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Kinetics and mechanism of the insertion of olefins into niobium- and tantalum-hydride bonds: a study of the competition between steric and electronic effects
Biologically useful chelators that release Ca2+ upon illumination
Evidence for an episulfonium ion intermediate in the formation of S-[2-(N7-guanyl)ethyl]glutathione in DNA
Stereochemistry of the addition of diarylsilylenes to cis- and trans-2-butenes
Book Reviews
Comparison of variable-temperature proton NMR spectra of five-coordinate high-spin (S = 5/2) iron(III) porphyrins and chlorins
Theoretical study of the decomposition of five-coordinate silicon anions
Aggregation of organometallic complex pillars in synthetic fluorhectorite and montmorillonite
Reversibly and irreversibly formed products from the reactions of mercaptalbumin (AlbSH) with Et3PAuCN and of AlbSAuPEt3 with hydrocyanic acid
MC-SCF study of the Diels-Alder reaction between ethylene and butadiene
The coordination of bare iron(I) ion (Fe+) to aliphatic isonitriles differs from that of Fe+ and nitriles
Time-resolved slow dissociation of benzonitrile ions by trapped-ion ion cyclotron resonance photodissociation
Reduction of hydrogen peroxide by the ferrous iron chelate of diethylenetriamine-N,N,N',N",N"-pentaacetate
Several polycyclic valence isomers of dimethyl [14]annulene-1,8-dicarboxylate. Reactivity of a nonconjugated bis[bicyclo[1.1.0]butane]
The synthesis and structure determination from powder diffraction data of LaMo5O8, a new oxomolybdate containing Mo10 clusters
Kinetics and thermochemistry of methyl, ethyl, and isopropyl. Study of the equilibrium R + HBr .dblharw. R-H + Br
Time-resolved resonance Raman spectroscopy and solution kinetics of photogenerated transients in the metal-carbene complex (OC)5W:C(OMe)Ph
Isotopic exchange reactions occurring in the hydrogenation of (1,5-cyclooctadiene)dialkylplatinum(II) complexes over platinum black
New conformation exhibiting near-threefold symmetry for uncomplexes valinomycin in crystals from dimethyl sulfoxide
Palladium-catalyzed arylation of siloxycyclopropanes with aryl triflates. Carbon chain elongation via catalytic carbon-carbon bond cleavage
A novel n-doped metallomacrocyclic conductor
Investigations of a siloxane-based polymer electrolyte employing carbon-13, silicon-29, lithium-7, and sodium-23 solid-state NMR spectroscopy
Absolute rate constants for bromine abstraction from N-bromoimides and Br2 by alkyl radicals
Kinetics and thermochemistry of the tert-butyl radical. Study of the equilibrium tert-C4H9 + HBr .dblharw. iso-C4H10 + Br
Chemical potential driven contraction and relaxation by ionic strength modulation of an inverse temperature transition
High-resolution electrophoretic NMR
Cyclopentenones from the reaction of alkynes with cyclopropylcarbenechromium complexes
Heterogeneous, platinum-catalyzed hydrogenation of (diolefin)dialkylplatinum(II) complexes: kinetics
Synthesis of boron carbide via poly(vinylpentaborane) precursors
Synthesis of bicyclic keto silanes by tandem rearrangement of silylacetylenic ketones
Preparation of polysilanes in the presence of ultrasound
Determination of the heat of reaction for the formation of diphenylcarbene from diphenyldiazomethane using photoacoustic calorimetry [Erratum to document cited in CA99(11):87472W]
Models for strong interactions in proteins and enzymes. 1. Enhanced acidities of principal biological hydrogen donors
1,2-Migrations in free radicals related to coenzyme B12-dependent rearrangements
Host-guest interactions: a fluorescence investigation of the solubilization of diphenylpolyene solute molecules in lipid bilayers
A solution to the in,out-bicyclo[4.4.1]undecan-7-one problem inherent in ingenane total synthesis
Properties of the Fe(II)-Fe(III) derivative of red kidney bean purple phosphatase. Evidence for a binuclear zinc-iron center in the native enzyme
Molecular recognition: hydrogen bonding and aromatic stacking converge to bind cytosine derivatives
Models for strong interactions in proteins and enzymes. 2. Interactions of ions with the peptide link and with imidazole
Synthesis and reactivity of binuclear tropocoronand and related organocopper(I) complexes. Catalytic enantioselective conjugate addition of Grignard reagents to 2-cyclohexen-1-one
The mechanism of the quinamine rearrangements
Diels-Alder reaction of dienes having stereogenic allylic substituents: control of diastereoface selectivity by the dienophile
Luminescent organometallic compounds with relativistic metal-metal bonds. Synthesis and characterization of AuTl[Ph2P(CH2)S]2, a one-dimensional gold-thallium metal-metal bonded polymer in the solid state
Synthesis and structural characterization of a thiolate coordination complex of a mixed-valence Mo(V)/Mo(VI) polyoxomolybdate, [Mo10O28(SCH2CH2O)2(HOCH3)2]4-, and of its decomposition product [Mo4O6(SCH2CH2O)5]2-
Preparation and x-ray structure of a mixed-metal double cubane-type aqua ion, [(H2O)9Mo3S4CuCuS4Mo3(H2O)9]8+
A single-crystal ESR and quantum chemical study of electron-capture trialkylphosphine sulfide and selenide radical anions with a three-electron bond
Electrophilic catalysis by vanadate of the dehydration of hydrated glyoxylate
Widely varying olefin rotation geometry in platinum(II)-olefin complexes containing the .eta.3-allyl ligand. Molecular structure, solution stability, and molecular orbital studies
Aluminum dichloride and dibromide. Preparation, spectroscopic (including matrix isolation) study, reactions, and role (together with alkyl(aryl)aluminum monohalides) in the preparation of organoaluminum compounds
Enzymochemical regioselective oxidation of steroids without oxidoreductase
Preparation and catalytic activity of a new solid acid catalyst
Experimental tests of models to predict nucleophilic addition stereochemistries
Temperature-induced spontaneous emission of uranyl nitrate hexahydrate
Deuterium-labeling experiments relevant to the mechanism of platinum-catalyzed hydrogenation of (diolefin)dialkylplatinum(II) complexes: evidence for isotopic exchange via platinum surface hydrogen. The stereochemistry of reduction
Kinetics and substituent effects in the formation of zirconocene thioaldehyde complexes: .beta.-hydride elimination versus cyclometalation
Metal ion lability constant derived from a linear free energy relationship between ligand-substitution rates of tris(acetylacetonato) and aqua complexes of various tervalent metal ions
4-Oxazoline route to stabilized azomethine ylides. Controlled reduction of oxazolium salts
Diastereoselective synthesis of the first 2,3,4-trisubstituted platina(IV)cyclobutanes
The role of nocardicin G in nocardicin A biosynthesis
Macrochelate complexes of purine 5'-nucleotide triphosphates and monophosphates: definitive multinuclear NMR evidence supported by molecular mechanics calculations
The 2 + 1 REMPI spectra of cyclic ketones in a cold molecular beam. 2. The n .fwdarw. 3s Rydberg transition of methyl-substituted cyclohexanones and cyclopentanones
Acetylenic esters. Preparation and characterization of alkynyl carboxylates via polyvalent iodonium species
Catalysis of the debromination of 4-alkyl-4-bromo-2,5-cyclohexadienones in aqueous solution by .alpha.-cyclodextrin
Mechanism of adenylate kinase. 3. Use of deuterium NMR to show lack of correlation between local substrate dynamics and local binding energy
Formation and autocatalytic destruction of the quinone methide from reductive cleavage of Menogaril
Phenoxazinone synthase: enzymatic catalysis of an aminophenol oxidative cascade
Computer Software Reviews
Proton NMR characterization of the catalytically relevant proximal and distal hydrogen-bonding networks in ligated resting state horseradish peroxidase
A new class of homoleptic 12-electron molybdenum and tungsten alkoxide clusters of formula [M4(OR)12]
Quantitative examination of the photoisomerization of retinal iminium salts by high-field proton NMR spectroscopy
Surface derivatization and isolation of semiconductor cluster molecules
Cyclopentane synthesis via free radical mediated addition of functionalized alkenes to substituted vinyl cyclopropanes
Silylation-mediated oxidation of 4-aza-3-ketosteroids with DDQ proceeds via DDQ-substrate adducts
Masthead
Do chemical reactions react along the reaction path?
Thermal decomposition and cobalt-carbon bond dissociation energies of organocobalamins: neopentyl-, (cyclopentylmethyl)-, (cyclohexylmethyl)-, (tetrahydrofurfuryl)- and ((tetrahydro-2H-pyryl)methyl)cobalamin
Carbon dioxide activation and catalytic lactone synthesis by telomerization of butadiene and carbon dioxide
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