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http://hub.abes.fr/acs/periodical/jacsat/1988/volume_110/issue_18/101021ja00226a026/authorship/4
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Synthesis, structure, and reactions of chiral rhenium vinylidene and acetylide complexes of the formula [(.eta.5-C5H5)Re(NO)(PPh3)(X)]n+. Vinylidene complexes that are formed by stereospecific C.beta. electrophilic attack, exist as two Re=C=C geometric isomers, and undergo stereospecific C.alpha. nucleophilic attack
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