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Cluster framework structures and relationships. Two compounds with a new connectivity, K2Zr6Cl15B and K3Zr6Cl15Be
Pentacoordinated molecules. 71. Hydrolysis reactions leading to ring-containing hexacoordinated distannoxanes. Tin-sulfur vs tin-oxygen bonding
Equilibrium isotope effects on the hydration of gas-phase ions. The effect of hydrogen bond formation on deuterium isotopic fractionation factors for H3O+, H5O2+, F(H2O)-, and Cl(H2O)-
Chemical properties of dodecahedrane. Monofunctionalization reactions
Isolation and structure determination of the didemnenones, novel cytotoxic metabolites from tunicates
Structural effect of gem-6 substitution on carbon, nitrogen, phosphorus, sulfur, and oxygen atoms: crystallographic data analysis of numerous C3CZCC3 fragments. Modelization of static and dynamic molecular states
Regioselective double vicinal carbon-carbon bond forming reactions of electron-deficient alkenes by use of allylic stannanes and organoiodo compounds
A rigid and nonperturbing probe for duplex DNA motion
Cyclopropanation of spherical hydrocarbons without need for prior olefination. The synthesis of cyclopropadodecahedranes
Translational symmetries in the linear-chain semiconductors K4[Pt2(P2O5H2)4X].cntdot.nH2O (X = Cl, Br, I)
Asymmetric Diels-Alder cycloaddition reactions with chiral .alpha.,.beta.-unsaturated N-acyloxazolidinones
Rates of specific peptide binding to the glycopeptide antibiotics vancomycin, ristocetin, and avoparcin
Biomimetic oxidation with molecular oxygen. Selective carbon-carbon bond cleavage of 1,2-diols by molecular oxygen and dihydropyridine in the presence of iron-porphyrin catalysts
A deoxymyoglobin model with a sterically unhindered axial imidazole
Periselective intramolecular cycloaddition of allene-1,3-dicarboxylates. Unusual structural feature of [2 + 2] cycloadducts
Peroxide model reaction for placental aromatase
The phosphorus-31 chemical shielding tensor in phospholipids
Observation of a mobile molybdenum carbonyl fragment on .gamma.-alumina by solid-state carbon-13 nuclear magnetic resonance spectroscopy
Characterization of two dissimilatory sulfite reductases (desulforubidin and desulfoviridin) from the sulfate-reducing bacteria. Moessbauer and EPR studies
High-resolution silicon-29 nuclear magnetic resonance in the Y-Si-O-N system
How is transition state looseness related to the reaction barrier?
Pentacoordinated molecules. 70. New five- and six-coordinated anionic tin(IV) complexes. Molecular structure of spirocyclic stannates with mixed ligands
Fundamental properties of Rose Bengal. 25. Bleaching studies of Rose Bengal onium salts
Nickel(0)-promotedcyclization of enynes with isocyanides: a new route to polycycliccyclopentenone skeletons
Generation and trapping of an alkynyl cation
Molecular recognition of biologically interesting substrates: synthesis of an artificial receptor for barbiturates employing six hydrogen bonds
Photoinduced intramolecular electron transfer in peptide-bridged molecules
X-ray absorption study of octafluorodirhenate(III): EXAFS structures and resonance Raman spectroscopy of octahalodirhenates
Ultraviolet resonance Raman excitation profiles of tyrosine: dependence of Raman cross sections on excited-state intermediates
Carbocupration of cyclopropene. A novel synthon of cyclopropanone enolate and its application to [3 + 2] and [3 + 2 + 2] annulation
Semiconductor particles in bilayer lipid membranes. Formation, characterization, and photoelectrochemistry
A new rigid sulfur-bridged dithiametacyclophane and its acyclic analogs: direct observation of the transannular bond formation between the three sulfur atoms and isolation of dicationic salts
Application of carbon-13 NMR spectroscopy to acyclic conformational analysis
Lewis acid catalysis of photochemical reactions. 7. Photodimerization and cross-cycloaddition of cinnamic esters
Lewis acid-promoted carbon-carbon bond formation between bridging isocyanides
Energy requirements for a chemical reaction. 2. Electron transfer to SbF5 and SnCl4
Very efficient visible light energy harvesting and conversion by spectral sensitization of high surface area polycrystalline titanium dioxide films
Chemical properties of dodecahedrane. The dodecahedryl cation and 1,16-dodecahedryl dication. Regioselective difunctionalization of the sphere
Triplet ground-state benzoylphenylmethylene and its quintet ground-state triplet-triplet radical pair
Synchrotron radiation selected s-tetrazine ion chemistry
Elemental carbon cages
Homolytic bond dissociation energies in solution from equilibrium acidity and electrochemical data
Photoinduced electron transfer in contact ion pairs
Total synthesis of (+)-CC-1065 and ent-(-)-CC-1065
Heteronuclear chemical-shift correlations of silanol groups studied by two-dimensional cross-polarization magic angle spinning NMR
High-field, high-resolution proton "magic-angle" sample-spinning nuclear magnetic resonance spectroscopic studies of gel and liquid crystalline lipid bilayers and the effects of cholesterol
Electron spin-echo studies of the copper binding site in phenylalanine hydroxylase from Chromobacterium violaceum
Radical intermediates in the epoxidation of alkenes by cytochrome P-450 model systems. The design of a hypersensitive radical probe
Book Reviews
Broken symmetry analysis of spin coupling in iron-sulfur clusters
Peptide conformations. 46. Conformational analysis of a superpotent cytoprotective cyclic somatostatin analog
Stereochemical effects in the gas-phase pinacol rearrangement. 2. Ring contraction versus methyl migration in cis- and trans-1,2-dimethylcyclohexane-1,2-diol
Homotropenylium cation revisited: POAV and 3D-HMO analysis
Kinetics, mechanism, and thermodynamic aspects of the interconversion of complexes of planar and nonplanar metallo-amido-N-groups
A theoretical treatment of nucleophilic reactivity in additions to carbonyl compounds. Role of the vertical ionization energy
Organic reactions in liquid crystalline solvents. 6. Regiochemical control of bimolecular chemical reactivity in smectic and cholesteric liquid crystals
A heteroaromatic trimethylenemethane
Relaxation or fluctuation of the ionic atmosphere in charge-transfer reactions. An ab initio study of the charge transfer in the (H3O2)- and (FCH3F)- systems
Combined single-crystal x-ray diffraction and magic angle spinning NMR study of .alpha.-CaZn2(PO4)2
Dioxygen-copper reactivity. Models for hemocyanin: Reversible O2 and CO binding to structurally characterized dicopper(I) complexes containing hydrocarbon-linked bis[2-(2-pyridyl)ethyl]amine units
Metalation and alkylation of 4H-1,3-dioxin: a new .beta.-acyl vinyl anion equivalent
Electronic absorptions in the high Tc superconductor YBa2Cu3Ox
Selective binding of imidazoles and related organic molecules in an organic solvent
Masthead
The quest for free metaphosphate in solution. Racemization at phosphorus in the transfer of the phospho group from aryl phosphate monoesters to tert-butyl alcohol in acetonitrile or in tert-butyl alcohol
Silacyclobutadienes: generation of 1-mesityl-2,3,4-tri-tert-butyl-1-silacyclobutadiene
Dinuclear formamidinato complexes of nickel and palladium
A general strategy for the chemical sequencing of polysaccharides
An iron-activated alcohol dehydrogenase: metal dissociation constants and magnetic and spectroscopic properties
Remarkable effects of lone pair-lone pair interactions on the extremely stereoselective [2 + 2] cycloaddition of azidoketene to chiral 3-imino-.beta.-lactams [Erratum to document cited in CA106(19):156852x]
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