electrode in aqueous solutions at ambient temperature and pressure Correction. Solvent and Free-Radical Effects on the 13C NMR Spectra of Hydrocarbons Parallel behavior in kinetic and NMR effects: secondary deuterium isotope effects on the alkaline hydrolysis of esters Bis(trifluoromethyl)sulfene: generation and cycloaddition reactions Correction. Biosynthesis of the Kinamycin Antibiotics by Strepomyces murayamaensis. Determination of the Origin of Carbon, Hydrogen, and Oxygen Atoms by 13C NMR Spectroscopy Synthesis and x-ray structural characterization of the metal borylamide complexes Li(Et2O)2NPhBMes2, (THF)(Et2O)2LiClCo{NPhBMes2}2, and Mn{NMesBMes2}2.cntdot.3PhMe (Mes = 2,4,6-Me3C6H2): modified amide ligands with poor bridging and .pi.-donor characteristics Primary and secondary kinetic deuterium isotope effects and transition-state structures for benzylic chlorination and bromination of toluene Masthead Volumes of activation for the cycloaddition reactions of phenylhalocarbenes to alkenes Molecular recognition: hydrogen bonding and stacking interactions stabilize a model for nucleic acid structure Mechanism-based isocoumarin inhibitors for trypsin-like serine proteases involved in blood coagulation Cation distributions within a cluster framework. Synthesis and structure of the carbon- and boron-centered zirconium cluster compounds KZr6Cl15C and CsKZr6Cl15B Photochemistry of multiply bonded dimolybdenum phosphate complexes in acidic solution: photoinduced two-electron oxidation of Mo2(HPO4)44- ion The conformational equilibrium of chorismate in solution: implications for the mechanism of the non-enzymic and the enzyme-catalyzed rearrangement of chorismate to prephenate Molecular dynamics of the primary photochemical event in bacteriorhodopsin. Theoretical evidence for an excited singlet state assignment for the J intermediate

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