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Low-temperature carbon-13 magnetic resonance. 8. Chemical shielding anisotropy of olefinic carbons
Directed reduction of .beta.-hydroxy ketones employing tetramethylammonium triacetoxyborohydride
Biosynthesis of riboflavin. The structure of the four-carbon precursor
Total synthesis of (.+-.)-forskolin
Theoretical investigation of the anaerobic reduction of halogenated alkanes by cytochrome P-450. 2. Vertical electron affinities of chlorofluoromethanes as a measure of their activity
Single-electron transfer in aromatic nucleophilic substitution in reaction of 1-substituted 2,4-dinitronaphthalenes with hydroxide ion
Free-radical macrocyclization-transannular cyclization
DNA strand scission by naturally occurring 5-alkylresorcinols
Moderately strong intramolecular magnetic exchange interaction between the copper(II) ions separated by 11.25 .ANG. in [L2Cu2(OH2)2(.eta.-terephthalato)](ClO4)2 (L = 1,4,7-trimethyl-1,4,7-triazacyclononane)
Reinterpretation of the bicyclomycin-sodium methanethiolate reaction
Palladium-catalyzed regular insertion of isonitriles into silicon-silicon linkage of polysilane
Proton exchange and NMR line broadening in aromatic nucleophilic addition and substitution
Amphiphilic reactions by means of exceptionally bulky organoaluminum reagents. Rational approach for obtaining unusual equatorial, anti-Cram, and 1,4 selectivity in carbonyl alkylation
Cycloaddition reactions of silyloxyacetylenes with ketenes: synthesis of cyclobutenones, resorcinols, and .DELTA.-6-tetrahydrocannabinol
Alkyl diazonium ion pairs and deamination. Part 45. The preparation of carbonium ions and other high-energy alkylating agents under mild conditions
Rearrangement through Berry pseudorotation and olefin insertion of d8 five-coordinate Rh(H)(C2H4)(CO)2(PH3). An ab initio MO study
Kinetic analysis of alkane polychlorination with molecular chlorine. Chlorine atom/monochloride geminate pairs and the effect of reactive cage walls on the competition between monochloride rotation and chlorine atom escape
An investigation of superoxide dismutase Lys-143, Ile-143, and Glu-143 mutants: Cu2Co2SOD derivatives
A symmetrically hydrogen-bonded binitrosamine cation produced on protonation of N-nitrosopyrrolidine
Lithium-6 and sodium-23 NMR spectroscopic studies of metalated hydrazone cryptates. Effects of ion triplet formation on the stereochemistry of alkylation
Transition structures of pericyclic reactions. Electron correlation and basis set effects on the transition structure and activation energy of the electrocyclization of cyclobutene to butadiene
Do stable isomers of N3H3 exist?
Does formal intramolecular transfer of an acidic deuterium to a site of halogen-lithium exchange show that lithium-halogen exchange is faster than loss of the acidic deuterium? Evidence in favor of an alternative mechanism
Electrochemical reduction of ketones mediated by (dimethylpyrrolidinio)mercury. Reductive cyclization of unsaturated ketones and redox catalysis studies
Correlations between wettability and structure in monolayers of alkanethiols adsorbed on gold
cis-Diaquabis(2,2'-bipyridyl-4,4'-dicarboxylate)ruthenium(II) sensitizes wide band gap oxide semiconductors very efficiently over a broad spectral range in the visible
Direct evidence for both thermal and photochemical stepwise cleavage in a pair of isomeric azo compounds
Bimodal inclusion of nitroxide radicals by .beta.-cyclodextrin in water as detected by electron spin resonance
Ligand-assisted nucleophilic additions. Control of site and face attack of nucleophiles on 4-oxido enones
Reversible binding of dinitrogen and dioxygen by a ruthenium picnic-basket porphyrin
Hexagonal lattice hosts for urea. A new series of designed heterocyclic receptors
Evidence for a chair cyclohexane-1,4-radical cation intermediate in the single electron-transfer-induced Cope rearrangement of 2,5-diaryl-1,5-hexadienes
Oxygen atom transfer from an iridium dioxygen complex: oxidation of carbon monoxide to carbonate
Ultrahigh-resolution silicon-29 solid-state MAS NMR investigation of sorbate and temperature-induced changes in the lattice structure of zeolite ZSM-5
Conformational dynamics detected by nuclear magnetic resonance NOE values and J coupling constants
Transition structures of aldol reactions
A copper-oxygen (Cu2-O2) complex. Crystal structure and characterization of a reversible dioxygen binding system
Free energy effects on biological electron transfer: reactions of iron(IV) cytochrome c peroxidase (ES) with metallocytochromes c
Rapid, reversible intramolecular carbon-hydrogen oxidative addition and hydrogen exchange in a heterodinuclear "early-late" transition metal complex
High-spin carbenes
Synthesis, characterization, and x-ray structure of the ruthenium picnic-basket porphyrins
Heterogeneous catalytic hydrogenation of poly(vinylethylene)
Novel triple-cubane type organometallic oxide clusters: [MCp*MoO4]4.nH2O (M = Rh and Ir; Cp* = C5Me5; n = 2 for Rh and 0 for Ir)
Ab initio calculations on the ring opening of cyclopropane radical cation. Trimethylene radical cation is not a stable intermediate
Single-electron transfer in aromatic nucleophilic addition and substitution in aqueous media
Methyl viologen-mediated oxidation-reduction across dihexadecylphosphate vesicles involves transmembrane diffusion
Quinone-substituted monometalated porphyrin dimers: models for photoinduced charge separation at fixed orientation and energy
The first cyclooctatetraene to which bond shifting is more accessible than ring inversion
The Gilman reagent Ph2CuLi and higher-order Ph3CuLi2: carbon-13 and lithium-6 NMR in dimethyl sulfide
Singlet oxygen production from the reaction of superoxide ion with halocarbons in acetonitrile
The conformational properties of the delta opioid peptide [cyclic] [D-pen2,D-pen5]enkephalin in aqueous solution determined by NMR and energy minimization calculations
Dinitrogen sulfide, N2S, revealed by photoelectron spectroscopy
Arylcyclopropane photochemistry. Unusual aromatic substituent effects on the photochemical rearrangement of (2-arylcyclopropyl)methyl acetates to 1-arylhomoallyl acetates
.eta.1-Coordination versus .eta.2-coordination in transition-metal phosphinomethanide complexes: synthesis and x-ray structure of Cp2Zr(Cl)[C(PMe2)(SiMe3)2]
Preparation and structure of [(C6H5)4P]3[NbTe10].cntdot.DMF: a soluble tellurium cluster containing an interstitial transition metal atom
Protocol for determining enantioselective binding of chiral analytes on chiral chromatographic surfaces
Magnetic field effects on the catalytic oxidation of 2,6-di-tert-butylphenol by CoSMDPT: Deuterium and oxygen-17 magnetic isotope effects
Total synthesis of (-)-Specionin
Photophysics of a cofacial porphyrin-quinone cage molecule and related compounds: fluorescence properties, flash transients, and electron-transfer reactions
An induced barrier to rotation about the .eta.6-arene-metal bond in centrally bound bent-terphenylenechromium tricarbonyl. A gauge for aromatic character and bond localization?
The first fluorinated cyclams
Insertion of (.eta.5-C5Me5)(PMe3)Ir into the carbon-hydrogen bonds of functionalized organic molecules: a C-H activation route to 2-oxa- and 2-azametallacyclobutanes, potential models for olefin oxidation intermediates
Biosynthesis of ephedrine
Sodium ion exchange reactions of monensin in methanol and methanol-water mixtures: a sodium-23 NMR study
Band structures of polyfulvene and related polymers. A model for the effects of benzannelation on the band structures of polythiophene, polypyrrole, and polyfulvene
Reactions of nido-2,3-Et2C2B4H6 with triethylamine-alane: syntheses of new small aluminacarboranes
Absence of a common ion effect on the hydrolysis of an .alpha.-azido ether of an aliphatic aldehyde
Intramolecular hydrosilation of .alpha.-hydroxy enol ethers: a new highly stereoselective route to polyhydroxylated molecules
Computational evaluation and comparison of some nitramine properties
Temperature dependence and electronic transition energies in the magnetic circular dichroism spectrum of horeseradish peroxidase compound I
Criteria for concertedness in cycloadditions
Electron transfer versus energy transfer in the reactions of 2E Cr(bpy)33+ with organochromium and organocobalt complexes
Competitive cage kinetics. Relative rates of complexation of chlorine atom by various arenes
Synthesis and molecular structure of [7]circulene
Modification of proteases to esterases for peptide synthesis: methylchymotrypsin
Book Reviews
Intermolecular hydrogen-bonding effect on carbon-13 NMR chemical shifts of glycine residue carbonyl carbons of peptides in the solid state
A total synthesis of (.+-.)-forskolin
Masthead
Side chain dynamics of crystalline L-[3,3-2H2]methionine studied by deuterium NMR spectroscopy
Novel chemical pathways and charge-transport dynamics of electrodes modified with electropolymerized layers of [Co(v-terpy)2]2+
A model for the diastereofacial differentiation in the alkylation of endocyclic enolate
Pillaring of layered double hydroxides (LDH's) by polyoxometalate anions
Hydride transfer catalyzed by lactate dehydrogenase displays absolute stereospecificity at C4 of the nicotinamide ring
Photoelectrochemical evolution of elemental fluorine at titanium dioxide electrodes in anhydrous hydrogen fluoride solutions
Reactions of alkylmercurials with heteroatom-centered acceptor radicals
Molecular recognition between oligopeptides and nucleic acids: influence of van der Waals contacts in determining the 3'-terminus of DNA sequences read by monocationic lexitropsins
Reactions of 1,1-dimethylsilabutadiene. Stereospecific 4 + 2 and nonstereospecific 2 + 2 cycloadditions
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